fosfato de cobre (ii) - universidad veracruzana

21
2/12/2020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem https://pubchem.ncbi.nlm.nih.gov/compound/Copper_II_-phosphate 1/21 RESUMEN COMPUESTO Fosfato de cobre (II) PubChem CID 86469 Estructura Encuentra estructuras similares Seguridad química Hoja de datos del resumen de seguridad química de laboratorio (LCSS) Fórmula molecular C u ( P O ) o C u O P Sinónimos Fosfato de cobre (II) Fosfato cúprico 7798-23-4 UNII-N8NP6FR80R N8NP6FR80R Más... Peso molecular 380,58 g / mol Compuestos componentes CID 23978 (Cobre) CID 1004 (ácido fosfórico) Fecha s Modificar 2020-11-29 Crear 2005-08-08 2D Irritant Environmental Hazard 3 4 2 3 8 2

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Page 1: Fosfato de cobre (II) - Universidad Veracruzana

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 121

RESUMEN COMPUESTO

Fosfato de cobre (II)PubChem CID 86469

Estructura

Encuentra estructuras similares

Seguridad quiacutemica

Hoja de datos del resumen de seguridad quiacutemica de laboratorio (LCSS)

Foacutermula molecular C u ( P O ) o C u O P

Sinoacutenimos

Fosfato de cobre (II)Fosfato cuacuteprico7798-23-4UNII-N8NP6FR80RN8NP6FR80R

Maacutes

Peso molecular 38058 g mol

Compuestos componentes

CID 23978 (Cobre)

CID 1004 (aacutecido fosfoacuterico)

Fecha sModificar2020-11-29

Crear2005-08-08

2D

IrritantEnvironmental

Hazard

3 4 2 3 8 2

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 221

1 Estructuras

11 Estructura 2D

PubChem

12 Estado 3D

La generacioacuten de conformadores no estaacute permitida ya que el elemento la mezcla o la sal no admitidos del MMFF94

PubChem

Representacioacuten de laestructura quiacutemica

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 321

2 Nombres e identificadores

21 Descriptores calculados

211 Nombre IUPAC

tricopper difosfatoCalculado por LexiChem 266 ( versioacuten PubChem 20190618)

PubChem

212 InChI

InChI = 1S 3Cu2H3O4P c 2 1-5 (23) 4 h 2 (H31234) q3 + 2 p -6Computed by InChI 105 (PubChem release 20190618)

PubChem

213 InChI Key

GQDHEYWVLBJKBA-UHFFFAOYSA-HComputed by InChI 105 (PubChem release 20190618)

PubChem

214 Canonical SMILES

[O-]P(=O)([O-])[O-][O-]P(=O)([O-])[O-][Cu+2][Cu+2][Cu+2]Computed by OEChem 215 (PubChem release 20190618)

PubChem

22 Molecular Formula

Cu3(PO4)2

Wikipedia

Cu3O8P2Computed by PubChem 21 (PubChem release 20190618)

PubChem

23 Other Identifiers

231 CAS

7798-23-4

ChemIDplus EPA Chemicals under the TSCA EPA DSSTox European Chemicals Agency (ECHA) Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 421

232 Deprecated CAS

1913303-43-1

ChemIDplus

233 European Community (EC) Number

232-254-5

European Chemicals Agency (ECHA)

234 UNII

N8NP6FR80R

FDASPL Indexing Data

235 DSSTox Substance ID

DTXSID00872547

EPA DSSTox

236 Wikipedia

Copper(II) phosphate

Wikipedia

24 Synonyms

241 Depositor-Supplied Synonyms

Copper(II) phosphateCupric phosphate7798-23-4UNII-N8NP6FR80RN8NP6FR80RTricopper bis(orthophosphate)Copper phosphate (Cu3(PO4)2)Copper phosphate (32)HSDB 267Phosphoric acid copper(2+) salt (23)Cupric phosphate (Cu3(PO4)2)Phosphoric acid copper(2+) saltcopper(ii)phosphate

EINECS 232-254-53Cu2PO4CTK3J2900DTXSID008725475341AFMFCD00036268AKOS015856691Phosphoric acidcopper(2+) salt (23)Q112356

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 521

3 Chemical and Physical Properties

31 Computed Properties

Property Name Property Value Reference

Molecular Weight 38058 gmol Computed by PubChem 21 (PubChem release 20190618)

Hydrogen Bond Donor Count 0 Computed by Cactvs 34611 (PubChem release 20190618)

Hydrogen Bond Acceptor Count 8 Computed by Cactvs 34611 (PubChem release 20190618)

Rotatable Bond Count 0 Computed by Cactvs 34611 (PubChem release 20190618)

Exact Mass 38069382 gmol Computed by PubChem 21 (PubChem release 20190618)

Monoisotopic Mass 37869563 gmol Computed by PubChem 21 (PubChem release 20190618)

Topological Polar Surface Area 173 Aringsup2 Computed by Cactvs 34611 (PubChem release 20190618)

Heavy Atom Count 13 Computed by PubChem

Formal Charge 0 Computed by PubChem

Complexity 368 Computed by Cactvs 34611 (PubChem release 20190618)

Isotope Atom Count 0 Computed by PubChem

Defined Atom Stereocenter Count 0 Computed by PubChem

Undefined Atom Stereocenter Count 0 Computed by PubChem

Defined Bond Stereocenter Count 0 Computed by PubChem

Undefined Bond Stereocenter Count 0 Computed by PubChem

Covalently-Bonded Unit Count 5 Computed by PubChem

Compound Is Canonicalized Yes Computed by PubChem (release 20190104)

PubChem

32 Experimental Properties

321 ColorForm

SOLID BLUISH-GREEN POWDERSax NI Dangerous Properties of Industrial Materials 4th ed New York Van Nostrand Reinhold 1975 p 576

Hazardous Substances Data Bank (HSDB)

Light blue powderGerhartz W (exec ed) Ullmanns Encyclopedia of Industrial Chemistry 5th edVol A1 Deerfield Beach FL VCH Publishers 1985 to Present p VA7(1986) 585

Hazardous Substances Data Bank (HSDB)

322 Solubility

Insoluble in cold water slightly soluble in hot water and soluble in ammonia solution and mineral acidsGerhartz W (exec ed) Ullmanns Encyclopedia of Industrial Chemistry 5th edVol A1 Deerfield Beach FL VCH Publishers 1985 to Present p VA7(1986) 585

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 621

323 Decomposition

DANGEROUS WHEN HEATED TO DECOMPOSITION CAN EMIT HIGHLY TOXIC FUMES OF PHOSPHORUS OXIDESPHOSPHATES

Sax NI Dangerous Properties of Industrial Materials 4th ed New York Van Nostrand Reinhold 1975 p 1021

Hazardous Substances Data Bank (HSDB)

324 Other Experimental Properties

Blue or olive orthorhombic crystals or blue to bluish green powder decomposes on heating practically insol in cold waterslightly sol in hot water sol in acids ammonium hydroxide Cupric phosphate trihydrate

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

MF Cu3(PO4)23H2O MW 43463 COFO blue rhombic crystals Solubility sol in water acid ammonium hydroxide slightlysoluble in acetone insoluble in ethanol Copper(II) phosphate trihydrate

Lide DR (ed) CRC Handbook of Chemistry and Physics 79th ed Boca Raton FL CRC Press Inc 1998-1999 p 4-56

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 721

4 Related Records

41 Related Compounds with Annotation

PubChem

42 Component Compounds

CID 23978 (Copper)

CID 1004 (Phosphoric acid)

PubChem

43 Related CompoundsMixtures Components andNeutralized Forms 2 Records

Similar Compounds 12 Records

PubChem

44 Substances

441 Related Substances

Same 34 Records

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 821

442 Substances by Category

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 921

5 Chemical Vendors

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1021

6 Drug and Medication Information

61 Therapeutic Uses

MEDICATION (VET) TRACE MINERAL ADDED TO ANIMAL FEEDSSax NI Dangerous Properties of Industrial Materials 4th ed New York Van Nostrand Reinhold 1975 p 576

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1121

7 Use and Manufacturing

71 Uses

Fungicide catalyst for org reactions fertilizer emulsifier corrosion inhibitor for phosphoric acid protectant for metal surfacesagainst oxidation

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

Fungicide formerGerhartz W (exec ed) Ullmanns Encyclopedia of Industrial Chemistry 5th edVol A1 Deerfield Beach FL VCH Publishers 1985 to Present p VA7(1986) 585

Hazardous Substances Data Bank (HSDB)

MEDICATION

Hazardous Substances Data Bank (HSDB)

MEDICATION (VET)

Hazardous Substances Data Bank (HSDB)

72 Methods of Manufacturing

Preparation from copper sulfate and diammonium hydrogen phosphate Klement Haselbeck Z Anorg Allgem Chem 334 27(1964)

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

Prepared by reaction of copper(II) sulfate solution with soluble alkali phosphatesGerhartz W (exec ed) Ullmanns Encyclopedia of Industrial Chemistry 5th edVol A1 Deerfield Beach FL VCH Publishers 1985 to Present p VA7(1986) 585

Hazardous Substances Data Bank (HSDB)

73 General Manufacturing Information

EPA TSCA Commercial Activity Status

Phosphoric acid copper(2+) salt (23) ACTIVEhttpswwwepagovtsca-inventory

EPA Chemicals under the TSCA

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1221

8 Safety and Hazards

81 Hazards Identification

811 GHS Classification

Pictogram(s)

Signal Warning

GHS Hazard Statements

Aggregated GHS information provided by 13 companies from 5 notifications to the ECHA CampL Inventory Eachnotification may be associated with multiple companies

H302 (3077) Harmful if swallowed [Warning Acute toxicity oral]

H315 (3077) Causes skin irritation [Warning Skin corrosionirritation]

H319 (2308) Causes serious eye irritation [Warning Serious eye damageeye irritation]

H335 (2308) May cause respiratory irritation [Warning Specific target organ toxicity single exposureRespiratory tract irritation]

H410 (1538) Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquaticenvironment long-term hazard]

H412 (3077) Harmful to aquatic life with long lasting effects [Hazardous to the aquatic environment long-term hazard]

Information may vary between notifications depending on impurities additives and other factors Thepercentage value in parenthesis indicates the notified classification ratio from companies that provide hazardcodes Only hazard codes with percentage values above 10 are shown

Precautionary StatementCodes

P261 P264 P270 P271 P273 P280 P301+P312 P302+P352 P304+P340 P305+P351+P338 P312 P321P330 P332+P313 P337+P313 P362 P391 P403+P233 P405 and P501

(The corresponding statement to each P-code can be found at the GHS Classification page)

European Chemicals Agency (ECHA)

812 Hazard Classes and Categories

Skin Irrit 2 (3077)

Eye Irrit 2 (2308)

STOT SE 3 (2308)

Aquatic Chronic 1 (1538)

Aquatic Chronic 3 (3077)

European Chemicals Agency (ECHA)

82 Safety and Hazard Properties

821 NIOSH Recommendations

Recommended Exposure Limit 10 Hr Time-Weighted Avg 1 mgcu m Copper (dusts and mists)NIOSH NIOSH Pocket Guide to Chemical Hazards DHHS (NIOSH) Publication No 97-140 Washington DC US Government Printing Office1997 p 76

IrritantEnvironmental

Hazard

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1321

Hazardous Substances Data Bank (HSDB)

83 Accidental Release Measures

831 Disposal Methods

SRP At the time of review criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significantrevision Prior to implementing land disposal of waste residue (including waste sludge) consult with environmental regulatoryagencies for guidance on acceptable disposal practices

Hazardous Substances Data Bank (HSDB)

Group III Containers (both combustible and non-combustible) that previously held organic mercury lead cadmium arsenic orinorganic pesticides should be triple rinsed punctured and disposed of in a sanitary landfill Non-rinsed containers should beencapsulated and buried at a specially designated landfill site Organic mercury lead cadmium arsenic or inorganicpesticides

40 CFR 165 (7188)

Hazardous Substances Data Bank (HSDB)

84 Exposure Control and Personal Protection

841 Threshold Limit Values (TLV)

8 hr Time Weighted Avg (TWA) 1 mgcu m Copper dusts and mists as CuAmerican Conference of Governmental Industrial Hygienists TLVs and BEIs Threshold Limit Values for Chemical Substances and Physical Agentsand Biological Exposure Indices Cincinnati OH 2008 p 21

Hazardous Substances Data Bank (HSDB)

Excursion Limit Recommendation Excursions in worker exposure levels may exceed 3 times the TLV-TWA for no more than atotal of 30 minutes during a work day and under no circumstances should they exceed 5 times the TLV-TWA provided that theTLV-TWA is not exceeded Copper dusts and mists as Cu

American Conference of Governmental Industrial Hygienists TLVs and BEIs Threshold Limit Values for Chemical Substances and Physical Agentsand Biological Exposure Indices Cincinnati OH 2008 p 5

Hazardous Substances Data Bank (HSDB)

842 Acceptable Daily Intakes

The available human data indicate that gastrointestinal distress occurred following ingestion of solutions that contained 5-7 mgof copper and other unknown chemicals as a single dose These data were used to derive a 1 day health advisory of 13 mglwhich when spread over a day should provide protection from these acute effects Since the effects appear to be local irritationthis health advisory is recommended for both the child and the adult There are no data indicating that human exposure tocopper results in chronic toxic effects Furthermore there is a nutritional requirement for copper and acute effects appear to bethe effects of concern Therefore the one day health advisory 13 mgl will also be used as the adjustable acceptable dailyintake Copper

USEPA Drinking Water Criteria Document for Copper (Final Draft) pI-2 (1985) EPA-600X-84-190-1

Hazardous Substances Data Bank (HSDB)

85 Stability and Reactivity

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1421

851 Hazardous Reactivities and Incompatibilities

Solutions of sodium hypobromite are decomposed by powerful catalytic action of cupric ions even as impurities Cupric saltsFire Protection Guide to Hazardous Materials 12 ed Quincy MA National Fire Protection Association 1997 p 491-181

Hazardous Substances Data Bank (HSDB)

86 Regulatory Information

861 Federal Drinking Water Standards

EPA 1300 ugl (Action Level) CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

862 Federal Drinking Water Guidelines

EPA 1000 ugl CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

863 State Drinking Water Guidelines

(AZ) ARIZONA 1300 ugl CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

864 Clean Water Act Requirements

Toxic pollutant designated pursuant to section 307(a)(1) of the Federal Water Pollution Control Act and is subject to effluentlimitations Copper and cmpd

40 CFR 40115 (712000)

Hazardous Substances Data Bank (HSDB)

87 Other Safety Information

871 Toxic Combustion Products

DANGEROUS WHEN HEATED TO DECOMPOSITION CAN EMIT HIGHLY TOXIC FUMES OF PO(X) PHOSPHATESSax NI Dangerous Properties of Industrial Materials 4th ed New York Van Nostrand Reinhold 1975 p 1021

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1521

9 Toxicity

91 Toxicological Information

911 Antidote and Emergency Treatment

Basic treatment Establish a patent airway Suction if necessary Watch for signs of respiratory insufficiency and assist ventilationsif necessary Administer oxygen by nonrebreather mask at 10 to 15 Lmin Monitor for shock and treat if necessary For eyecontamination flush eyes immediately with water Irrigate each eye continuously with normal saline during transport Do notuse emetics For ingestion rinse mouth and administer 5 mlkg up to 200 ml of water for dilution if the patient can swallow hasa strong gag reflex and does not drool Administer activated charcoal Copper and related compounds

Bronstein AC PL Currance Emergency Care for Hazardous Materials Exposure 2nd ed St Louis MO Mosby Lifeline 1994 p 350

Hazardous Substances Data Bank (HSDB)

Advanced treatment Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious Startan IV with lactated Ringers SRP To keep open minimal flow rate Watch for signs of fluid overload For hypotension withsigns of hypovolemia administer fluid cautiously Consider vasopressors if hypotensive with a normal fluid volume Watch forsigns of fluid overload Use proparacaine hydrochloride to assist eye irrigation Copper and related compounds

Bronstein AC PL Currance Emergency Care for Hazardous Materials Exposure 2nd ed St Louis MO Mosby Lifeline 1994 p 351

Hazardous Substances Data Bank (HSDB)

92 Ecological Information

921 Natural Pollution Sources

Basic salts occur in nature as the minerals cornetite dihydrite libethenite phosphorochalcite pseudolibethenitepseudomalachite tagilite

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1621

10 Literature

101 Springer Nature References

Springer Nature

102 Chemical Co-Occurrences in Literature

PubChem

103 Chemical-Gene Co-Occurrences in Literature

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1721

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1821

11 Patents

111 WIPO PATENTSCOPE

Patents are available for this chemical structure

httpspatentscopewipointsearchenresultjsfinchikey=GQDHEYWVLBJKBA-UHFFFAOYSA-H

PATENTSCOPE (WIPO)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1921

12 Classification

121 Ontologies

1211 ChemIDplus

ChemIDplus

1212 UN GHS Classification

UN Globally Harmonized System of Classification and Labelling of Chemicals (GHS)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2021

13 Information Sources

FILTER BY SOURCE

1 ChemIDplusLICENSEhttpswwwnlmnihgovcopyrighthtml

Copper(II) phosphatehttpschemnlmnihgovchemidplussid0007798234

ChemIDplus Chemical Information Classificationhttpschemnlmnihgovchemidplus

2 EPA Chemicals under the TSCALICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Phosphoric acid copper(2+) salt (23)httpswwwepagovchemicals-under-tsca

3 EPA DSSToxLICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Copper(II) phosphatehttpscomptoxepagovdashboardDTXSID00872547

4 European Chemicals Agency (ECHA)LICENSEUse of the information documents and data from the ECHA website is subject to the terms and conditions of this Legal Notice and subject to otherbinding limitations provided for under applicable law the information documents and data made available on the ECHA website may be reproduceddistributed andor used totally or in part for non-commercial purposes provided that ECHA is acknowledged as the source Source European ChemicalsAgency httpechaeuropaeu Such acknowledgement must be included in each copy of the material ECHA permits and encourages organisations andindividuals to create links to the ECHA website under the following cumulative conditions Links can only be made to webpages that provide a link to theLegal Notice pagehttpsechaeuropaeuwebguestlegal-notice

Tricopper bis(orthophosphate)httpsechaeuropaeusubstance-information-substanceinfo100029322

Tricopper bis(orthophosphate)httpsechaeuropaeuinformation-on-chemicalscl-inventory-database-disclidetails62531

5 Hazardous Substances Data Bank (HSDB)COPPER(II) PHOSPHATEhttpspubchemncbinlmnihgovsourcehsdb267

6 FDASPL Indexing DataLICENSEUnless otherwise noted the contents of the FDA website (wwwfdagov) both text and graphics are not copyrighted They are in the public domain andmay be republished reprinted and otherwise used freely by anyone without the need to obtain permission from FDA Credit to the US Food and DrugAdministration as the source is appreciated but not requiredhttpswwwfdagovabout-fdaabout-websitewebsite-policieslinking

N8NP6FR80RhttpswwwfdagovForIndustryDataStandardsSubstanceRegistrationSystem-UniqueIngredientIdentifierUNII

7 Springer Naturehttpspubchemncbinlmnihgovsubstance341378879

8 Wikipediafosfato de cobre (II)httpsenwikipediaorgwikiCopper(II)_phosphate

ALL SOURCES

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2121

9 PubChemhttpspubchemncbinlmnihgov

10 Sistema Globalmente Armonizado de Clasificacioacuten y Etiquetado de Productos Quiacutemicos(GHS) de las Naciones UnidasAacuterbol de clasificacioacuten GHShttpwwwuneceorgtransdangerpublighsghs_welcome_ehtml

11 PATENTSCOPE (OMPI)SID 403419907httpspubchemncbinlmnihgovsubstance403419907

Page 2: Fosfato de cobre (II) - Universidad Veracruzana

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 221

1 Estructuras

11 Estructura 2D

PubChem

12 Estado 3D

La generacioacuten de conformadores no estaacute permitida ya que el elemento la mezcla o la sal no admitidos del MMFF94

PubChem

Representacioacuten de laestructura quiacutemica

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 321

2 Nombres e identificadores

21 Descriptores calculados

211 Nombre IUPAC

tricopper difosfatoCalculado por LexiChem 266 ( versioacuten PubChem 20190618)

PubChem

212 InChI

InChI = 1S 3Cu2H3O4P c 2 1-5 (23) 4 h 2 (H31234) q3 + 2 p -6Computed by InChI 105 (PubChem release 20190618)

PubChem

213 InChI Key

GQDHEYWVLBJKBA-UHFFFAOYSA-HComputed by InChI 105 (PubChem release 20190618)

PubChem

214 Canonical SMILES

[O-]P(=O)([O-])[O-][O-]P(=O)([O-])[O-][Cu+2][Cu+2][Cu+2]Computed by OEChem 215 (PubChem release 20190618)

PubChem

22 Molecular Formula

Cu3(PO4)2

Wikipedia

Cu3O8P2Computed by PubChem 21 (PubChem release 20190618)

PubChem

23 Other Identifiers

231 CAS

7798-23-4

ChemIDplus EPA Chemicals under the TSCA EPA DSSTox European Chemicals Agency (ECHA) Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 421

232 Deprecated CAS

1913303-43-1

ChemIDplus

233 European Community (EC) Number

232-254-5

European Chemicals Agency (ECHA)

234 UNII

N8NP6FR80R

FDASPL Indexing Data

235 DSSTox Substance ID

DTXSID00872547

EPA DSSTox

236 Wikipedia

Copper(II) phosphate

Wikipedia

24 Synonyms

241 Depositor-Supplied Synonyms

Copper(II) phosphateCupric phosphate7798-23-4UNII-N8NP6FR80RN8NP6FR80RTricopper bis(orthophosphate)Copper phosphate (Cu3(PO4)2)Copper phosphate (32)HSDB 267Phosphoric acid copper(2+) salt (23)Cupric phosphate (Cu3(PO4)2)Phosphoric acid copper(2+) saltcopper(ii)phosphate

EINECS 232-254-53Cu2PO4CTK3J2900DTXSID008725475341AFMFCD00036268AKOS015856691Phosphoric acidcopper(2+) salt (23)Q112356

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 521

3 Chemical and Physical Properties

31 Computed Properties

Property Name Property Value Reference

Molecular Weight 38058 gmol Computed by PubChem 21 (PubChem release 20190618)

Hydrogen Bond Donor Count 0 Computed by Cactvs 34611 (PubChem release 20190618)

Hydrogen Bond Acceptor Count 8 Computed by Cactvs 34611 (PubChem release 20190618)

Rotatable Bond Count 0 Computed by Cactvs 34611 (PubChem release 20190618)

Exact Mass 38069382 gmol Computed by PubChem 21 (PubChem release 20190618)

Monoisotopic Mass 37869563 gmol Computed by PubChem 21 (PubChem release 20190618)

Topological Polar Surface Area 173 Aringsup2 Computed by Cactvs 34611 (PubChem release 20190618)

Heavy Atom Count 13 Computed by PubChem

Formal Charge 0 Computed by PubChem

Complexity 368 Computed by Cactvs 34611 (PubChem release 20190618)

Isotope Atom Count 0 Computed by PubChem

Defined Atom Stereocenter Count 0 Computed by PubChem

Undefined Atom Stereocenter Count 0 Computed by PubChem

Defined Bond Stereocenter Count 0 Computed by PubChem

Undefined Bond Stereocenter Count 0 Computed by PubChem

Covalently-Bonded Unit Count 5 Computed by PubChem

Compound Is Canonicalized Yes Computed by PubChem (release 20190104)

PubChem

32 Experimental Properties

321 ColorForm

SOLID BLUISH-GREEN POWDERSax NI Dangerous Properties of Industrial Materials 4th ed New York Van Nostrand Reinhold 1975 p 576

Hazardous Substances Data Bank (HSDB)

Light blue powderGerhartz W (exec ed) Ullmanns Encyclopedia of Industrial Chemistry 5th edVol A1 Deerfield Beach FL VCH Publishers 1985 to Present p VA7(1986) 585

Hazardous Substances Data Bank (HSDB)

322 Solubility

Insoluble in cold water slightly soluble in hot water and soluble in ammonia solution and mineral acidsGerhartz W (exec ed) Ullmanns Encyclopedia of Industrial Chemistry 5th edVol A1 Deerfield Beach FL VCH Publishers 1985 to Present p VA7(1986) 585

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 621

323 Decomposition

DANGEROUS WHEN HEATED TO DECOMPOSITION CAN EMIT HIGHLY TOXIC FUMES OF PHOSPHORUS OXIDESPHOSPHATES

Sax NI Dangerous Properties of Industrial Materials 4th ed New York Van Nostrand Reinhold 1975 p 1021

Hazardous Substances Data Bank (HSDB)

324 Other Experimental Properties

Blue or olive orthorhombic crystals or blue to bluish green powder decomposes on heating practically insol in cold waterslightly sol in hot water sol in acids ammonium hydroxide Cupric phosphate trihydrate

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

MF Cu3(PO4)23H2O MW 43463 COFO blue rhombic crystals Solubility sol in water acid ammonium hydroxide slightlysoluble in acetone insoluble in ethanol Copper(II) phosphate trihydrate

Lide DR (ed) CRC Handbook of Chemistry and Physics 79th ed Boca Raton FL CRC Press Inc 1998-1999 p 4-56

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 721

4 Related Records

41 Related Compounds with Annotation

PubChem

42 Component Compounds

CID 23978 (Copper)

CID 1004 (Phosphoric acid)

PubChem

43 Related CompoundsMixtures Components andNeutralized Forms 2 Records

Similar Compounds 12 Records

PubChem

44 Substances

441 Related Substances

Same 34 Records

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 821

442 Substances by Category

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 921

5 Chemical Vendors

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1021

6 Drug and Medication Information

61 Therapeutic Uses

MEDICATION (VET) TRACE MINERAL ADDED TO ANIMAL FEEDSSax NI Dangerous Properties of Industrial Materials 4th ed New York Van Nostrand Reinhold 1975 p 576

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1121

7 Use and Manufacturing

71 Uses

Fungicide catalyst for org reactions fertilizer emulsifier corrosion inhibitor for phosphoric acid protectant for metal surfacesagainst oxidation

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

Fungicide formerGerhartz W (exec ed) Ullmanns Encyclopedia of Industrial Chemistry 5th edVol A1 Deerfield Beach FL VCH Publishers 1985 to Present p VA7(1986) 585

Hazardous Substances Data Bank (HSDB)

MEDICATION

Hazardous Substances Data Bank (HSDB)

MEDICATION (VET)

Hazardous Substances Data Bank (HSDB)

72 Methods of Manufacturing

Preparation from copper sulfate and diammonium hydrogen phosphate Klement Haselbeck Z Anorg Allgem Chem 334 27(1964)

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

Prepared by reaction of copper(II) sulfate solution with soluble alkali phosphatesGerhartz W (exec ed) Ullmanns Encyclopedia of Industrial Chemistry 5th edVol A1 Deerfield Beach FL VCH Publishers 1985 to Present p VA7(1986) 585

Hazardous Substances Data Bank (HSDB)

73 General Manufacturing Information

EPA TSCA Commercial Activity Status

Phosphoric acid copper(2+) salt (23) ACTIVEhttpswwwepagovtsca-inventory

EPA Chemicals under the TSCA

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1221

8 Safety and Hazards

81 Hazards Identification

811 GHS Classification

Pictogram(s)

Signal Warning

GHS Hazard Statements

Aggregated GHS information provided by 13 companies from 5 notifications to the ECHA CampL Inventory Eachnotification may be associated with multiple companies

H302 (3077) Harmful if swallowed [Warning Acute toxicity oral]

H315 (3077) Causes skin irritation [Warning Skin corrosionirritation]

H319 (2308) Causes serious eye irritation [Warning Serious eye damageeye irritation]

H335 (2308) May cause respiratory irritation [Warning Specific target organ toxicity single exposureRespiratory tract irritation]

H410 (1538) Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquaticenvironment long-term hazard]

H412 (3077) Harmful to aquatic life with long lasting effects [Hazardous to the aquatic environment long-term hazard]

Information may vary between notifications depending on impurities additives and other factors Thepercentage value in parenthesis indicates the notified classification ratio from companies that provide hazardcodes Only hazard codes with percentage values above 10 are shown

Precautionary StatementCodes

P261 P264 P270 P271 P273 P280 P301+P312 P302+P352 P304+P340 P305+P351+P338 P312 P321P330 P332+P313 P337+P313 P362 P391 P403+P233 P405 and P501

(The corresponding statement to each P-code can be found at the GHS Classification page)

European Chemicals Agency (ECHA)

812 Hazard Classes and Categories

Skin Irrit 2 (3077)

Eye Irrit 2 (2308)

STOT SE 3 (2308)

Aquatic Chronic 1 (1538)

Aquatic Chronic 3 (3077)

European Chemicals Agency (ECHA)

82 Safety and Hazard Properties

821 NIOSH Recommendations

Recommended Exposure Limit 10 Hr Time-Weighted Avg 1 mgcu m Copper (dusts and mists)NIOSH NIOSH Pocket Guide to Chemical Hazards DHHS (NIOSH) Publication No 97-140 Washington DC US Government Printing Office1997 p 76

IrritantEnvironmental

Hazard

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1321

Hazardous Substances Data Bank (HSDB)

83 Accidental Release Measures

831 Disposal Methods

SRP At the time of review criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significantrevision Prior to implementing land disposal of waste residue (including waste sludge) consult with environmental regulatoryagencies for guidance on acceptable disposal practices

Hazardous Substances Data Bank (HSDB)

Group III Containers (both combustible and non-combustible) that previously held organic mercury lead cadmium arsenic orinorganic pesticides should be triple rinsed punctured and disposed of in a sanitary landfill Non-rinsed containers should beencapsulated and buried at a specially designated landfill site Organic mercury lead cadmium arsenic or inorganicpesticides

40 CFR 165 (7188)

Hazardous Substances Data Bank (HSDB)

84 Exposure Control and Personal Protection

841 Threshold Limit Values (TLV)

8 hr Time Weighted Avg (TWA) 1 mgcu m Copper dusts and mists as CuAmerican Conference of Governmental Industrial Hygienists TLVs and BEIs Threshold Limit Values for Chemical Substances and Physical Agentsand Biological Exposure Indices Cincinnati OH 2008 p 21

Hazardous Substances Data Bank (HSDB)

Excursion Limit Recommendation Excursions in worker exposure levels may exceed 3 times the TLV-TWA for no more than atotal of 30 minutes during a work day and under no circumstances should they exceed 5 times the TLV-TWA provided that theTLV-TWA is not exceeded Copper dusts and mists as Cu

American Conference of Governmental Industrial Hygienists TLVs and BEIs Threshold Limit Values for Chemical Substances and Physical Agentsand Biological Exposure Indices Cincinnati OH 2008 p 5

Hazardous Substances Data Bank (HSDB)

842 Acceptable Daily Intakes

The available human data indicate that gastrointestinal distress occurred following ingestion of solutions that contained 5-7 mgof copper and other unknown chemicals as a single dose These data were used to derive a 1 day health advisory of 13 mglwhich when spread over a day should provide protection from these acute effects Since the effects appear to be local irritationthis health advisory is recommended for both the child and the adult There are no data indicating that human exposure tocopper results in chronic toxic effects Furthermore there is a nutritional requirement for copper and acute effects appear to bethe effects of concern Therefore the one day health advisory 13 mgl will also be used as the adjustable acceptable dailyintake Copper

USEPA Drinking Water Criteria Document for Copper (Final Draft) pI-2 (1985) EPA-600X-84-190-1

Hazardous Substances Data Bank (HSDB)

85 Stability and Reactivity

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1421

851 Hazardous Reactivities and Incompatibilities

Solutions of sodium hypobromite are decomposed by powerful catalytic action of cupric ions even as impurities Cupric saltsFire Protection Guide to Hazardous Materials 12 ed Quincy MA National Fire Protection Association 1997 p 491-181

Hazardous Substances Data Bank (HSDB)

86 Regulatory Information

861 Federal Drinking Water Standards

EPA 1300 ugl (Action Level) CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

862 Federal Drinking Water Guidelines

EPA 1000 ugl CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

863 State Drinking Water Guidelines

(AZ) ARIZONA 1300 ugl CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

864 Clean Water Act Requirements

Toxic pollutant designated pursuant to section 307(a)(1) of the Federal Water Pollution Control Act and is subject to effluentlimitations Copper and cmpd

40 CFR 40115 (712000)

Hazardous Substances Data Bank (HSDB)

87 Other Safety Information

871 Toxic Combustion Products

DANGEROUS WHEN HEATED TO DECOMPOSITION CAN EMIT HIGHLY TOXIC FUMES OF PO(X) PHOSPHATESSax NI Dangerous Properties of Industrial Materials 4th ed New York Van Nostrand Reinhold 1975 p 1021

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1521

9 Toxicity

91 Toxicological Information

911 Antidote and Emergency Treatment

Basic treatment Establish a patent airway Suction if necessary Watch for signs of respiratory insufficiency and assist ventilationsif necessary Administer oxygen by nonrebreather mask at 10 to 15 Lmin Monitor for shock and treat if necessary For eyecontamination flush eyes immediately with water Irrigate each eye continuously with normal saline during transport Do notuse emetics For ingestion rinse mouth and administer 5 mlkg up to 200 ml of water for dilution if the patient can swallow hasa strong gag reflex and does not drool Administer activated charcoal Copper and related compounds

Bronstein AC PL Currance Emergency Care for Hazardous Materials Exposure 2nd ed St Louis MO Mosby Lifeline 1994 p 350

Hazardous Substances Data Bank (HSDB)

Advanced treatment Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious Startan IV with lactated Ringers SRP To keep open minimal flow rate Watch for signs of fluid overload For hypotension withsigns of hypovolemia administer fluid cautiously Consider vasopressors if hypotensive with a normal fluid volume Watch forsigns of fluid overload Use proparacaine hydrochloride to assist eye irrigation Copper and related compounds

Bronstein AC PL Currance Emergency Care for Hazardous Materials Exposure 2nd ed St Louis MO Mosby Lifeline 1994 p 351

Hazardous Substances Data Bank (HSDB)

92 Ecological Information

921 Natural Pollution Sources

Basic salts occur in nature as the minerals cornetite dihydrite libethenite phosphorochalcite pseudolibethenitepseudomalachite tagilite

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1621

10 Literature

101 Springer Nature References

Springer Nature

102 Chemical Co-Occurrences in Literature

PubChem

103 Chemical-Gene Co-Occurrences in Literature

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1721

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1821

11 Patents

111 WIPO PATENTSCOPE

Patents are available for this chemical structure

httpspatentscopewipointsearchenresultjsfinchikey=GQDHEYWVLBJKBA-UHFFFAOYSA-H

PATENTSCOPE (WIPO)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1921

12 Classification

121 Ontologies

1211 ChemIDplus

ChemIDplus

1212 UN GHS Classification

UN Globally Harmonized System of Classification and Labelling of Chemicals (GHS)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2021

13 Information Sources

FILTER BY SOURCE

1 ChemIDplusLICENSEhttpswwwnlmnihgovcopyrighthtml

Copper(II) phosphatehttpschemnlmnihgovchemidplussid0007798234

ChemIDplus Chemical Information Classificationhttpschemnlmnihgovchemidplus

2 EPA Chemicals under the TSCALICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Phosphoric acid copper(2+) salt (23)httpswwwepagovchemicals-under-tsca

3 EPA DSSToxLICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Copper(II) phosphatehttpscomptoxepagovdashboardDTXSID00872547

4 European Chemicals Agency (ECHA)LICENSEUse of the information documents and data from the ECHA website is subject to the terms and conditions of this Legal Notice and subject to otherbinding limitations provided for under applicable law the information documents and data made available on the ECHA website may be reproduceddistributed andor used totally or in part for non-commercial purposes provided that ECHA is acknowledged as the source Source European ChemicalsAgency httpechaeuropaeu Such acknowledgement must be included in each copy of the material ECHA permits and encourages organisations andindividuals to create links to the ECHA website under the following cumulative conditions Links can only be made to webpages that provide a link to theLegal Notice pagehttpsechaeuropaeuwebguestlegal-notice

Tricopper bis(orthophosphate)httpsechaeuropaeusubstance-information-substanceinfo100029322

Tricopper bis(orthophosphate)httpsechaeuropaeuinformation-on-chemicalscl-inventory-database-disclidetails62531

5 Hazardous Substances Data Bank (HSDB)COPPER(II) PHOSPHATEhttpspubchemncbinlmnihgovsourcehsdb267

6 FDASPL Indexing DataLICENSEUnless otherwise noted the contents of the FDA website (wwwfdagov) both text and graphics are not copyrighted They are in the public domain andmay be republished reprinted and otherwise used freely by anyone without the need to obtain permission from FDA Credit to the US Food and DrugAdministration as the source is appreciated but not requiredhttpswwwfdagovabout-fdaabout-websitewebsite-policieslinking

N8NP6FR80RhttpswwwfdagovForIndustryDataStandardsSubstanceRegistrationSystem-UniqueIngredientIdentifierUNII

7 Springer Naturehttpspubchemncbinlmnihgovsubstance341378879

8 Wikipediafosfato de cobre (II)httpsenwikipediaorgwikiCopper(II)_phosphate

ALL SOURCES

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2121

9 PubChemhttpspubchemncbinlmnihgov

10 Sistema Globalmente Armonizado de Clasificacioacuten y Etiquetado de Productos Quiacutemicos(GHS) de las Naciones UnidasAacuterbol de clasificacioacuten GHShttpwwwuneceorgtransdangerpublighsghs_welcome_ehtml

11 PATENTSCOPE (OMPI)SID 403419907httpspubchemncbinlmnihgovsubstance403419907

Page 3: Fosfato de cobre (II) - Universidad Veracruzana

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 321

2 Nombres e identificadores

21 Descriptores calculados

211 Nombre IUPAC

tricopper difosfatoCalculado por LexiChem 266 ( versioacuten PubChem 20190618)

PubChem

212 InChI

InChI = 1S 3Cu2H3O4P c 2 1-5 (23) 4 h 2 (H31234) q3 + 2 p -6Computed by InChI 105 (PubChem release 20190618)

PubChem

213 InChI Key

GQDHEYWVLBJKBA-UHFFFAOYSA-HComputed by InChI 105 (PubChem release 20190618)

PubChem

214 Canonical SMILES

[O-]P(=O)([O-])[O-][O-]P(=O)([O-])[O-][Cu+2][Cu+2][Cu+2]Computed by OEChem 215 (PubChem release 20190618)

PubChem

22 Molecular Formula

Cu3(PO4)2

Wikipedia

Cu3O8P2Computed by PubChem 21 (PubChem release 20190618)

PubChem

23 Other Identifiers

231 CAS

7798-23-4

ChemIDplus EPA Chemicals under the TSCA EPA DSSTox European Chemicals Agency (ECHA) Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 421

232 Deprecated CAS

1913303-43-1

ChemIDplus

233 European Community (EC) Number

232-254-5

European Chemicals Agency (ECHA)

234 UNII

N8NP6FR80R

FDASPL Indexing Data

235 DSSTox Substance ID

DTXSID00872547

EPA DSSTox

236 Wikipedia

Copper(II) phosphate

Wikipedia

24 Synonyms

241 Depositor-Supplied Synonyms

Copper(II) phosphateCupric phosphate7798-23-4UNII-N8NP6FR80RN8NP6FR80RTricopper bis(orthophosphate)Copper phosphate (Cu3(PO4)2)Copper phosphate (32)HSDB 267Phosphoric acid copper(2+) salt (23)Cupric phosphate (Cu3(PO4)2)Phosphoric acid copper(2+) saltcopper(ii)phosphate

EINECS 232-254-53Cu2PO4CTK3J2900DTXSID008725475341AFMFCD00036268AKOS015856691Phosphoric acidcopper(2+) salt (23)Q112356

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 521

3 Chemical and Physical Properties

31 Computed Properties

Property Name Property Value Reference

Molecular Weight 38058 gmol Computed by PubChem 21 (PubChem release 20190618)

Hydrogen Bond Donor Count 0 Computed by Cactvs 34611 (PubChem release 20190618)

Hydrogen Bond Acceptor Count 8 Computed by Cactvs 34611 (PubChem release 20190618)

Rotatable Bond Count 0 Computed by Cactvs 34611 (PubChem release 20190618)

Exact Mass 38069382 gmol Computed by PubChem 21 (PubChem release 20190618)

Monoisotopic Mass 37869563 gmol Computed by PubChem 21 (PubChem release 20190618)

Topological Polar Surface Area 173 Aringsup2 Computed by Cactvs 34611 (PubChem release 20190618)

Heavy Atom Count 13 Computed by PubChem

Formal Charge 0 Computed by PubChem

Complexity 368 Computed by Cactvs 34611 (PubChem release 20190618)

Isotope Atom Count 0 Computed by PubChem

Defined Atom Stereocenter Count 0 Computed by PubChem

Undefined Atom Stereocenter Count 0 Computed by PubChem

Defined Bond Stereocenter Count 0 Computed by PubChem

Undefined Bond Stereocenter Count 0 Computed by PubChem

Covalently-Bonded Unit Count 5 Computed by PubChem

Compound Is Canonicalized Yes Computed by PubChem (release 20190104)

PubChem

32 Experimental Properties

321 ColorForm

SOLID BLUISH-GREEN POWDERSax NI Dangerous Properties of Industrial Materials 4th ed New York Van Nostrand Reinhold 1975 p 576

Hazardous Substances Data Bank (HSDB)

Light blue powderGerhartz W (exec ed) Ullmanns Encyclopedia of Industrial Chemistry 5th edVol A1 Deerfield Beach FL VCH Publishers 1985 to Present p VA7(1986) 585

Hazardous Substances Data Bank (HSDB)

322 Solubility

Insoluble in cold water slightly soluble in hot water and soluble in ammonia solution and mineral acidsGerhartz W (exec ed) Ullmanns Encyclopedia of Industrial Chemistry 5th edVol A1 Deerfield Beach FL VCH Publishers 1985 to Present p VA7(1986) 585

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 621

323 Decomposition

DANGEROUS WHEN HEATED TO DECOMPOSITION CAN EMIT HIGHLY TOXIC FUMES OF PHOSPHORUS OXIDESPHOSPHATES

Sax NI Dangerous Properties of Industrial Materials 4th ed New York Van Nostrand Reinhold 1975 p 1021

Hazardous Substances Data Bank (HSDB)

324 Other Experimental Properties

Blue or olive orthorhombic crystals or blue to bluish green powder decomposes on heating practically insol in cold waterslightly sol in hot water sol in acids ammonium hydroxide Cupric phosphate trihydrate

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

MF Cu3(PO4)23H2O MW 43463 COFO blue rhombic crystals Solubility sol in water acid ammonium hydroxide slightlysoluble in acetone insoluble in ethanol Copper(II) phosphate trihydrate

Lide DR (ed) CRC Handbook of Chemistry and Physics 79th ed Boca Raton FL CRC Press Inc 1998-1999 p 4-56

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 721

4 Related Records

41 Related Compounds with Annotation

PubChem

42 Component Compounds

CID 23978 (Copper)

CID 1004 (Phosphoric acid)

PubChem

43 Related CompoundsMixtures Components andNeutralized Forms 2 Records

Similar Compounds 12 Records

PubChem

44 Substances

441 Related Substances

Same 34 Records

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 821

442 Substances by Category

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 921

5 Chemical Vendors

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1021

6 Drug and Medication Information

61 Therapeutic Uses

MEDICATION (VET) TRACE MINERAL ADDED TO ANIMAL FEEDSSax NI Dangerous Properties of Industrial Materials 4th ed New York Van Nostrand Reinhold 1975 p 576

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1121

7 Use and Manufacturing

71 Uses

Fungicide catalyst for org reactions fertilizer emulsifier corrosion inhibitor for phosphoric acid protectant for metal surfacesagainst oxidation

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

Fungicide formerGerhartz W (exec ed) Ullmanns Encyclopedia of Industrial Chemistry 5th edVol A1 Deerfield Beach FL VCH Publishers 1985 to Present p VA7(1986) 585

Hazardous Substances Data Bank (HSDB)

MEDICATION

Hazardous Substances Data Bank (HSDB)

MEDICATION (VET)

Hazardous Substances Data Bank (HSDB)

72 Methods of Manufacturing

Preparation from copper sulfate and diammonium hydrogen phosphate Klement Haselbeck Z Anorg Allgem Chem 334 27(1964)

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

Prepared by reaction of copper(II) sulfate solution with soluble alkali phosphatesGerhartz W (exec ed) Ullmanns Encyclopedia of Industrial Chemistry 5th edVol A1 Deerfield Beach FL VCH Publishers 1985 to Present p VA7(1986) 585

Hazardous Substances Data Bank (HSDB)

73 General Manufacturing Information

EPA TSCA Commercial Activity Status

Phosphoric acid copper(2+) salt (23) ACTIVEhttpswwwepagovtsca-inventory

EPA Chemicals under the TSCA

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1221

8 Safety and Hazards

81 Hazards Identification

811 GHS Classification

Pictogram(s)

Signal Warning

GHS Hazard Statements

Aggregated GHS information provided by 13 companies from 5 notifications to the ECHA CampL Inventory Eachnotification may be associated with multiple companies

H302 (3077) Harmful if swallowed [Warning Acute toxicity oral]

H315 (3077) Causes skin irritation [Warning Skin corrosionirritation]

H319 (2308) Causes serious eye irritation [Warning Serious eye damageeye irritation]

H335 (2308) May cause respiratory irritation [Warning Specific target organ toxicity single exposureRespiratory tract irritation]

H410 (1538) Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquaticenvironment long-term hazard]

H412 (3077) Harmful to aquatic life with long lasting effects [Hazardous to the aquatic environment long-term hazard]

Information may vary between notifications depending on impurities additives and other factors Thepercentage value in parenthesis indicates the notified classification ratio from companies that provide hazardcodes Only hazard codes with percentage values above 10 are shown

Precautionary StatementCodes

P261 P264 P270 P271 P273 P280 P301+P312 P302+P352 P304+P340 P305+P351+P338 P312 P321P330 P332+P313 P337+P313 P362 P391 P403+P233 P405 and P501

(The corresponding statement to each P-code can be found at the GHS Classification page)

European Chemicals Agency (ECHA)

812 Hazard Classes and Categories

Skin Irrit 2 (3077)

Eye Irrit 2 (2308)

STOT SE 3 (2308)

Aquatic Chronic 1 (1538)

Aquatic Chronic 3 (3077)

European Chemicals Agency (ECHA)

82 Safety and Hazard Properties

821 NIOSH Recommendations

Recommended Exposure Limit 10 Hr Time-Weighted Avg 1 mgcu m Copper (dusts and mists)NIOSH NIOSH Pocket Guide to Chemical Hazards DHHS (NIOSH) Publication No 97-140 Washington DC US Government Printing Office1997 p 76

IrritantEnvironmental

Hazard

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1321

Hazardous Substances Data Bank (HSDB)

83 Accidental Release Measures

831 Disposal Methods

SRP At the time of review criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significantrevision Prior to implementing land disposal of waste residue (including waste sludge) consult with environmental regulatoryagencies for guidance on acceptable disposal practices

Hazardous Substances Data Bank (HSDB)

Group III Containers (both combustible and non-combustible) that previously held organic mercury lead cadmium arsenic orinorganic pesticides should be triple rinsed punctured and disposed of in a sanitary landfill Non-rinsed containers should beencapsulated and buried at a specially designated landfill site Organic mercury lead cadmium arsenic or inorganicpesticides

40 CFR 165 (7188)

Hazardous Substances Data Bank (HSDB)

84 Exposure Control and Personal Protection

841 Threshold Limit Values (TLV)

8 hr Time Weighted Avg (TWA) 1 mgcu m Copper dusts and mists as CuAmerican Conference of Governmental Industrial Hygienists TLVs and BEIs Threshold Limit Values for Chemical Substances and Physical Agentsand Biological Exposure Indices Cincinnati OH 2008 p 21

Hazardous Substances Data Bank (HSDB)

Excursion Limit Recommendation Excursions in worker exposure levels may exceed 3 times the TLV-TWA for no more than atotal of 30 minutes during a work day and under no circumstances should they exceed 5 times the TLV-TWA provided that theTLV-TWA is not exceeded Copper dusts and mists as Cu

American Conference of Governmental Industrial Hygienists TLVs and BEIs Threshold Limit Values for Chemical Substances and Physical Agentsand Biological Exposure Indices Cincinnati OH 2008 p 5

Hazardous Substances Data Bank (HSDB)

842 Acceptable Daily Intakes

The available human data indicate that gastrointestinal distress occurred following ingestion of solutions that contained 5-7 mgof copper and other unknown chemicals as a single dose These data were used to derive a 1 day health advisory of 13 mglwhich when spread over a day should provide protection from these acute effects Since the effects appear to be local irritationthis health advisory is recommended for both the child and the adult There are no data indicating that human exposure tocopper results in chronic toxic effects Furthermore there is a nutritional requirement for copper and acute effects appear to bethe effects of concern Therefore the one day health advisory 13 mgl will also be used as the adjustable acceptable dailyintake Copper

USEPA Drinking Water Criteria Document for Copper (Final Draft) pI-2 (1985) EPA-600X-84-190-1

Hazardous Substances Data Bank (HSDB)

85 Stability and Reactivity

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1421

851 Hazardous Reactivities and Incompatibilities

Solutions of sodium hypobromite are decomposed by powerful catalytic action of cupric ions even as impurities Cupric saltsFire Protection Guide to Hazardous Materials 12 ed Quincy MA National Fire Protection Association 1997 p 491-181

Hazardous Substances Data Bank (HSDB)

86 Regulatory Information

861 Federal Drinking Water Standards

EPA 1300 ugl (Action Level) CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

862 Federal Drinking Water Guidelines

EPA 1000 ugl CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

863 State Drinking Water Guidelines

(AZ) ARIZONA 1300 ugl CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

864 Clean Water Act Requirements

Toxic pollutant designated pursuant to section 307(a)(1) of the Federal Water Pollution Control Act and is subject to effluentlimitations Copper and cmpd

40 CFR 40115 (712000)

Hazardous Substances Data Bank (HSDB)

87 Other Safety Information

871 Toxic Combustion Products

DANGEROUS WHEN HEATED TO DECOMPOSITION CAN EMIT HIGHLY TOXIC FUMES OF PO(X) PHOSPHATESSax NI Dangerous Properties of Industrial Materials 4th ed New York Van Nostrand Reinhold 1975 p 1021

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1521

9 Toxicity

91 Toxicological Information

911 Antidote and Emergency Treatment

Basic treatment Establish a patent airway Suction if necessary Watch for signs of respiratory insufficiency and assist ventilationsif necessary Administer oxygen by nonrebreather mask at 10 to 15 Lmin Monitor for shock and treat if necessary For eyecontamination flush eyes immediately with water Irrigate each eye continuously with normal saline during transport Do notuse emetics For ingestion rinse mouth and administer 5 mlkg up to 200 ml of water for dilution if the patient can swallow hasa strong gag reflex and does not drool Administer activated charcoal Copper and related compounds

Bronstein AC PL Currance Emergency Care for Hazardous Materials Exposure 2nd ed St Louis MO Mosby Lifeline 1994 p 350

Hazardous Substances Data Bank (HSDB)

Advanced treatment Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious Startan IV with lactated Ringers SRP To keep open minimal flow rate Watch for signs of fluid overload For hypotension withsigns of hypovolemia administer fluid cautiously Consider vasopressors if hypotensive with a normal fluid volume Watch forsigns of fluid overload Use proparacaine hydrochloride to assist eye irrigation Copper and related compounds

Bronstein AC PL Currance Emergency Care for Hazardous Materials Exposure 2nd ed St Louis MO Mosby Lifeline 1994 p 351

Hazardous Substances Data Bank (HSDB)

92 Ecological Information

921 Natural Pollution Sources

Basic salts occur in nature as the minerals cornetite dihydrite libethenite phosphorochalcite pseudolibethenitepseudomalachite tagilite

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1621

10 Literature

101 Springer Nature References

Springer Nature

102 Chemical Co-Occurrences in Literature

PubChem

103 Chemical-Gene Co-Occurrences in Literature

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1721

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1821

11 Patents

111 WIPO PATENTSCOPE

Patents are available for this chemical structure

httpspatentscopewipointsearchenresultjsfinchikey=GQDHEYWVLBJKBA-UHFFFAOYSA-H

PATENTSCOPE (WIPO)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1921

12 Classification

121 Ontologies

1211 ChemIDplus

ChemIDplus

1212 UN GHS Classification

UN Globally Harmonized System of Classification and Labelling of Chemicals (GHS)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2021

13 Information Sources

FILTER BY SOURCE

1 ChemIDplusLICENSEhttpswwwnlmnihgovcopyrighthtml

Copper(II) phosphatehttpschemnlmnihgovchemidplussid0007798234

ChemIDplus Chemical Information Classificationhttpschemnlmnihgovchemidplus

2 EPA Chemicals under the TSCALICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Phosphoric acid copper(2+) salt (23)httpswwwepagovchemicals-under-tsca

3 EPA DSSToxLICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Copper(II) phosphatehttpscomptoxepagovdashboardDTXSID00872547

4 European Chemicals Agency (ECHA)LICENSEUse of the information documents and data from the ECHA website is subject to the terms and conditions of this Legal Notice and subject to otherbinding limitations provided for under applicable law the information documents and data made available on the ECHA website may be reproduceddistributed andor used totally or in part for non-commercial purposes provided that ECHA is acknowledged as the source Source European ChemicalsAgency httpechaeuropaeu Such acknowledgement must be included in each copy of the material ECHA permits and encourages organisations andindividuals to create links to the ECHA website under the following cumulative conditions Links can only be made to webpages that provide a link to theLegal Notice pagehttpsechaeuropaeuwebguestlegal-notice

Tricopper bis(orthophosphate)httpsechaeuropaeusubstance-information-substanceinfo100029322

Tricopper bis(orthophosphate)httpsechaeuropaeuinformation-on-chemicalscl-inventory-database-disclidetails62531

5 Hazardous Substances Data Bank (HSDB)COPPER(II) PHOSPHATEhttpspubchemncbinlmnihgovsourcehsdb267

6 FDASPL Indexing DataLICENSEUnless otherwise noted the contents of the FDA website (wwwfdagov) both text and graphics are not copyrighted They are in the public domain andmay be republished reprinted and otherwise used freely by anyone without the need to obtain permission from FDA Credit to the US Food and DrugAdministration as the source is appreciated but not requiredhttpswwwfdagovabout-fdaabout-websitewebsite-policieslinking

N8NP6FR80RhttpswwwfdagovForIndustryDataStandardsSubstanceRegistrationSystem-UniqueIngredientIdentifierUNII

7 Springer Naturehttpspubchemncbinlmnihgovsubstance341378879

8 Wikipediafosfato de cobre (II)httpsenwikipediaorgwikiCopper(II)_phosphate

ALL SOURCES

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2121

9 PubChemhttpspubchemncbinlmnihgov

10 Sistema Globalmente Armonizado de Clasificacioacuten y Etiquetado de Productos Quiacutemicos(GHS) de las Naciones UnidasAacuterbol de clasificacioacuten GHShttpwwwuneceorgtransdangerpublighsghs_welcome_ehtml

11 PATENTSCOPE (OMPI)SID 403419907httpspubchemncbinlmnihgovsubstance403419907

Page 4: Fosfato de cobre (II) - Universidad Veracruzana

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 421

232 Deprecated CAS

1913303-43-1

ChemIDplus

233 European Community (EC) Number

232-254-5

European Chemicals Agency (ECHA)

234 UNII

N8NP6FR80R

FDASPL Indexing Data

235 DSSTox Substance ID

DTXSID00872547

EPA DSSTox

236 Wikipedia

Copper(II) phosphate

Wikipedia

24 Synonyms

241 Depositor-Supplied Synonyms

Copper(II) phosphateCupric phosphate7798-23-4UNII-N8NP6FR80RN8NP6FR80RTricopper bis(orthophosphate)Copper phosphate (Cu3(PO4)2)Copper phosphate (32)HSDB 267Phosphoric acid copper(2+) salt (23)Cupric phosphate (Cu3(PO4)2)Phosphoric acid copper(2+) saltcopper(ii)phosphate

EINECS 232-254-53Cu2PO4CTK3J2900DTXSID008725475341AFMFCD00036268AKOS015856691Phosphoric acidcopper(2+) salt (23)Q112356

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 521

3 Chemical and Physical Properties

31 Computed Properties

Property Name Property Value Reference

Molecular Weight 38058 gmol Computed by PubChem 21 (PubChem release 20190618)

Hydrogen Bond Donor Count 0 Computed by Cactvs 34611 (PubChem release 20190618)

Hydrogen Bond Acceptor Count 8 Computed by Cactvs 34611 (PubChem release 20190618)

Rotatable Bond Count 0 Computed by Cactvs 34611 (PubChem release 20190618)

Exact Mass 38069382 gmol Computed by PubChem 21 (PubChem release 20190618)

Monoisotopic Mass 37869563 gmol Computed by PubChem 21 (PubChem release 20190618)

Topological Polar Surface Area 173 Aringsup2 Computed by Cactvs 34611 (PubChem release 20190618)

Heavy Atom Count 13 Computed by PubChem

Formal Charge 0 Computed by PubChem

Complexity 368 Computed by Cactvs 34611 (PubChem release 20190618)

Isotope Atom Count 0 Computed by PubChem

Defined Atom Stereocenter Count 0 Computed by PubChem

Undefined Atom Stereocenter Count 0 Computed by PubChem

Defined Bond Stereocenter Count 0 Computed by PubChem

Undefined Bond Stereocenter Count 0 Computed by PubChem

Covalently-Bonded Unit Count 5 Computed by PubChem

Compound Is Canonicalized Yes Computed by PubChem (release 20190104)

PubChem

32 Experimental Properties

321 ColorForm

SOLID BLUISH-GREEN POWDERSax NI Dangerous Properties of Industrial Materials 4th ed New York Van Nostrand Reinhold 1975 p 576

Hazardous Substances Data Bank (HSDB)

Light blue powderGerhartz W (exec ed) Ullmanns Encyclopedia of Industrial Chemistry 5th edVol A1 Deerfield Beach FL VCH Publishers 1985 to Present p VA7(1986) 585

Hazardous Substances Data Bank (HSDB)

322 Solubility

Insoluble in cold water slightly soluble in hot water and soluble in ammonia solution and mineral acidsGerhartz W (exec ed) Ullmanns Encyclopedia of Industrial Chemistry 5th edVol A1 Deerfield Beach FL VCH Publishers 1985 to Present p VA7(1986) 585

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 621

323 Decomposition

DANGEROUS WHEN HEATED TO DECOMPOSITION CAN EMIT HIGHLY TOXIC FUMES OF PHOSPHORUS OXIDESPHOSPHATES

Sax NI Dangerous Properties of Industrial Materials 4th ed New York Van Nostrand Reinhold 1975 p 1021

Hazardous Substances Data Bank (HSDB)

324 Other Experimental Properties

Blue or olive orthorhombic crystals or blue to bluish green powder decomposes on heating practically insol in cold waterslightly sol in hot water sol in acids ammonium hydroxide Cupric phosphate trihydrate

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

MF Cu3(PO4)23H2O MW 43463 COFO blue rhombic crystals Solubility sol in water acid ammonium hydroxide slightlysoluble in acetone insoluble in ethanol Copper(II) phosphate trihydrate

Lide DR (ed) CRC Handbook of Chemistry and Physics 79th ed Boca Raton FL CRC Press Inc 1998-1999 p 4-56

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 721

4 Related Records

41 Related Compounds with Annotation

PubChem

42 Component Compounds

CID 23978 (Copper)

CID 1004 (Phosphoric acid)

PubChem

43 Related CompoundsMixtures Components andNeutralized Forms 2 Records

Similar Compounds 12 Records

PubChem

44 Substances

441 Related Substances

Same 34 Records

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 821

442 Substances by Category

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 921

5 Chemical Vendors

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1021

6 Drug and Medication Information

61 Therapeutic Uses

MEDICATION (VET) TRACE MINERAL ADDED TO ANIMAL FEEDSSax NI Dangerous Properties of Industrial Materials 4th ed New York Van Nostrand Reinhold 1975 p 576

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1121

7 Use and Manufacturing

71 Uses

Fungicide catalyst for org reactions fertilizer emulsifier corrosion inhibitor for phosphoric acid protectant for metal surfacesagainst oxidation

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

Fungicide formerGerhartz W (exec ed) Ullmanns Encyclopedia of Industrial Chemistry 5th edVol A1 Deerfield Beach FL VCH Publishers 1985 to Present p VA7(1986) 585

Hazardous Substances Data Bank (HSDB)

MEDICATION

Hazardous Substances Data Bank (HSDB)

MEDICATION (VET)

Hazardous Substances Data Bank (HSDB)

72 Methods of Manufacturing

Preparation from copper sulfate and diammonium hydrogen phosphate Klement Haselbeck Z Anorg Allgem Chem 334 27(1964)

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

Prepared by reaction of copper(II) sulfate solution with soluble alkali phosphatesGerhartz W (exec ed) Ullmanns Encyclopedia of Industrial Chemistry 5th edVol A1 Deerfield Beach FL VCH Publishers 1985 to Present p VA7(1986) 585

Hazardous Substances Data Bank (HSDB)

73 General Manufacturing Information

EPA TSCA Commercial Activity Status

Phosphoric acid copper(2+) salt (23) ACTIVEhttpswwwepagovtsca-inventory

EPA Chemicals under the TSCA

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1221

8 Safety and Hazards

81 Hazards Identification

811 GHS Classification

Pictogram(s)

Signal Warning

GHS Hazard Statements

Aggregated GHS information provided by 13 companies from 5 notifications to the ECHA CampL Inventory Eachnotification may be associated with multiple companies

H302 (3077) Harmful if swallowed [Warning Acute toxicity oral]

H315 (3077) Causes skin irritation [Warning Skin corrosionirritation]

H319 (2308) Causes serious eye irritation [Warning Serious eye damageeye irritation]

H335 (2308) May cause respiratory irritation [Warning Specific target organ toxicity single exposureRespiratory tract irritation]

H410 (1538) Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquaticenvironment long-term hazard]

H412 (3077) Harmful to aquatic life with long lasting effects [Hazardous to the aquatic environment long-term hazard]

Information may vary between notifications depending on impurities additives and other factors Thepercentage value in parenthesis indicates the notified classification ratio from companies that provide hazardcodes Only hazard codes with percentage values above 10 are shown

Precautionary StatementCodes

P261 P264 P270 P271 P273 P280 P301+P312 P302+P352 P304+P340 P305+P351+P338 P312 P321P330 P332+P313 P337+P313 P362 P391 P403+P233 P405 and P501

(The corresponding statement to each P-code can be found at the GHS Classification page)

European Chemicals Agency (ECHA)

812 Hazard Classes and Categories

Skin Irrit 2 (3077)

Eye Irrit 2 (2308)

STOT SE 3 (2308)

Aquatic Chronic 1 (1538)

Aquatic Chronic 3 (3077)

European Chemicals Agency (ECHA)

82 Safety and Hazard Properties

821 NIOSH Recommendations

Recommended Exposure Limit 10 Hr Time-Weighted Avg 1 mgcu m Copper (dusts and mists)NIOSH NIOSH Pocket Guide to Chemical Hazards DHHS (NIOSH) Publication No 97-140 Washington DC US Government Printing Office1997 p 76

IrritantEnvironmental

Hazard

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1321

Hazardous Substances Data Bank (HSDB)

83 Accidental Release Measures

831 Disposal Methods

SRP At the time of review criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significantrevision Prior to implementing land disposal of waste residue (including waste sludge) consult with environmental regulatoryagencies for guidance on acceptable disposal practices

Hazardous Substances Data Bank (HSDB)

Group III Containers (both combustible and non-combustible) that previously held organic mercury lead cadmium arsenic orinorganic pesticides should be triple rinsed punctured and disposed of in a sanitary landfill Non-rinsed containers should beencapsulated and buried at a specially designated landfill site Organic mercury lead cadmium arsenic or inorganicpesticides

40 CFR 165 (7188)

Hazardous Substances Data Bank (HSDB)

84 Exposure Control and Personal Protection

841 Threshold Limit Values (TLV)

8 hr Time Weighted Avg (TWA) 1 mgcu m Copper dusts and mists as CuAmerican Conference of Governmental Industrial Hygienists TLVs and BEIs Threshold Limit Values for Chemical Substances and Physical Agentsand Biological Exposure Indices Cincinnati OH 2008 p 21

Hazardous Substances Data Bank (HSDB)

Excursion Limit Recommendation Excursions in worker exposure levels may exceed 3 times the TLV-TWA for no more than atotal of 30 minutes during a work day and under no circumstances should they exceed 5 times the TLV-TWA provided that theTLV-TWA is not exceeded Copper dusts and mists as Cu

American Conference of Governmental Industrial Hygienists TLVs and BEIs Threshold Limit Values for Chemical Substances and Physical Agentsand Biological Exposure Indices Cincinnati OH 2008 p 5

Hazardous Substances Data Bank (HSDB)

842 Acceptable Daily Intakes

The available human data indicate that gastrointestinal distress occurred following ingestion of solutions that contained 5-7 mgof copper and other unknown chemicals as a single dose These data were used to derive a 1 day health advisory of 13 mglwhich when spread over a day should provide protection from these acute effects Since the effects appear to be local irritationthis health advisory is recommended for both the child and the adult There are no data indicating that human exposure tocopper results in chronic toxic effects Furthermore there is a nutritional requirement for copper and acute effects appear to bethe effects of concern Therefore the one day health advisory 13 mgl will also be used as the adjustable acceptable dailyintake Copper

USEPA Drinking Water Criteria Document for Copper (Final Draft) pI-2 (1985) EPA-600X-84-190-1

Hazardous Substances Data Bank (HSDB)

85 Stability and Reactivity

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1421

851 Hazardous Reactivities and Incompatibilities

Solutions of sodium hypobromite are decomposed by powerful catalytic action of cupric ions even as impurities Cupric saltsFire Protection Guide to Hazardous Materials 12 ed Quincy MA National Fire Protection Association 1997 p 491-181

Hazardous Substances Data Bank (HSDB)

86 Regulatory Information

861 Federal Drinking Water Standards

EPA 1300 ugl (Action Level) CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

862 Federal Drinking Water Guidelines

EPA 1000 ugl CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

863 State Drinking Water Guidelines

(AZ) ARIZONA 1300 ugl CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

864 Clean Water Act Requirements

Toxic pollutant designated pursuant to section 307(a)(1) of the Federal Water Pollution Control Act and is subject to effluentlimitations Copper and cmpd

40 CFR 40115 (712000)

Hazardous Substances Data Bank (HSDB)

87 Other Safety Information

871 Toxic Combustion Products

DANGEROUS WHEN HEATED TO DECOMPOSITION CAN EMIT HIGHLY TOXIC FUMES OF PO(X) PHOSPHATESSax NI Dangerous Properties of Industrial Materials 4th ed New York Van Nostrand Reinhold 1975 p 1021

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1521

9 Toxicity

91 Toxicological Information

911 Antidote and Emergency Treatment

Basic treatment Establish a patent airway Suction if necessary Watch for signs of respiratory insufficiency and assist ventilationsif necessary Administer oxygen by nonrebreather mask at 10 to 15 Lmin Monitor for shock and treat if necessary For eyecontamination flush eyes immediately with water Irrigate each eye continuously with normal saline during transport Do notuse emetics For ingestion rinse mouth and administer 5 mlkg up to 200 ml of water for dilution if the patient can swallow hasa strong gag reflex and does not drool Administer activated charcoal Copper and related compounds

Bronstein AC PL Currance Emergency Care for Hazardous Materials Exposure 2nd ed St Louis MO Mosby Lifeline 1994 p 350

Hazardous Substances Data Bank (HSDB)

Advanced treatment Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious Startan IV with lactated Ringers SRP To keep open minimal flow rate Watch for signs of fluid overload For hypotension withsigns of hypovolemia administer fluid cautiously Consider vasopressors if hypotensive with a normal fluid volume Watch forsigns of fluid overload Use proparacaine hydrochloride to assist eye irrigation Copper and related compounds

Bronstein AC PL Currance Emergency Care for Hazardous Materials Exposure 2nd ed St Louis MO Mosby Lifeline 1994 p 351

Hazardous Substances Data Bank (HSDB)

92 Ecological Information

921 Natural Pollution Sources

Basic salts occur in nature as the minerals cornetite dihydrite libethenite phosphorochalcite pseudolibethenitepseudomalachite tagilite

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1621

10 Literature

101 Springer Nature References

Springer Nature

102 Chemical Co-Occurrences in Literature

PubChem

103 Chemical-Gene Co-Occurrences in Literature

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1721

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1821

11 Patents

111 WIPO PATENTSCOPE

Patents are available for this chemical structure

httpspatentscopewipointsearchenresultjsfinchikey=GQDHEYWVLBJKBA-UHFFFAOYSA-H

PATENTSCOPE (WIPO)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1921

12 Classification

121 Ontologies

1211 ChemIDplus

ChemIDplus

1212 UN GHS Classification

UN Globally Harmonized System of Classification and Labelling of Chemicals (GHS)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2021

13 Information Sources

FILTER BY SOURCE

1 ChemIDplusLICENSEhttpswwwnlmnihgovcopyrighthtml

Copper(II) phosphatehttpschemnlmnihgovchemidplussid0007798234

ChemIDplus Chemical Information Classificationhttpschemnlmnihgovchemidplus

2 EPA Chemicals under the TSCALICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Phosphoric acid copper(2+) salt (23)httpswwwepagovchemicals-under-tsca

3 EPA DSSToxLICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Copper(II) phosphatehttpscomptoxepagovdashboardDTXSID00872547

4 European Chemicals Agency (ECHA)LICENSEUse of the information documents and data from the ECHA website is subject to the terms and conditions of this Legal Notice and subject to otherbinding limitations provided for under applicable law the information documents and data made available on the ECHA website may be reproduceddistributed andor used totally or in part for non-commercial purposes provided that ECHA is acknowledged as the source Source European ChemicalsAgency httpechaeuropaeu Such acknowledgement must be included in each copy of the material ECHA permits and encourages organisations andindividuals to create links to the ECHA website under the following cumulative conditions Links can only be made to webpages that provide a link to theLegal Notice pagehttpsechaeuropaeuwebguestlegal-notice

Tricopper bis(orthophosphate)httpsechaeuropaeusubstance-information-substanceinfo100029322

Tricopper bis(orthophosphate)httpsechaeuropaeuinformation-on-chemicalscl-inventory-database-disclidetails62531

5 Hazardous Substances Data Bank (HSDB)COPPER(II) PHOSPHATEhttpspubchemncbinlmnihgovsourcehsdb267

6 FDASPL Indexing DataLICENSEUnless otherwise noted the contents of the FDA website (wwwfdagov) both text and graphics are not copyrighted They are in the public domain andmay be republished reprinted and otherwise used freely by anyone without the need to obtain permission from FDA Credit to the US Food and DrugAdministration as the source is appreciated but not requiredhttpswwwfdagovabout-fdaabout-websitewebsite-policieslinking

N8NP6FR80RhttpswwwfdagovForIndustryDataStandardsSubstanceRegistrationSystem-UniqueIngredientIdentifierUNII

7 Springer Naturehttpspubchemncbinlmnihgovsubstance341378879

8 Wikipediafosfato de cobre (II)httpsenwikipediaorgwikiCopper(II)_phosphate

ALL SOURCES

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2121

9 PubChemhttpspubchemncbinlmnihgov

10 Sistema Globalmente Armonizado de Clasificacioacuten y Etiquetado de Productos Quiacutemicos(GHS) de las Naciones UnidasAacuterbol de clasificacioacuten GHShttpwwwuneceorgtransdangerpublighsghs_welcome_ehtml

11 PATENTSCOPE (OMPI)SID 403419907httpspubchemncbinlmnihgovsubstance403419907

Page 5: Fosfato de cobre (II) - Universidad Veracruzana

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 521

3 Chemical and Physical Properties

31 Computed Properties

Property Name Property Value Reference

Molecular Weight 38058 gmol Computed by PubChem 21 (PubChem release 20190618)

Hydrogen Bond Donor Count 0 Computed by Cactvs 34611 (PubChem release 20190618)

Hydrogen Bond Acceptor Count 8 Computed by Cactvs 34611 (PubChem release 20190618)

Rotatable Bond Count 0 Computed by Cactvs 34611 (PubChem release 20190618)

Exact Mass 38069382 gmol Computed by PubChem 21 (PubChem release 20190618)

Monoisotopic Mass 37869563 gmol Computed by PubChem 21 (PubChem release 20190618)

Topological Polar Surface Area 173 Aringsup2 Computed by Cactvs 34611 (PubChem release 20190618)

Heavy Atom Count 13 Computed by PubChem

Formal Charge 0 Computed by PubChem

Complexity 368 Computed by Cactvs 34611 (PubChem release 20190618)

Isotope Atom Count 0 Computed by PubChem

Defined Atom Stereocenter Count 0 Computed by PubChem

Undefined Atom Stereocenter Count 0 Computed by PubChem

Defined Bond Stereocenter Count 0 Computed by PubChem

Undefined Bond Stereocenter Count 0 Computed by PubChem

Covalently-Bonded Unit Count 5 Computed by PubChem

Compound Is Canonicalized Yes Computed by PubChem (release 20190104)

PubChem

32 Experimental Properties

321 ColorForm

SOLID BLUISH-GREEN POWDERSax NI Dangerous Properties of Industrial Materials 4th ed New York Van Nostrand Reinhold 1975 p 576

Hazardous Substances Data Bank (HSDB)

Light blue powderGerhartz W (exec ed) Ullmanns Encyclopedia of Industrial Chemistry 5th edVol A1 Deerfield Beach FL VCH Publishers 1985 to Present p VA7(1986) 585

Hazardous Substances Data Bank (HSDB)

322 Solubility

Insoluble in cold water slightly soluble in hot water and soluble in ammonia solution and mineral acidsGerhartz W (exec ed) Ullmanns Encyclopedia of Industrial Chemistry 5th edVol A1 Deerfield Beach FL VCH Publishers 1985 to Present p VA7(1986) 585

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 621

323 Decomposition

DANGEROUS WHEN HEATED TO DECOMPOSITION CAN EMIT HIGHLY TOXIC FUMES OF PHOSPHORUS OXIDESPHOSPHATES

Sax NI Dangerous Properties of Industrial Materials 4th ed New York Van Nostrand Reinhold 1975 p 1021

Hazardous Substances Data Bank (HSDB)

324 Other Experimental Properties

Blue or olive orthorhombic crystals or blue to bluish green powder decomposes on heating practically insol in cold waterslightly sol in hot water sol in acids ammonium hydroxide Cupric phosphate trihydrate

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

MF Cu3(PO4)23H2O MW 43463 COFO blue rhombic crystals Solubility sol in water acid ammonium hydroxide slightlysoluble in acetone insoluble in ethanol Copper(II) phosphate trihydrate

Lide DR (ed) CRC Handbook of Chemistry and Physics 79th ed Boca Raton FL CRC Press Inc 1998-1999 p 4-56

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 721

4 Related Records

41 Related Compounds with Annotation

PubChem

42 Component Compounds

CID 23978 (Copper)

CID 1004 (Phosphoric acid)

PubChem

43 Related CompoundsMixtures Components andNeutralized Forms 2 Records

Similar Compounds 12 Records

PubChem

44 Substances

441 Related Substances

Same 34 Records

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 821

442 Substances by Category

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 921

5 Chemical Vendors

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1021

6 Drug and Medication Information

61 Therapeutic Uses

MEDICATION (VET) TRACE MINERAL ADDED TO ANIMAL FEEDSSax NI Dangerous Properties of Industrial Materials 4th ed New York Van Nostrand Reinhold 1975 p 576

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1121

7 Use and Manufacturing

71 Uses

Fungicide catalyst for org reactions fertilizer emulsifier corrosion inhibitor for phosphoric acid protectant for metal surfacesagainst oxidation

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

Fungicide formerGerhartz W (exec ed) Ullmanns Encyclopedia of Industrial Chemistry 5th edVol A1 Deerfield Beach FL VCH Publishers 1985 to Present p VA7(1986) 585

Hazardous Substances Data Bank (HSDB)

MEDICATION

Hazardous Substances Data Bank (HSDB)

MEDICATION (VET)

Hazardous Substances Data Bank (HSDB)

72 Methods of Manufacturing

Preparation from copper sulfate and diammonium hydrogen phosphate Klement Haselbeck Z Anorg Allgem Chem 334 27(1964)

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

Prepared by reaction of copper(II) sulfate solution with soluble alkali phosphatesGerhartz W (exec ed) Ullmanns Encyclopedia of Industrial Chemistry 5th edVol A1 Deerfield Beach FL VCH Publishers 1985 to Present p VA7(1986) 585

Hazardous Substances Data Bank (HSDB)

73 General Manufacturing Information

EPA TSCA Commercial Activity Status

Phosphoric acid copper(2+) salt (23) ACTIVEhttpswwwepagovtsca-inventory

EPA Chemicals under the TSCA

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1221

8 Safety and Hazards

81 Hazards Identification

811 GHS Classification

Pictogram(s)

Signal Warning

GHS Hazard Statements

Aggregated GHS information provided by 13 companies from 5 notifications to the ECHA CampL Inventory Eachnotification may be associated with multiple companies

H302 (3077) Harmful if swallowed [Warning Acute toxicity oral]

H315 (3077) Causes skin irritation [Warning Skin corrosionirritation]

H319 (2308) Causes serious eye irritation [Warning Serious eye damageeye irritation]

H335 (2308) May cause respiratory irritation [Warning Specific target organ toxicity single exposureRespiratory tract irritation]

H410 (1538) Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquaticenvironment long-term hazard]

H412 (3077) Harmful to aquatic life with long lasting effects [Hazardous to the aquatic environment long-term hazard]

Information may vary between notifications depending on impurities additives and other factors Thepercentage value in parenthesis indicates the notified classification ratio from companies that provide hazardcodes Only hazard codes with percentage values above 10 are shown

Precautionary StatementCodes

P261 P264 P270 P271 P273 P280 P301+P312 P302+P352 P304+P340 P305+P351+P338 P312 P321P330 P332+P313 P337+P313 P362 P391 P403+P233 P405 and P501

(The corresponding statement to each P-code can be found at the GHS Classification page)

European Chemicals Agency (ECHA)

812 Hazard Classes and Categories

Skin Irrit 2 (3077)

Eye Irrit 2 (2308)

STOT SE 3 (2308)

Aquatic Chronic 1 (1538)

Aquatic Chronic 3 (3077)

European Chemicals Agency (ECHA)

82 Safety and Hazard Properties

821 NIOSH Recommendations

Recommended Exposure Limit 10 Hr Time-Weighted Avg 1 mgcu m Copper (dusts and mists)NIOSH NIOSH Pocket Guide to Chemical Hazards DHHS (NIOSH) Publication No 97-140 Washington DC US Government Printing Office1997 p 76

IrritantEnvironmental

Hazard

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1321

Hazardous Substances Data Bank (HSDB)

83 Accidental Release Measures

831 Disposal Methods

SRP At the time of review criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significantrevision Prior to implementing land disposal of waste residue (including waste sludge) consult with environmental regulatoryagencies for guidance on acceptable disposal practices

Hazardous Substances Data Bank (HSDB)

Group III Containers (both combustible and non-combustible) that previously held organic mercury lead cadmium arsenic orinorganic pesticides should be triple rinsed punctured and disposed of in a sanitary landfill Non-rinsed containers should beencapsulated and buried at a specially designated landfill site Organic mercury lead cadmium arsenic or inorganicpesticides

40 CFR 165 (7188)

Hazardous Substances Data Bank (HSDB)

84 Exposure Control and Personal Protection

841 Threshold Limit Values (TLV)

8 hr Time Weighted Avg (TWA) 1 mgcu m Copper dusts and mists as CuAmerican Conference of Governmental Industrial Hygienists TLVs and BEIs Threshold Limit Values for Chemical Substances and Physical Agentsand Biological Exposure Indices Cincinnati OH 2008 p 21

Hazardous Substances Data Bank (HSDB)

Excursion Limit Recommendation Excursions in worker exposure levels may exceed 3 times the TLV-TWA for no more than atotal of 30 minutes during a work day and under no circumstances should they exceed 5 times the TLV-TWA provided that theTLV-TWA is not exceeded Copper dusts and mists as Cu

American Conference of Governmental Industrial Hygienists TLVs and BEIs Threshold Limit Values for Chemical Substances and Physical Agentsand Biological Exposure Indices Cincinnati OH 2008 p 5

Hazardous Substances Data Bank (HSDB)

842 Acceptable Daily Intakes

The available human data indicate that gastrointestinal distress occurred following ingestion of solutions that contained 5-7 mgof copper and other unknown chemicals as a single dose These data were used to derive a 1 day health advisory of 13 mglwhich when spread over a day should provide protection from these acute effects Since the effects appear to be local irritationthis health advisory is recommended for both the child and the adult There are no data indicating that human exposure tocopper results in chronic toxic effects Furthermore there is a nutritional requirement for copper and acute effects appear to bethe effects of concern Therefore the one day health advisory 13 mgl will also be used as the adjustable acceptable dailyintake Copper

USEPA Drinking Water Criteria Document for Copper (Final Draft) pI-2 (1985) EPA-600X-84-190-1

Hazardous Substances Data Bank (HSDB)

85 Stability and Reactivity

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1421

851 Hazardous Reactivities and Incompatibilities

Solutions of sodium hypobromite are decomposed by powerful catalytic action of cupric ions even as impurities Cupric saltsFire Protection Guide to Hazardous Materials 12 ed Quincy MA National Fire Protection Association 1997 p 491-181

Hazardous Substances Data Bank (HSDB)

86 Regulatory Information

861 Federal Drinking Water Standards

EPA 1300 ugl (Action Level) CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

862 Federal Drinking Water Guidelines

EPA 1000 ugl CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

863 State Drinking Water Guidelines

(AZ) ARIZONA 1300 ugl CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

864 Clean Water Act Requirements

Toxic pollutant designated pursuant to section 307(a)(1) of the Federal Water Pollution Control Act and is subject to effluentlimitations Copper and cmpd

40 CFR 40115 (712000)

Hazardous Substances Data Bank (HSDB)

87 Other Safety Information

871 Toxic Combustion Products

DANGEROUS WHEN HEATED TO DECOMPOSITION CAN EMIT HIGHLY TOXIC FUMES OF PO(X) PHOSPHATESSax NI Dangerous Properties of Industrial Materials 4th ed New York Van Nostrand Reinhold 1975 p 1021

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1521

9 Toxicity

91 Toxicological Information

911 Antidote and Emergency Treatment

Basic treatment Establish a patent airway Suction if necessary Watch for signs of respiratory insufficiency and assist ventilationsif necessary Administer oxygen by nonrebreather mask at 10 to 15 Lmin Monitor for shock and treat if necessary For eyecontamination flush eyes immediately with water Irrigate each eye continuously with normal saline during transport Do notuse emetics For ingestion rinse mouth and administer 5 mlkg up to 200 ml of water for dilution if the patient can swallow hasa strong gag reflex and does not drool Administer activated charcoal Copper and related compounds

Bronstein AC PL Currance Emergency Care for Hazardous Materials Exposure 2nd ed St Louis MO Mosby Lifeline 1994 p 350

Hazardous Substances Data Bank (HSDB)

Advanced treatment Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious Startan IV with lactated Ringers SRP To keep open minimal flow rate Watch for signs of fluid overload For hypotension withsigns of hypovolemia administer fluid cautiously Consider vasopressors if hypotensive with a normal fluid volume Watch forsigns of fluid overload Use proparacaine hydrochloride to assist eye irrigation Copper and related compounds

Bronstein AC PL Currance Emergency Care for Hazardous Materials Exposure 2nd ed St Louis MO Mosby Lifeline 1994 p 351

Hazardous Substances Data Bank (HSDB)

92 Ecological Information

921 Natural Pollution Sources

Basic salts occur in nature as the minerals cornetite dihydrite libethenite phosphorochalcite pseudolibethenitepseudomalachite tagilite

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1621

10 Literature

101 Springer Nature References

Springer Nature

102 Chemical Co-Occurrences in Literature

PubChem

103 Chemical-Gene Co-Occurrences in Literature

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1721

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1821

11 Patents

111 WIPO PATENTSCOPE

Patents are available for this chemical structure

httpspatentscopewipointsearchenresultjsfinchikey=GQDHEYWVLBJKBA-UHFFFAOYSA-H

PATENTSCOPE (WIPO)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1921

12 Classification

121 Ontologies

1211 ChemIDplus

ChemIDplus

1212 UN GHS Classification

UN Globally Harmonized System of Classification and Labelling of Chemicals (GHS)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2021

13 Information Sources

FILTER BY SOURCE

1 ChemIDplusLICENSEhttpswwwnlmnihgovcopyrighthtml

Copper(II) phosphatehttpschemnlmnihgovchemidplussid0007798234

ChemIDplus Chemical Information Classificationhttpschemnlmnihgovchemidplus

2 EPA Chemicals under the TSCALICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Phosphoric acid copper(2+) salt (23)httpswwwepagovchemicals-under-tsca

3 EPA DSSToxLICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Copper(II) phosphatehttpscomptoxepagovdashboardDTXSID00872547

4 European Chemicals Agency (ECHA)LICENSEUse of the information documents and data from the ECHA website is subject to the terms and conditions of this Legal Notice and subject to otherbinding limitations provided for under applicable law the information documents and data made available on the ECHA website may be reproduceddistributed andor used totally or in part for non-commercial purposes provided that ECHA is acknowledged as the source Source European ChemicalsAgency httpechaeuropaeu Such acknowledgement must be included in each copy of the material ECHA permits and encourages organisations andindividuals to create links to the ECHA website under the following cumulative conditions Links can only be made to webpages that provide a link to theLegal Notice pagehttpsechaeuropaeuwebguestlegal-notice

Tricopper bis(orthophosphate)httpsechaeuropaeusubstance-information-substanceinfo100029322

Tricopper bis(orthophosphate)httpsechaeuropaeuinformation-on-chemicalscl-inventory-database-disclidetails62531

5 Hazardous Substances Data Bank (HSDB)COPPER(II) PHOSPHATEhttpspubchemncbinlmnihgovsourcehsdb267

6 FDASPL Indexing DataLICENSEUnless otherwise noted the contents of the FDA website (wwwfdagov) both text and graphics are not copyrighted They are in the public domain andmay be republished reprinted and otherwise used freely by anyone without the need to obtain permission from FDA Credit to the US Food and DrugAdministration as the source is appreciated but not requiredhttpswwwfdagovabout-fdaabout-websitewebsite-policieslinking

N8NP6FR80RhttpswwwfdagovForIndustryDataStandardsSubstanceRegistrationSystem-UniqueIngredientIdentifierUNII

7 Springer Naturehttpspubchemncbinlmnihgovsubstance341378879

8 Wikipediafosfato de cobre (II)httpsenwikipediaorgwikiCopper(II)_phosphate

ALL SOURCES

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2121

9 PubChemhttpspubchemncbinlmnihgov

10 Sistema Globalmente Armonizado de Clasificacioacuten y Etiquetado de Productos Quiacutemicos(GHS) de las Naciones UnidasAacuterbol de clasificacioacuten GHShttpwwwuneceorgtransdangerpublighsghs_welcome_ehtml

11 PATENTSCOPE (OMPI)SID 403419907httpspubchemncbinlmnihgovsubstance403419907

Page 6: Fosfato de cobre (II) - Universidad Veracruzana

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 621

323 Decomposition

DANGEROUS WHEN HEATED TO DECOMPOSITION CAN EMIT HIGHLY TOXIC FUMES OF PHOSPHORUS OXIDESPHOSPHATES

Sax NI Dangerous Properties of Industrial Materials 4th ed New York Van Nostrand Reinhold 1975 p 1021

Hazardous Substances Data Bank (HSDB)

324 Other Experimental Properties

Blue or olive orthorhombic crystals or blue to bluish green powder decomposes on heating practically insol in cold waterslightly sol in hot water sol in acids ammonium hydroxide Cupric phosphate trihydrate

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

MF Cu3(PO4)23H2O MW 43463 COFO blue rhombic crystals Solubility sol in water acid ammonium hydroxide slightlysoluble in acetone insoluble in ethanol Copper(II) phosphate trihydrate

Lide DR (ed) CRC Handbook of Chemistry and Physics 79th ed Boca Raton FL CRC Press Inc 1998-1999 p 4-56

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 721

4 Related Records

41 Related Compounds with Annotation

PubChem

42 Component Compounds

CID 23978 (Copper)

CID 1004 (Phosphoric acid)

PubChem

43 Related CompoundsMixtures Components andNeutralized Forms 2 Records

Similar Compounds 12 Records

PubChem

44 Substances

441 Related Substances

Same 34 Records

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 821

442 Substances by Category

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 921

5 Chemical Vendors

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1021

6 Drug and Medication Information

61 Therapeutic Uses

MEDICATION (VET) TRACE MINERAL ADDED TO ANIMAL FEEDSSax NI Dangerous Properties of Industrial Materials 4th ed New York Van Nostrand Reinhold 1975 p 576

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1121

7 Use and Manufacturing

71 Uses

Fungicide catalyst for org reactions fertilizer emulsifier corrosion inhibitor for phosphoric acid protectant for metal surfacesagainst oxidation

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

Fungicide formerGerhartz W (exec ed) Ullmanns Encyclopedia of Industrial Chemistry 5th edVol A1 Deerfield Beach FL VCH Publishers 1985 to Present p VA7(1986) 585

Hazardous Substances Data Bank (HSDB)

MEDICATION

Hazardous Substances Data Bank (HSDB)

MEDICATION (VET)

Hazardous Substances Data Bank (HSDB)

72 Methods of Manufacturing

Preparation from copper sulfate and diammonium hydrogen phosphate Klement Haselbeck Z Anorg Allgem Chem 334 27(1964)

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

Prepared by reaction of copper(II) sulfate solution with soluble alkali phosphatesGerhartz W (exec ed) Ullmanns Encyclopedia of Industrial Chemistry 5th edVol A1 Deerfield Beach FL VCH Publishers 1985 to Present p VA7(1986) 585

Hazardous Substances Data Bank (HSDB)

73 General Manufacturing Information

EPA TSCA Commercial Activity Status

Phosphoric acid copper(2+) salt (23) ACTIVEhttpswwwepagovtsca-inventory

EPA Chemicals under the TSCA

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1221

8 Safety and Hazards

81 Hazards Identification

811 GHS Classification

Pictogram(s)

Signal Warning

GHS Hazard Statements

Aggregated GHS information provided by 13 companies from 5 notifications to the ECHA CampL Inventory Eachnotification may be associated with multiple companies

H302 (3077) Harmful if swallowed [Warning Acute toxicity oral]

H315 (3077) Causes skin irritation [Warning Skin corrosionirritation]

H319 (2308) Causes serious eye irritation [Warning Serious eye damageeye irritation]

H335 (2308) May cause respiratory irritation [Warning Specific target organ toxicity single exposureRespiratory tract irritation]

H410 (1538) Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquaticenvironment long-term hazard]

H412 (3077) Harmful to aquatic life with long lasting effects [Hazardous to the aquatic environment long-term hazard]

Information may vary between notifications depending on impurities additives and other factors Thepercentage value in parenthesis indicates the notified classification ratio from companies that provide hazardcodes Only hazard codes with percentage values above 10 are shown

Precautionary StatementCodes

P261 P264 P270 P271 P273 P280 P301+P312 P302+P352 P304+P340 P305+P351+P338 P312 P321P330 P332+P313 P337+P313 P362 P391 P403+P233 P405 and P501

(The corresponding statement to each P-code can be found at the GHS Classification page)

European Chemicals Agency (ECHA)

812 Hazard Classes and Categories

Skin Irrit 2 (3077)

Eye Irrit 2 (2308)

STOT SE 3 (2308)

Aquatic Chronic 1 (1538)

Aquatic Chronic 3 (3077)

European Chemicals Agency (ECHA)

82 Safety and Hazard Properties

821 NIOSH Recommendations

Recommended Exposure Limit 10 Hr Time-Weighted Avg 1 mgcu m Copper (dusts and mists)NIOSH NIOSH Pocket Guide to Chemical Hazards DHHS (NIOSH) Publication No 97-140 Washington DC US Government Printing Office1997 p 76

IrritantEnvironmental

Hazard

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1321

Hazardous Substances Data Bank (HSDB)

83 Accidental Release Measures

831 Disposal Methods

SRP At the time of review criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significantrevision Prior to implementing land disposal of waste residue (including waste sludge) consult with environmental regulatoryagencies for guidance on acceptable disposal practices

Hazardous Substances Data Bank (HSDB)

Group III Containers (both combustible and non-combustible) that previously held organic mercury lead cadmium arsenic orinorganic pesticides should be triple rinsed punctured and disposed of in a sanitary landfill Non-rinsed containers should beencapsulated and buried at a specially designated landfill site Organic mercury lead cadmium arsenic or inorganicpesticides

40 CFR 165 (7188)

Hazardous Substances Data Bank (HSDB)

84 Exposure Control and Personal Protection

841 Threshold Limit Values (TLV)

8 hr Time Weighted Avg (TWA) 1 mgcu m Copper dusts and mists as CuAmerican Conference of Governmental Industrial Hygienists TLVs and BEIs Threshold Limit Values for Chemical Substances and Physical Agentsand Biological Exposure Indices Cincinnati OH 2008 p 21

Hazardous Substances Data Bank (HSDB)

Excursion Limit Recommendation Excursions in worker exposure levels may exceed 3 times the TLV-TWA for no more than atotal of 30 minutes during a work day and under no circumstances should they exceed 5 times the TLV-TWA provided that theTLV-TWA is not exceeded Copper dusts and mists as Cu

American Conference of Governmental Industrial Hygienists TLVs and BEIs Threshold Limit Values for Chemical Substances and Physical Agentsand Biological Exposure Indices Cincinnati OH 2008 p 5

Hazardous Substances Data Bank (HSDB)

842 Acceptable Daily Intakes

The available human data indicate that gastrointestinal distress occurred following ingestion of solutions that contained 5-7 mgof copper and other unknown chemicals as a single dose These data were used to derive a 1 day health advisory of 13 mglwhich when spread over a day should provide protection from these acute effects Since the effects appear to be local irritationthis health advisory is recommended for both the child and the adult There are no data indicating that human exposure tocopper results in chronic toxic effects Furthermore there is a nutritional requirement for copper and acute effects appear to bethe effects of concern Therefore the one day health advisory 13 mgl will also be used as the adjustable acceptable dailyintake Copper

USEPA Drinking Water Criteria Document for Copper (Final Draft) pI-2 (1985) EPA-600X-84-190-1

Hazardous Substances Data Bank (HSDB)

85 Stability and Reactivity

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1421

851 Hazardous Reactivities and Incompatibilities

Solutions of sodium hypobromite are decomposed by powerful catalytic action of cupric ions even as impurities Cupric saltsFire Protection Guide to Hazardous Materials 12 ed Quincy MA National Fire Protection Association 1997 p 491-181

Hazardous Substances Data Bank (HSDB)

86 Regulatory Information

861 Federal Drinking Water Standards

EPA 1300 ugl (Action Level) CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

862 Federal Drinking Water Guidelines

EPA 1000 ugl CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

863 State Drinking Water Guidelines

(AZ) ARIZONA 1300 ugl CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

864 Clean Water Act Requirements

Toxic pollutant designated pursuant to section 307(a)(1) of the Federal Water Pollution Control Act and is subject to effluentlimitations Copper and cmpd

40 CFR 40115 (712000)

Hazardous Substances Data Bank (HSDB)

87 Other Safety Information

871 Toxic Combustion Products

DANGEROUS WHEN HEATED TO DECOMPOSITION CAN EMIT HIGHLY TOXIC FUMES OF PO(X) PHOSPHATESSax NI Dangerous Properties of Industrial Materials 4th ed New York Van Nostrand Reinhold 1975 p 1021

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1521

9 Toxicity

91 Toxicological Information

911 Antidote and Emergency Treatment

Basic treatment Establish a patent airway Suction if necessary Watch for signs of respiratory insufficiency and assist ventilationsif necessary Administer oxygen by nonrebreather mask at 10 to 15 Lmin Monitor for shock and treat if necessary For eyecontamination flush eyes immediately with water Irrigate each eye continuously with normal saline during transport Do notuse emetics For ingestion rinse mouth and administer 5 mlkg up to 200 ml of water for dilution if the patient can swallow hasa strong gag reflex and does not drool Administer activated charcoal Copper and related compounds

Bronstein AC PL Currance Emergency Care for Hazardous Materials Exposure 2nd ed St Louis MO Mosby Lifeline 1994 p 350

Hazardous Substances Data Bank (HSDB)

Advanced treatment Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious Startan IV with lactated Ringers SRP To keep open minimal flow rate Watch for signs of fluid overload For hypotension withsigns of hypovolemia administer fluid cautiously Consider vasopressors if hypotensive with a normal fluid volume Watch forsigns of fluid overload Use proparacaine hydrochloride to assist eye irrigation Copper and related compounds

Bronstein AC PL Currance Emergency Care for Hazardous Materials Exposure 2nd ed St Louis MO Mosby Lifeline 1994 p 351

Hazardous Substances Data Bank (HSDB)

92 Ecological Information

921 Natural Pollution Sources

Basic salts occur in nature as the minerals cornetite dihydrite libethenite phosphorochalcite pseudolibethenitepseudomalachite tagilite

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1621

10 Literature

101 Springer Nature References

Springer Nature

102 Chemical Co-Occurrences in Literature

PubChem

103 Chemical-Gene Co-Occurrences in Literature

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1721

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1821

11 Patents

111 WIPO PATENTSCOPE

Patents are available for this chemical structure

httpspatentscopewipointsearchenresultjsfinchikey=GQDHEYWVLBJKBA-UHFFFAOYSA-H

PATENTSCOPE (WIPO)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1921

12 Classification

121 Ontologies

1211 ChemIDplus

ChemIDplus

1212 UN GHS Classification

UN Globally Harmonized System of Classification and Labelling of Chemicals (GHS)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2021

13 Information Sources

FILTER BY SOURCE

1 ChemIDplusLICENSEhttpswwwnlmnihgovcopyrighthtml

Copper(II) phosphatehttpschemnlmnihgovchemidplussid0007798234

ChemIDplus Chemical Information Classificationhttpschemnlmnihgovchemidplus

2 EPA Chemicals under the TSCALICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Phosphoric acid copper(2+) salt (23)httpswwwepagovchemicals-under-tsca

3 EPA DSSToxLICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Copper(II) phosphatehttpscomptoxepagovdashboardDTXSID00872547

4 European Chemicals Agency (ECHA)LICENSEUse of the information documents and data from the ECHA website is subject to the terms and conditions of this Legal Notice and subject to otherbinding limitations provided for under applicable law the information documents and data made available on the ECHA website may be reproduceddistributed andor used totally or in part for non-commercial purposes provided that ECHA is acknowledged as the source Source European ChemicalsAgency httpechaeuropaeu Such acknowledgement must be included in each copy of the material ECHA permits and encourages organisations andindividuals to create links to the ECHA website under the following cumulative conditions Links can only be made to webpages that provide a link to theLegal Notice pagehttpsechaeuropaeuwebguestlegal-notice

Tricopper bis(orthophosphate)httpsechaeuropaeusubstance-information-substanceinfo100029322

Tricopper bis(orthophosphate)httpsechaeuropaeuinformation-on-chemicalscl-inventory-database-disclidetails62531

5 Hazardous Substances Data Bank (HSDB)COPPER(II) PHOSPHATEhttpspubchemncbinlmnihgovsourcehsdb267

6 FDASPL Indexing DataLICENSEUnless otherwise noted the contents of the FDA website (wwwfdagov) both text and graphics are not copyrighted They are in the public domain andmay be republished reprinted and otherwise used freely by anyone without the need to obtain permission from FDA Credit to the US Food and DrugAdministration as the source is appreciated but not requiredhttpswwwfdagovabout-fdaabout-websitewebsite-policieslinking

N8NP6FR80RhttpswwwfdagovForIndustryDataStandardsSubstanceRegistrationSystem-UniqueIngredientIdentifierUNII

7 Springer Naturehttpspubchemncbinlmnihgovsubstance341378879

8 Wikipediafosfato de cobre (II)httpsenwikipediaorgwikiCopper(II)_phosphate

ALL SOURCES

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2121

9 PubChemhttpspubchemncbinlmnihgov

10 Sistema Globalmente Armonizado de Clasificacioacuten y Etiquetado de Productos Quiacutemicos(GHS) de las Naciones UnidasAacuterbol de clasificacioacuten GHShttpwwwuneceorgtransdangerpublighsghs_welcome_ehtml

11 PATENTSCOPE (OMPI)SID 403419907httpspubchemncbinlmnihgovsubstance403419907

Page 7: Fosfato de cobre (II) - Universidad Veracruzana

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 721

4 Related Records

41 Related Compounds with Annotation

PubChem

42 Component Compounds

CID 23978 (Copper)

CID 1004 (Phosphoric acid)

PubChem

43 Related CompoundsMixtures Components andNeutralized Forms 2 Records

Similar Compounds 12 Records

PubChem

44 Substances

441 Related Substances

Same 34 Records

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 821

442 Substances by Category

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 921

5 Chemical Vendors

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1021

6 Drug and Medication Information

61 Therapeutic Uses

MEDICATION (VET) TRACE MINERAL ADDED TO ANIMAL FEEDSSax NI Dangerous Properties of Industrial Materials 4th ed New York Van Nostrand Reinhold 1975 p 576

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1121

7 Use and Manufacturing

71 Uses

Fungicide catalyst for org reactions fertilizer emulsifier corrosion inhibitor for phosphoric acid protectant for metal surfacesagainst oxidation

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

Fungicide formerGerhartz W (exec ed) Ullmanns Encyclopedia of Industrial Chemistry 5th edVol A1 Deerfield Beach FL VCH Publishers 1985 to Present p VA7(1986) 585

Hazardous Substances Data Bank (HSDB)

MEDICATION

Hazardous Substances Data Bank (HSDB)

MEDICATION (VET)

Hazardous Substances Data Bank (HSDB)

72 Methods of Manufacturing

Preparation from copper sulfate and diammonium hydrogen phosphate Klement Haselbeck Z Anorg Allgem Chem 334 27(1964)

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

Prepared by reaction of copper(II) sulfate solution with soluble alkali phosphatesGerhartz W (exec ed) Ullmanns Encyclopedia of Industrial Chemistry 5th edVol A1 Deerfield Beach FL VCH Publishers 1985 to Present p VA7(1986) 585

Hazardous Substances Data Bank (HSDB)

73 General Manufacturing Information

EPA TSCA Commercial Activity Status

Phosphoric acid copper(2+) salt (23) ACTIVEhttpswwwepagovtsca-inventory

EPA Chemicals under the TSCA

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1221

8 Safety and Hazards

81 Hazards Identification

811 GHS Classification

Pictogram(s)

Signal Warning

GHS Hazard Statements

Aggregated GHS information provided by 13 companies from 5 notifications to the ECHA CampL Inventory Eachnotification may be associated with multiple companies

H302 (3077) Harmful if swallowed [Warning Acute toxicity oral]

H315 (3077) Causes skin irritation [Warning Skin corrosionirritation]

H319 (2308) Causes serious eye irritation [Warning Serious eye damageeye irritation]

H335 (2308) May cause respiratory irritation [Warning Specific target organ toxicity single exposureRespiratory tract irritation]

H410 (1538) Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquaticenvironment long-term hazard]

H412 (3077) Harmful to aquatic life with long lasting effects [Hazardous to the aquatic environment long-term hazard]

Information may vary between notifications depending on impurities additives and other factors Thepercentage value in parenthesis indicates the notified classification ratio from companies that provide hazardcodes Only hazard codes with percentage values above 10 are shown

Precautionary StatementCodes

P261 P264 P270 P271 P273 P280 P301+P312 P302+P352 P304+P340 P305+P351+P338 P312 P321P330 P332+P313 P337+P313 P362 P391 P403+P233 P405 and P501

(The corresponding statement to each P-code can be found at the GHS Classification page)

European Chemicals Agency (ECHA)

812 Hazard Classes and Categories

Skin Irrit 2 (3077)

Eye Irrit 2 (2308)

STOT SE 3 (2308)

Aquatic Chronic 1 (1538)

Aquatic Chronic 3 (3077)

European Chemicals Agency (ECHA)

82 Safety and Hazard Properties

821 NIOSH Recommendations

Recommended Exposure Limit 10 Hr Time-Weighted Avg 1 mgcu m Copper (dusts and mists)NIOSH NIOSH Pocket Guide to Chemical Hazards DHHS (NIOSH) Publication No 97-140 Washington DC US Government Printing Office1997 p 76

IrritantEnvironmental

Hazard

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1321

Hazardous Substances Data Bank (HSDB)

83 Accidental Release Measures

831 Disposal Methods

SRP At the time of review criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significantrevision Prior to implementing land disposal of waste residue (including waste sludge) consult with environmental regulatoryagencies for guidance on acceptable disposal practices

Hazardous Substances Data Bank (HSDB)

Group III Containers (both combustible and non-combustible) that previously held organic mercury lead cadmium arsenic orinorganic pesticides should be triple rinsed punctured and disposed of in a sanitary landfill Non-rinsed containers should beencapsulated and buried at a specially designated landfill site Organic mercury lead cadmium arsenic or inorganicpesticides

40 CFR 165 (7188)

Hazardous Substances Data Bank (HSDB)

84 Exposure Control and Personal Protection

841 Threshold Limit Values (TLV)

8 hr Time Weighted Avg (TWA) 1 mgcu m Copper dusts and mists as CuAmerican Conference of Governmental Industrial Hygienists TLVs and BEIs Threshold Limit Values for Chemical Substances and Physical Agentsand Biological Exposure Indices Cincinnati OH 2008 p 21

Hazardous Substances Data Bank (HSDB)

Excursion Limit Recommendation Excursions in worker exposure levels may exceed 3 times the TLV-TWA for no more than atotal of 30 minutes during a work day and under no circumstances should they exceed 5 times the TLV-TWA provided that theTLV-TWA is not exceeded Copper dusts and mists as Cu

American Conference of Governmental Industrial Hygienists TLVs and BEIs Threshold Limit Values for Chemical Substances and Physical Agentsand Biological Exposure Indices Cincinnati OH 2008 p 5

Hazardous Substances Data Bank (HSDB)

842 Acceptable Daily Intakes

The available human data indicate that gastrointestinal distress occurred following ingestion of solutions that contained 5-7 mgof copper and other unknown chemicals as a single dose These data were used to derive a 1 day health advisory of 13 mglwhich when spread over a day should provide protection from these acute effects Since the effects appear to be local irritationthis health advisory is recommended for both the child and the adult There are no data indicating that human exposure tocopper results in chronic toxic effects Furthermore there is a nutritional requirement for copper and acute effects appear to bethe effects of concern Therefore the one day health advisory 13 mgl will also be used as the adjustable acceptable dailyintake Copper

USEPA Drinking Water Criteria Document for Copper (Final Draft) pI-2 (1985) EPA-600X-84-190-1

Hazardous Substances Data Bank (HSDB)

85 Stability and Reactivity

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1421

851 Hazardous Reactivities and Incompatibilities

Solutions of sodium hypobromite are decomposed by powerful catalytic action of cupric ions even as impurities Cupric saltsFire Protection Guide to Hazardous Materials 12 ed Quincy MA National Fire Protection Association 1997 p 491-181

Hazardous Substances Data Bank (HSDB)

86 Regulatory Information

861 Federal Drinking Water Standards

EPA 1300 ugl (Action Level) CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

862 Federal Drinking Water Guidelines

EPA 1000 ugl CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

863 State Drinking Water Guidelines

(AZ) ARIZONA 1300 ugl CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

864 Clean Water Act Requirements

Toxic pollutant designated pursuant to section 307(a)(1) of the Federal Water Pollution Control Act and is subject to effluentlimitations Copper and cmpd

40 CFR 40115 (712000)

Hazardous Substances Data Bank (HSDB)

87 Other Safety Information

871 Toxic Combustion Products

DANGEROUS WHEN HEATED TO DECOMPOSITION CAN EMIT HIGHLY TOXIC FUMES OF PO(X) PHOSPHATESSax NI Dangerous Properties of Industrial Materials 4th ed New York Van Nostrand Reinhold 1975 p 1021

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1521

9 Toxicity

91 Toxicological Information

911 Antidote and Emergency Treatment

Basic treatment Establish a patent airway Suction if necessary Watch for signs of respiratory insufficiency and assist ventilationsif necessary Administer oxygen by nonrebreather mask at 10 to 15 Lmin Monitor for shock and treat if necessary For eyecontamination flush eyes immediately with water Irrigate each eye continuously with normal saline during transport Do notuse emetics For ingestion rinse mouth and administer 5 mlkg up to 200 ml of water for dilution if the patient can swallow hasa strong gag reflex and does not drool Administer activated charcoal Copper and related compounds

Bronstein AC PL Currance Emergency Care for Hazardous Materials Exposure 2nd ed St Louis MO Mosby Lifeline 1994 p 350

Hazardous Substances Data Bank (HSDB)

Advanced treatment Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious Startan IV with lactated Ringers SRP To keep open minimal flow rate Watch for signs of fluid overload For hypotension withsigns of hypovolemia administer fluid cautiously Consider vasopressors if hypotensive with a normal fluid volume Watch forsigns of fluid overload Use proparacaine hydrochloride to assist eye irrigation Copper and related compounds

Bronstein AC PL Currance Emergency Care for Hazardous Materials Exposure 2nd ed St Louis MO Mosby Lifeline 1994 p 351

Hazardous Substances Data Bank (HSDB)

92 Ecological Information

921 Natural Pollution Sources

Basic salts occur in nature as the minerals cornetite dihydrite libethenite phosphorochalcite pseudolibethenitepseudomalachite tagilite

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1621

10 Literature

101 Springer Nature References

Springer Nature

102 Chemical Co-Occurrences in Literature

PubChem

103 Chemical-Gene Co-Occurrences in Literature

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1721

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1821

11 Patents

111 WIPO PATENTSCOPE

Patents are available for this chemical structure

httpspatentscopewipointsearchenresultjsfinchikey=GQDHEYWVLBJKBA-UHFFFAOYSA-H

PATENTSCOPE (WIPO)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1921

12 Classification

121 Ontologies

1211 ChemIDplus

ChemIDplus

1212 UN GHS Classification

UN Globally Harmonized System of Classification and Labelling of Chemicals (GHS)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2021

13 Information Sources

FILTER BY SOURCE

1 ChemIDplusLICENSEhttpswwwnlmnihgovcopyrighthtml

Copper(II) phosphatehttpschemnlmnihgovchemidplussid0007798234

ChemIDplus Chemical Information Classificationhttpschemnlmnihgovchemidplus

2 EPA Chemicals under the TSCALICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Phosphoric acid copper(2+) salt (23)httpswwwepagovchemicals-under-tsca

3 EPA DSSToxLICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Copper(II) phosphatehttpscomptoxepagovdashboardDTXSID00872547

4 European Chemicals Agency (ECHA)LICENSEUse of the information documents and data from the ECHA website is subject to the terms and conditions of this Legal Notice and subject to otherbinding limitations provided for under applicable law the information documents and data made available on the ECHA website may be reproduceddistributed andor used totally or in part for non-commercial purposes provided that ECHA is acknowledged as the source Source European ChemicalsAgency httpechaeuropaeu Such acknowledgement must be included in each copy of the material ECHA permits and encourages organisations andindividuals to create links to the ECHA website under the following cumulative conditions Links can only be made to webpages that provide a link to theLegal Notice pagehttpsechaeuropaeuwebguestlegal-notice

Tricopper bis(orthophosphate)httpsechaeuropaeusubstance-information-substanceinfo100029322

Tricopper bis(orthophosphate)httpsechaeuropaeuinformation-on-chemicalscl-inventory-database-disclidetails62531

5 Hazardous Substances Data Bank (HSDB)COPPER(II) PHOSPHATEhttpspubchemncbinlmnihgovsourcehsdb267

6 FDASPL Indexing DataLICENSEUnless otherwise noted the contents of the FDA website (wwwfdagov) both text and graphics are not copyrighted They are in the public domain andmay be republished reprinted and otherwise used freely by anyone without the need to obtain permission from FDA Credit to the US Food and DrugAdministration as the source is appreciated but not requiredhttpswwwfdagovabout-fdaabout-websitewebsite-policieslinking

N8NP6FR80RhttpswwwfdagovForIndustryDataStandardsSubstanceRegistrationSystem-UniqueIngredientIdentifierUNII

7 Springer Naturehttpspubchemncbinlmnihgovsubstance341378879

8 Wikipediafosfato de cobre (II)httpsenwikipediaorgwikiCopper(II)_phosphate

ALL SOURCES

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2121

9 PubChemhttpspubchemncbinlmnihgov

10 Sistema Globalmente Armonizado de Clasificacioacuten y Etiquetado de Productos Quiacutemicos(GHS) de las Naciones UnidasAacuterbol de clasificacioacuten GHShttpwwwuneceorgtransdangerpublighsghs_welcome_ehtml

11 PATENTSCOPE (OMPI)SID 403419907httpspubchemncbinlmnihgovsubstance403419907

Page 8: Fosfato de cobre (II) - Universidad Veracruzana

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 821

442 Substances by Category

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 921

5 Chemical Vendors

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1021

6 Drug and Medication Information

61 Therapeutic Uses

MEDICATION (VET) TRACE MINERAL ADDED TO ANIMAL FEEDSSax NI Dangerous Properties of Industrial Materials 4th ed New York Van Nostrand Reinhold 1975 p 576

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1121

7 Use and Manufacturing

71 Uses

Fungicide catalyst for org reactions fertilizer emulsifier corrosion inhibitor for phosphoric acid protectant for metal surfacesagainst oxidation

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

Fungicide formerGerhartz W (exec ed) Ullmanns Encyclopedia of Industrial Chemistry 5th edVol A1 Deerfield Beach FL VCH Publishers 1985 to Present p VA7(1986) 585

Hazardous Substances Data Bank (HSDB)

MEDICATION

Hazardous Substances Data Bank (HSDB)

MEDICATION (VET)

Hazardous Substances Data Bank (HSDB)

72 Methods of Manufacturing

Preparation from copper sulfate and diammonium hydrogen phosphate Klement Haselbeck Z Anorg Allgem Chem 334 27(1964)

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

Prepared by reaction of copper(II) sulfate solution with soluble alkali phosphatesGerhartz W (exec ed) Ullmanns Encyclopedia of Industrial Chemistry 5th edVol A1 Deerfield Beach FL VCH Publishers 1985 to Present p VA7(1986) 585

Hazardous Substances Data Bank (HSDB)

73 General Manufacturing Information

EPA TSCA Commercial Activity Status

Phosphoric acid copper(2+) salt (23) ACTIVEhttpswwwepagovtsca-inventory

EPA Chemicals under the TSCA

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1221

8 Safety and Hazards

81 Hazards Identification

811 GHS Classification

Pictogram(s)

Signal Warning

GHS Hazard Statements

Aggregated GHS information provided by 13 companies from 5 notifications to the ECHA CampL Inventory Eachnotification may be associated with multiple companies

H302 (3077) Harmful if swallowed [Warning Acute toxicity oral]

H315 (3077) Causes skin irritation [Warning Skin corrosionirritation]

H319 (2308) Causes serious eye irritation [Warning Serious eye damageeye irritation]

H335 (2308) May cause respiratory irritation [Warning Specific target organ toxicity single exposureRespiratory tract irritation]

H410 (1538) Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquaticenvironment long-term hazard]

H412 (3077) Harmful to aquatic life with long lasting effects [Hazardous to the aquatic environment long-term hazard]

Information may vary between notifications depending on impurities additives and other factors Thepercentage value in parenthesis indicates the notified classification ratio from companies that provide hazardcodes Only hazard codes with percentage values above 10 are shown

Precautionary StatementCodes

P261 P264 P270 P271 P273 P280 P301+P312 P302+P352 P304+P340 P305+P351+P338 P312 P321P330 P332+P313 P337+P313 P362 P391 P403+P233 P405 and P501

(The corresponding statement to each P-code can be found at the GHS Classification page)

European Chemicals Agency (ECHA)

812 Hazard Classes and Categories

Skin Irrit 2 (3077)

Eye Irrit 2 (2308)

STOT SE 3 (2308)

Aquatic Chronic 1 (1538)

Aquatic Chronic 3 (3077)

European Chemicals Agency (ECHA)

82 Safety and Hazard Properties

821 NIOSH Recommendations

Recommended Exposure Limit 10 Hr Time-Weighted Avg 1 mgcu m Copper (dusts and mists)NIOSH NIOSH Pocket Guide to Chemical Hazards DHHS (NIOSH) Publication No 97-140 Washington DC US Government Printing Office1997 p 76

IrritantEnvironmental

Hazard

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1321

Hazardous Substances Data Bank (HSDB)

83 Accidental Release Measures

831 Disposal Methods

SRP At the time of review criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significantrevision Prior to implementing land disposal of waste residue (including waste sludge) consult with environmental regulatoryagencies for guidance on acceptable disposal practices

Hazardous Substances Data Bank (HSDB)

Group III Containers (both combustible and non-combustible) that previously held organic mercury lead cadmium arsenic orinorganic pesticides should be triple rinsed punctured and disposed of in a sanitary landfill Non-rinsed containers should beencapsulated and buried at a specially designated landfill site Organic mercury lead cadmium arsenic or inorganicpesticides

40 CFR 165 (7188)

Hazardous Substances Data Bank (HSDB)

84 Exposure Control and Personal Protection

841 Threshold Limit Values (TLV)

8 hr Time Weighted Avg (TWA) 1 mgcu m Copper dusts and mists as CuAmerican Conference of Governmental Industrial Hygienists TLVs and BEIs Threshold Limit Values for Chemical Substances and Physical Agentsand Biological Exposure Indices Cincinnati OH 2008 p 21

Hazardous Substances Data Bank (HSDB)

Excursion Limit Recommendation Excursions in worker exposure levels may exceed 3 times the TLV-TWA for no more than atotal of 30 minutes during a work day and under no circumstances should they exceed 5 times the TLV-TWA provided that theTLV-TWA is not exceeded Copper dusts and mists as Cu

American Conference of Governmental Industrial Hygienists TLVs and BEIs Threshold Limit Values for Chemical Substances and Physical Agentsand Biological Exposure Indices Cincinnati OH 2008 p 5

Hazardous Substances Data Bank (HSDB)

842 Acceptable Daily Intakes

The available human data indicate that gastrointestinal distress occurred following ingestion of solutions that contained 5-7 mgof copper and other unknown chemicals as a single dose These data were used to derive a 1 day health advisory of 13 mglwhich when spread over a day should provide protection from these acute effects Since the effects appear to be local irritationthis health advisory is recommended for both the child and the adult There are no data indicating that human exposure tocopper results in chronic toxic effects Furthermore there is a nutritional requirement for copper and acute effects appear to bethe effects of concern Therefore the one day health advisory 13 mgl will also be used as the adjustable acceptable dailyintake Copper

USEPA Drinking Water Criteria Document for Copper (Final Draft) pI-2 (1985) EPA-600X-84-190-1

Hazardous Substances Data Bank (HSDB)

85 Stability and Reactivity

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1421

851 Hazardous Reactivities and Incompatibilities

Solutions of sodium hypobromite are decomposed by powerful catalytic action of cupric ions even as impurities Cupric saltsFire Protection Guide to Hazardous Materials 12 ed Quincy MA National Fire Protection Association 1997 p 491-181

Hazardous Substances Data Bank (HSDB)

86 Regulatory Information

861 Federal Drinking Water Standards

EPA 1300 ugl (Action Level) CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

862 Federal Drinking Water Guidelines

EPA 1000 ugl CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

863 State Drinking Water Guidelines

(AZ) ARIZONA 1300 ugl CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

864 Clean Water Act Requirements

Toxic pollutant designated pursuant to section 307(a)(1) of the Federal Water Pollution Control Act and is subject to effluentlimitations Copper and cmpd

40 CFR 40115 (712000)

Hazardous Substances Data Bank (HSDB)

87 Other Safety Information

871 Toxic Combustion Products

DANGEROUS WHEN HEATED TO DECOMPOSITION CAN EMIT HIGHLY TOXIC FUMES OF PO(X) PHOSPHATESSax NI Dangerous Properties of Industrial Materials 4th ed New York Van Nostrand Reinhold 1975 p 1021

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1521

9 Toxicity

91 Toxicological Information

911 Antidote and Emergency Treatment

Basic treatment Establish a patent airway Suction if necessary Watch for signs of respiratory insufficiency and assist ventilationsif necessary Administer oxygen by nonrebreather mask at 10 to 15 Lmin Monitor for shock and treat if necessary For eyecontamination flush eyes immediately with water Irrigate each eye continuously with normal saline during transport Do notuse emetics For ingestion rinse mouth and administer 5 mlkg up to 200 ml of water for dilution if the patient can swallow hasa strong gag reflex and does not drool Administer activated charcoal Copper and related compounds

Bronstein AC PL Currance Emergency Care for Hazardous Materials Exposure 2nd ed St Louis MO Mosby Lifeline 1994 p 350

Hazardous Substances Data Bank (HSDB)

Advanced treatment Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious Startan IV with lactated Ringers SRP To keep open minimal flow rate Watch for signs of fluid overload For hypotension withsigns of hypovolemia administer fluid cautiously Consider vasopressors if hypotensive with a normal fluid volume Watch forsigns of fluid overload Use proparacaine hydrochloride to assist eye irrigation Copper and related compounds

Bronstein AC PL Currance Emergency Care for Hazardous Materials Exposure 2nd ed St Louis MO Mosby Lifeline 1994 p 351

Hazardous Substances Data Bank (HSDB)

92 Ecological Information

921 Natural Pollution Sources

Basic salts occur in nature as the minerals cornetite dihydrite libethenite phosphorochalcite pseudolibethenitepseudomalachite tagilite

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1621

10 Literature

101 Springer Nature References

Springer Nature

102 Chemical Co-Occurrences in Literature

PubChem

103 Chemical-Gene Co-Occurrences in Literature

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1721

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1821

11 Patents

111 WIPO PATENTSCOPE

Patents are available for this chemical structure

httpspatentscopewipointsearchenresultjsfinchikey=GQDHEYWVLBJKBA-UHFFFAOYSA-H

PATENTSCOPE (WIPO)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1921

12 Classification

121 Ontologies

1211 ChemIDplus

ChemIDplus

1212 UN GHS Classification

UN Globally Harmonized System of Classification and Labelling of Chemicals (GHS)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2021

13 Information Sources

FILTER BY SOURCE

1 ChemIDplusLICENSEhttpswwwnlmnihgovcopyrighthtml

Copper(II) phosphatehttpschemnlmnihgovchemidplussid0007798234

ChemIDplus Chemical Information Classificationhttpschemnlmnihgovchemidplus

2 EPA Chemicals under the TSCALICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Phosphoric acid copper(2+) salt (23)httpswwwepagovchemicals-under-tsca

3 EPA DSSToxLICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Copper(II) phosphatehttpscomptoxepagovdashboardDTXSID00872547

4 European Chemicals Agency (ECHA)LICENSEUse of the information documents and data from the ECHA website is subject to the terms and conditions of this Legal Notice and subject to otherbinding limitations provided for under applicable law the information documents and data made available on the ECHA website may be reproduceddistributed andor used totally or in part for non-commercial purposes provided that ECHA is acknowledged as the source Source European ChemicalsAgency httpechaeuropaeu Such acknowledgement must be included in each copy of the material ECHA permits and encourages organisations andindividuals to create links to the ECHA website under the following cumulative conditions Links can only be made to webpages that provide a link to theLegal Notice pagehttpsechaeuropaeuwebguestlegal-notice

Tricopper bis(orthophosphate)httpsechaeuropaeusubstance-information-substanceinfo100029322

Tricopper bis(orthophosphate)httpsechaeuropaeuinformation-on-chemicalscl-inventory-database-disclidetails62531

5 Hazardous Substances Data Bank (HSDB)COPPER(II) PHOSPHATEhttpspubchemncbinlmnihgovsourcehsdb267

6 FDASPL Indexing DataLICENSEUnless otherwise noted the contents of the FDA website (wwwfdagov) both text and graphics are not copyrighted They are in the public domain andmay be republished reprinted and otherwise used freely by anyone without the need to obtain permission from FDA Credit to the US Food and DrugAdministration as the source is appreciated but not requiredhttpswwwfdagovabout-fdaabout-websitewebsite-policieslinking

N8NP6FR80RhttpswwwfdagovForIndustryDataStandardsSubstanceRegistrationSystem-UniqueIngredientIdentifierUNII

7 Springer Naturehttpspubchemncbinlmnihgovsubstance341378879

8 Wikipediafosfato de cobre (II)httpsenwikipediaorgwikiCopper(II)_phosphate

ALL SOURCES

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2121

9 PubChemhttpspubchemncbinlmnihgov

10 Sistema Globalmente Armonizado de Clasificacioacuten y Etiquetado de Productos Quiacutemicos(GHS) de las Naciones UnidasAacuterbol de clasificacioacuten GHShttpwwwuneceorgtransdangerpublighsghs_welcome_ehtml

11 PATENTSCOPE (OMPI)SID 403419907httpspubchemncbinlmnihgovsubstance403419907

Page 9: Fosfato de cobre (II) - Universidad Veracruzana

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 921

5 Chemical Vendors

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1021

6 Drug and Medication Information

61 Therapeutic Uses

MEDICATION (VET) TRACE MINERAL ADDED TO ANIMAL FEEDSSax NI Dangerous Properties of Industrial Materials 4th ed New York Van Nostrand Reinhold 1975 p 576

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1121

7 Use and Manufacturing

71 Uses

Fungicide catalyst for org reactions fertilizer emulsifier corrosion inhibitor for phosphoric acid protectant for metal surfacesagainst oxidation

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

Fungicide formerGerhartz W (exec ed) Ullmanns Encyclopedia of Industrial Chemistry 5th edVol A1 Deerfield Beach FL VCH Publishers 1985 to Present p VA7(1986) 585

Hazardous Substances Data Bank (HSDB)

MEDICATION

Hazardous Substances Data Bank (HSDB)

MEDICATION (VET)

Hazardous Substances Data Bank (HSDB)

72 Methods of Manufacturing

Preparation from copper sulfate and diammonium hydrogen phosphate Klement Haselbeck Z Anorg Allgem Chem 334 27(1964)

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

Prepared by reaction of copper(II) sulfate solution with soluble alkali phosphatesGerhartz W (exec ed) Ullmanns Encyclopedia of Industrial Chemistry 5th edVol A1 Deerfield Beach FL VCH Publishers 1985 to Present p VA7(1986) 585

Hazardous Substances Data Bank (HSDB)

73 General Manufacturing Information

EPA TSCA Commercial Activity Status

Phosphoric acid copper(2+) salt (23) ACTIVEhttpswwwepagovtsca-inventory

EPA Chemicals under the TSCA

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1221

8 Safety and Hazards

81 Hazards Identification

811 GHS Classification

Pictogram(s)

Signal Warning

GHS Hazard Statements

Aggregated GHS information provided by 13 companies from 5 notifications to the ECHA CampL Inventory Eachnotification may be associated with multiple companies

H302 (3077) Harmful if swallowed [Warning Acute toxicity oral]

H315 (3077) Causes skin irritation [Warning Skin corrosionirritation]

H319 (2308) Causes serious eye irritation [Warning Serious eye damageeye irritation]

H335 (2308) May cause respiratory irritation [Warning Specific target organ toxicity single exposureRespiratory tract irritation]

H410 (1538) Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquaticenvironment long-term hazard]

H412 (3077) Harmful to aquatic life with long lasting effects [Hazardous to the aquatic environment long-term hazard]

Information may vary between notifications depending on impurities additives and other factors Thepercentage value in parenthesis indicates the notified classification ratio from companies that provide hazardcodes Only hazard codes with percentage values above 10 are shown

Precautionary StatementCodes

P261 P264 P270 P271 P273 P280 P301+P312 P302+P352 P304+P340 P305+P351+P338 P312 P321P330 P332+P313 P337+P313 P362 P391 P403+P233 P405 and P501

(The corresponding statement to each P-code can be found at the GHS Classification page)

European Chemicals Agency (ECHA)

812 Hazard Classes and Categories

Skin Irrit 2 (3077)

Eye Irrit 2 (2308)

STOT SE 3 (2308)

Aquatic Chronic 1 (1538)

Aquatic Chronic 3 (3077)

European Chemicals Agency (ECHA)

82 Safety and Hazard Properties

821 NIOSH Recommendations

Recommended Exposure Limit 10 Hr Time-Weighted Avg 1 mgcu m Copper (dusts and mists)NIOSH NIOSH Pocket Guide to Chemical Hazards DHHS (NIOSH) Publication No 97-140 Washington DC US Government Printing Office1997 p 76

IrritantEnvironmental

Hazard

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1321

Hazardous Substances Data Bank (HSDB)

83 Accidental Release Measures

831 Disposal Methods

SRP At the time of review criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significantrevision Prior to implementing land disposal of waste residue (including waste sludge) consult with environmental regulatoryagencies for guidance on acceptable disposal practices

Hazardous Substances Data Bank (HSDB)

Group III Containers (both combustible and non-combustible) that previously held organic mercury lead cadmium arsenic orinorganic pesticides should be triple rinsed punctured and disposed of in a sanitary landfill Non-rinsed containers should beencapsulated and buried at a specially designated landfill site Organic mercury lead cadmium arsenic or inorganicpesticides

40 CFR 165 (7188)

Hazardous Substances Data Bank (HSDB)

84 Exposure Control and Personal Protection

841 Threshold Limit Values (TLV)

8 hr Time Weighted Avg (TWA) 1 mgcu m Copper dusts and mists as CuAmerican Conference of Governmental Industrial Hygienists TLVs and BEIs Threshold Limit Values for Chemical Substances and Physical Agentsand Biological Exposure Indices Cincinnati OH 2008 p 21

Hazardous Substances Data Bank (HSDB)

Excursion Limit Recommendation Excursions in worker exposure levels may exceed 3 times the TLV-TWA for no more than atotal of 30 minutes during a work day and under no circumstances should they exceed 5 times the TLV-TWA provided that theTLV-TWA is not exceeded Copper dusts and mists as Cu

American Conference of Governmental Industrial Hygienists TLVs and BEIs Threshold Limit Values for Chemical Substances and Physical Agentsand Biological Exposure Indices Cincinnati OH 2008 p 5

Hazardous Substances Data Bank (HSDB)

842 Acceptable Daily Intakes

The available human data indicate that gastrointestinal distress occurred following ingestion of solutions that contained 5-7 mgof copper and other unknown chemicals as a single dose These data were used to derive a 1 day health advisory of 13 mglwhich when spread over a day should provide protection from these acute effects Since the effects appear to be local irritationthis health advisory is recommended for both the child and the adult There are no data indicating that human exposure tocopper results in chronic toxic effects Furthermore there is a nutritional requirement for copper and acute effects appear to bethe effects of concern Therefore the one day health advisory 13 mgl will also be used as the adjustable acceptable dailyintake Copper

USEPA Drinking Water Criteria Document for Copper (Final Draft) pI-2 (1985) EPA-600X-84-190-1

Hazardous Substances Data Bank (HSDB)

85 Stability and Reactivity

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1421

851 Hazardous Reactivities and Incompatibilities

Solutions of sodium hypobromite are decomposed by powerful catalytic action of cupric ions even as impurities Cupric saltsFire Protection Guide to Hazardous Materials 12 ed Quincy MA National Fire Protection Association 1997 p 491-181

Hazardous Substances Data Bank (HSDB)

86 Regulatory Information

861 Federal Drinking Water Standards

EPA 1300 ugl (Action Level) CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

862 Federal Drinking Water Guidelines

EPA 1000 ugl CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

863 State Drinking Water Guidelines

(AZ) ARIZONA 1300 ugl CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

864 Clean Water Act Requirements

Toxic pollutant designated pursuant to section 307(a)(1) of the Federal Water Pollution Control Act and is subject to effluentlimitations Copper and cmpd

40 CFR 40115 (712000)

Hazardous Substances Data Bank (HSDB)

87 Other Safety Information

871 Toxic Combustion Products

DANGEROUS WHEN HEATED TO DECOMPOSITION CAN EMIT HIGHLY TOXIC FUMES OF PO(X) PHOSPHATESSax NI Dangerous Properties of Industrial Materials 4th ed New York Van Nostrand Reinhold 1975 p 1021

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1521

9 Toxicity

91 Toxicological Information

911 Antidote and Emergency Treatment

Basic treatment Establish a patent airway Suction if necessary Watch for signs of respiratory insufficiency and assist ventilationsif necessary Administer oxygen by nonrebreather mask at 10 to 15 Lmin Monitor for shock and treat if necessary For eyecontamination flush eyes immediately with water Irrigate each eye continuously with normal saline during transport Do notuse emetics For ingestion rinse mouth and administer 5 mlkg up to 200 ml of water for dilution if the patient can swallow hasa strong gag reflex and does not drool Administer activated charcoal Copper and related compounds

Bronstein AC PL Currance Emergency Care for Hazardous Materials Exposure 2nd ed St Louis MO Mosby Lifeline 1994 p 350

Hazardous Substances Data Bank (HSDB)

Advanced treatment Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious Startan IV with lactated Ringers SRP To keep open minimal flow rate Watch for signs of fluid overload For hypotension withsigns of hypovolemia administer fluid cautiously Consider vasopressors if hypotensive with a normal fluid volume Watch forsigns of fluid overload Use proparacaine hydrochloride to assist eye irrigation Copper and related compounds

Bronstein AC PL Currance Emergency Care for Hazardous Materials Exposure 2nd ed St Louis MO Mosby Lifeline 1994 p 351

Hazardous Substances Data Bank (HSDB)

92 Ecological Information

921 Natural Pollution Sources

Basic salts occur in nature as the minerals cornetite dihydrite libethenite phosphorochalcite pseudolibethenitepseudomalachite tagilite

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1621

10 Literature

101 Springer Nature References

Springer Nature

102 Chemical Co-Occurrences in Literature

PubChem

103 Chemical-Gene Co-Occurrences in Literature

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1721

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1821

11 Patents

111 WIPO PATENTSCOPE

Patents are available for this chemical structure

httpspatentscopewipointsearchenresultjsfinchikey=GQDHEYWVLBJKBA-UHFFFAOYSA-H

PATENTSCOPE (WIPO)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1921

12 Classification

121 Ontologies

1211 ChemIDplus

ChemIDplus

1212 UN GHS Classification

UN Globally Harmonized System of Classification and Labelling of Chemicals (GHS)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2021

13 Information Sources

FILTER BY SOURCE

1 ChemIDplusLICENSEhttpswwwnlmnihgovcopyrighthtml

Copper(II) phosphatehttpschemnlmnihgovchemidplussid0007798234

ChemIDplus Chemical Information Classificationhttpschemnlmnihgovchemidplus

2 EPA Chemicals under the TSCALICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Phosphoric acid copper(2+) salt (23)httpswwwepagovchemicals-under-tsca

3 EPA DSSToxLICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Copper(II) phosphatehttpscomptoxepagovdashboardDTXSID00872547

4 European Chemicals Agency (ECHA)LICENSEUse of the information documents and data from the ECHA website is subject to the terms and conditions of this Legal Notice and subject to otherbinding limitations provided for under applicable law the information documents and data made available on the ECHA website may be reproduceddistributed andor used totally or in part for non-commercial purposes provided that ECHA is acknowledged as the source Source European ChemicalsAgency httpechaeuropaeu Such acknowledgement must be included in each copy of the material ECHA permits and encourages organisations andindividuals to create links to the ECHA website under the following cumulative conditions Links can only be made to webpages that provide a link to theLegal Notice pagehttpsechaeuropaeuwebguestlegal-notice

Tricopper bis(orthophosphate)httpsechaeuropaeusubstance-information-substanceinfo100029322

Tricopper bis(orthophosphate)httpsechaeuropaeuinformation-on-chemicalscl-inventory-database-disclidetails62531

5 Hazardous Substances Data Bank (HSDB)COPPER(II) PHOSPHATEhttpspubchemncbinlmnihgovsourcehsdb267

6 FDASPL Indexing DataLICENSEUnless otherwise noted the contents of the FDA website (wwwfdagov) both text and graphics are not copyrighted They are in the public domain andmay be republished reprinted and otherwise used freely by anyone without the need to obtain permission from FDA Credit to the US Food and DrugAdministration as the source is appreciated but not requiredhttpswwwfdagovabout-fdaabout-websitewebsite-policieslinking

N8NP6FR80RhttpswwwfdagovForIndustryDataStandardsSubstanceRegistrationSystem-UniqueIngredientIdentifierUNII

7 Springer Naturehttpspubchemncbinlmnihgovsubstance341378879

8 Wikipediafosfato de cobre (II)httpsenwikipediaorgwikiCopper(II)_phosphate

ALL SOURCES

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2121

9 PubChemhttpspubchemncbinlmnihgov

10 Sistema Globalmente Armonizado de Clasificacioacuten y Etiquetado de Productos Quiacutemicos(GHS) de las Naciones UnidasAacuterbol de clasificacioacuten GHShttpwwwuneceorgtransdangerpublighsghs_welcome_ehtml

11 PATENTSCOPE (OMPI)SID 403419907httpspubchemncbinlmnihgovsubstance403419907

Page 10: Fosfato de cobre (II) - Universidad Veracruzana

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1021

6 Drug and Medication Information

61 Therapeutic Uses

MEDICATION (VET) TRACE MINERAL ADDED TO ANIMAL FEEDSSax NI Dangerous Properties of Industrial Materials 4th ed New York Van Nostrand Reinhold 1975 p 576

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1121

7 Use and Manufacturing

71 Uses

Fungicide catalyst for org reactions fertilizer emulsifier corrosion inhibitor for phosphoric acid protectant for metal surfacesagainst oxidation

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

Fungicide formerGerhartz W (exec ed) Ullmanns Encyclopedia of Industrial Chemistry 5th edVol A1 Deerfield Beach FL VCH Publishers 1985 to Present p VA7(1986) 585

Hazardous Substances Data Bank (HSDB)

MEDICATION

Hazardous Substances Data Bank (HSDB)

MEDICATION (VET)

Hazardous Substances Data Bank (HSDB)

72 Methods of Manufacturing

Preparation from copper sulfate and diammonium hydrogen phosphate Klement Haselbeck Z Anorg Allgem Chem 334 27(1964)

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

Prepared by reaction of copper(II) sulfate solution with soluble alkali phosphatesGerhartz W (exec ed) Ullmanns Encyclopedia of Industrial Chemistry 5th edVol A1 Deerfield Beach FL VCH Publishers 1985 to Present p VA7(1986) 585

Hazardous Substances Data Bank (HSDB)

73 General Manufacturing Information

EPA TSCA Commercial Activity Status

Phosphoric acid copper(2+) salt (23) ACTIVEhttpswwwepagovtsca-inventory

EPA Chemicals under the TSCA

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1221

8 Safety and Hazards

81 Hazards Identification

811 GHS Classification

Pictogram(s)

Signal Warning

GHS Hazard Statements

Aggregated GHS information provided by 13 companies from 5 notifications to the ECHA CampL Inventory Eachnotification may be associated with multiple companies

H302 (3077) Harmful if swallowed [Warning Acute toxicity oral]

H315 (3077) Causes skin irritation [Warning Skin corrosionirritation]

H319 (2308) Causes serious eye irritation [Warning Serious eye damageeye irritation]

H335 (2308) May cause respiratory irritation [Warning Specific target organ toxicity single exposureRespiratory tract irritation]

H410 (1538) Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquaticenvironment long-term hazard]

H412 (3077) Harmful to aquatic life with long lasting effects [Hazardous to the aquatic environment long-term hazard]

Information may vary between notifications depending on impurities additives and other factors Thepercentage value in parenthesis indicates the notified classification ratio from companies that provide hazardcodes Only hazard codes with percentage values above 10 are shown

Precautionary StatementCodes

P261 P264 P270 P271 P273 P280 P301+P312 P302+P352 P304+P340 P305+P351+P338 P312 P321P330 P332+P313 P337+P313 P362 P391 P403+P233 P405 and P501

(The corresponding statement to each P-code can be found at the GHS Classification page)

European Chemicals Agency (ECHA)

812 Hazard Classes and Categories

Skin Irrit 2 (3077)

Eye Irrit 2 (2308)

STOT SE 3 (2308)

Aquatic Chronic 1 (1538)

Aquatic Chronic 3 (3077)

European Chemicals Agency (ECHA)

82 Safety and Hazard Properties

821 NIOSH Recommendations

Recommended Exposure Limit 10 Hr Time-Weighted Avg 1 mgcu m Copper (dusts and mists)NIOSH NIOSH Pocket Guide to Chemical Hazards DHHS (NIOSH) Publication No 97-140 Washington DC US Government Printing Office1997 p 76

IrritantEnvironmental

Hazard

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1321

Hazardous Substances Data Bank (HSDB)

83 Accidental Release Measures

831 Disposal Methods

SRP At the time of review criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significantrevision Prior to implementing land disposal of waste residue (including waste sludge) consult with environmental regulatoryagencies for guidance on acceptable disposal practices

Hazardous Substances Data Bank (HSDB)

Group III Containers (both combustible and non-combustible) that previously held organic mercury lead cadmium arsenic orinorganic pesticides should be triple rinsed punctured and disposed of in a sanitary landfill Non-rinsed containers should beencapsulated and buried at a specially designated landfill site Organic mercury lead cadmium arsenic or inorganicpesticides

40 CFR 165 (7188)

Hazardous Substances Data Bank (HSDB)

84 Exposure Control and Personal Protection

841 Threshold Limit Values (TLV)

8 hr Time Weighted Avg (TWA) 1 mgcu m Copper dusts and mists as CuAmerican Conference of Governmental Industrial Hygienists TLVs and BEIs Threshold Limit Values for Chemical Substances and Physical Agentsand Biological Exposure Indices Cincinnati OH 2008 p 21

Hazardous Substances Data Bank (HSDB)

Excursion Limit Recommendation Excursions in worker exposure levels may exceed 3 times the TLV-TWA for no more than atotal of 30 minutes during a work day and under no circumstances should they exceed 5 times the TLV-TWA provided that theTLV-TWA is not exceeded Copper dusts and mists as Cu

American Conference of Governmental Industrial Hygienists TLVs and BEIs Threshold Limit Values for Chemical Substances and Physical Agentsand Biological Exposure Indices Cincinnati OH 2008 p 5

Hazardous Substances Data Bank (HSDB)

842 Acceptable Daily Intakes

The available human data indicate that gastrointestinal distress occurred following ingestion of solutions that contained 5-7 mgof copper and other unknown chemicals as a single dose These data were used to derive a 1 day health advisory of 13 mglwhich when spread over a day should provide protection from these acute effects Since the effects appear to be local irritationthis health advisory is recommended for both the child and the adult There are no data indicating that human exposure tocopper results in chronic toxic effects Furthermore there is a nutritional requirement for copper and acute effects appear to bethe effects of concern Therefore the one day health advisory 13 mgl will also be used as the adjustable acceptable dailyintake Copper

USEPA Drinking Water Criteria Document for Copper (Final Draft) pI-2 (1985) EPA-600X-84-190-1

Hazardous Substances Data Bank (HSDB)

85 Stability and Reactivity

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1421

851 Hazardous Reactivities and Incompatibilities

Solutions of sodium hypobromite are decomposed by powerful catalytic action of cupric ions even as impurities Cupric saltsFire Protection Guide to Hazardous Materials 12 ed Quincy MA National Fire Protection Association 1997 p 491-181

Hazardous Substances Data Bank (HSDB)

86 Regulatory Information

861 Federal Drinking Water Standards

EPA 1300 ugl (Action Level) CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

862 Federal Drinking Water Guidelines

EPA 1000 ugl CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

863 State Drinking Water Guidelines

(AZ) ARIZONA 1300 ugl CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

864 Clean Water Act Requirements

Toxic pollutant designated pursuant to section 307(a)(1) of the Federal Water Pollution Control Act and is subject to effluentlimitations Copper and cmpd

40 CFR 40115 (712000)

Hazardous Substances Data Bank (HSDB)

87 Other Safety Information

871 Toxic Combustion Products

DANGEROUS WHEN HEATED TO DECOMPOSITION CAN EMIT HIGHLY TOXIC FUMES OF PO(X) PHOSPHATESSax NI Dangerous Properties of Industrial Materials 4th ed New York Van Nostrand Reinhold 1975 p 1021

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1521

9 Toxicity

91 Toxicological Information

911 Antidote and Emergency Treatment

Basic treatment Establish a patent airway Suction if necessary Watch for signs of respiratory insufficiency and assist ventilationsif necessary Administer oxygen by nonrebreather mask at 10 to 15 Lmin Monitor for shock and treat if necessary For eyecontamination flush eyes immediately with water Irrigate each eye continuously with normal saline during transport Do notuse emetics For ingestion rinse mouth and administer 5 mlkg up to 200 ml of water for dilution if the patient can swallow hasa strong gag reflex and does not drool Administer activated charcoal Copper and related compounds

Bronstein AC PL Currance Emergency Care for Hazardous Materials Exposure 2nd ed St Louis MO Mosby Lifeline 1994 p 350

Hazardous Substances Data Bank (HSDB)

Advanced treatment Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious Startan IV with lactated Ringers SRP To keep open minimal flow rate Watch for signs of fluid overload For hypotension withsigns of hypovolemia administer fluid cautiously Consider vasopressors if hypotensive with a normal fluid volume Watch forsigns of fluid overload Use proparacaine hydrochloride to assist eye irrigation Copper and related compounds

Bronstein AC PL Currance Emergency Care for Hazardous Materials Exposure 2nd ed St Louis MO Mosby Lifeline 1994 p 351

Hazardous Substances Data Bank (HSDB)

92 Ecological Information

921 Natural Pollution Sources

Basic salts occur in nature as the minerals cornetite dihydrite libethenite phosphorochalcite pseudolibethenitepseudomalachite tagilite

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1621

10 Literature

101 Springer Nature References

Springer Nature

102 Chemical Co-Occurrences in Literature

PubChem

103 Chemical-Gene Co-Occurrences in Literature

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1721

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1821

11 Patents

111 WIPO PATENTSCOPE

Patents are available for this chemical structure

httpspatentscopewipointsearchenresultjsfinchikey=GQDHEYWVLBJKBA-UHFFFAOYSA-H

PATENTSCOPE (WIPO)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1921

12 Classification

121 Ontologies

1211 ChemIDplus

ChemIDplus

1212 UN GHS Classification

UN Globally Harmonized System of Classification and Labelling of Chemicals (GHS)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2021

13 Information Sources

FILTER BY SOURCE

1 ChemIDplusLICENSEhttpswwwnlmnihgovcopyrighthtml

Copper(II) phosphatehttpschemnlmnihgovchemidplussid0007798234

ChemIDplus Chemical Information Classificationhttpschemnlmnihgovchemidplus

2 EPA Chemicals under the TSCALICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Phosphoric acid copper(2+) salt (23)httpswwwepagovchemicals-under-tsca

3 EPA DSSToxLICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Copper(II) phosphatehttpscomptoxepagovdashboardDTXSID00872547

4 European Chemicals Agency (ECHA)LICENSEUse of the information documents and data from the ECHA website is subject to the terms and conditions of this Legal Notice and subject to otherbinding limitations provided for under applicable law the information documents and data made available on the ECHA website may be reproduceddistributed andor used totally or in part for non-commercial purposes provided that ECHA is acknowledged as the source Source European ChemicalsAgency httpechaeuropaeu Such acknowledgement must be included in each copy of the material ECHA permits and encourages organisations andindividuals to create links to the ECHA website under the following cumulative conditions Links can only be made to webpages that provide a link to theLegal Notice pagehttpsechaeuropaeuwebguestlegal-notice

Tricopper bis(orthophosphate)httpsechaeuropaeusubstance-information-substanceinfo100029322

Tricopper bis(orthophosphate)httpsechaeuropaeuinformation-on-chemicalscl-inventory-database-disclidetails62531

5 Hazardous Substances Data Bank (HSDB)COPPER(II) PHOSPHATEhttpspubchemncbinlmnihgovsourcehsdb267

6 FDASPL Indexing DataLICENSEUnless otherwise noted the contents of the FDA website (wwwfdagov) both text and graphics are not copyrighted They are in the public domain andmay be republished reprinted and otherwise used freely by anyone without the need to obtain permission from FDA Credit to the US Food and DrugAdministration as the source is appreciated but not requiredhttpswwwfdagovabout-fdaabout-websitewebsite-policieslinking

N8NP6FR80RhttpswwwfdagovForIndustryDataStandardsSubstanceRegistrationSystem-UniqueIngredientIdentifierUNII

7 Springer Naturehttpspubchemncbinlmnihgovsubstance341378879

8 Wikipediafosfato de cobre (II)httpsenwikipediaorgwikiCopper(II)_phosphate

ALL SOURCES

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2121

9 PubChemhttpspubchemncbinlmnihgov

10 Sistema Globalmente Armonizado de Clasificacioacuten y Etiquetado de Productos Quiacutemicos(GHS) de las Naciones UnidasAacuterbol de clasificacioacuten GHShttpwwwuneceorgtransdangerpublighsghs_welcome_ehtml

11 PATENTSCOPE (OMPI)SID 403419907httpspubchemncbinlmnihgovsubstance403419907

Page 11: Fosfato de cobre (II) - Universidad Veracruzana

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1121

7 Use and Manufacturing

71 Uses

Fungicide catalyst for org reactions fertilizer emulsifier corrosion inhibitor for phosphoric acid protectant for metal surfacesagainst oxidation

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

Fungicide formerGerhartz W (exec ed) Ullmanns Encyclopedia of Industrial Chemistry 5th edVol A1 Deerfield Beach FL VCH Publishers 1985 to Present p VA7(1986) 585

Hazardous Substances Data Bank (HSDB)

MEDICATION

Hazardous Substances Data Bank (HSDB)

MEDICATION (VET)

Hazardous Substances Data Bank (HSDB)

72 Methods of Manufacturing

Preparation from copper sulfate and diammonium hydrogen phosphate Klement Haselbeck Z Anorg Allgem Chem 334 27(1964)

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

Prepared by reaction of copper(II) sulfate solution with soluble alkali phosphatesGerhartz W (exec ed) Ullmanns Encyclopedia of Industrial Chemistry 5th edVol A1 Deerfield Beach FL VCH Publishers 1985 to Present p VA7(1986) 585

Hazardous Substances Data Bank (HSDB)

73 General Manufacturing Information

EPA TSCA Commercial Activity Status

Phosphoric acid copper(2+) salt (23) ACTIVEhttpswwwepagovtsca-inventory

EPA Chemicals under the TSCA

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1221

8 Safety and Hazards

81 Hazards Identification

811 GHS Classification

Pictogram(s)

Signal Warning

GHS Hazard Statements

Aggregated GHS information provided by 13 companies from 5 notifications to the ECHA CampL Inventory Eachnotification may be associated with multiple companies

H302 (3077) Harmful if swallowed [Warning Acute toxicity oral]

H315 (3077) Causes skin irritation [Warning Skin corrosionirritation]

H319 (2308) Causes serious eye irritation [Warning Serious eye damageeye irritation]

H335 (2308) May cause respiratory irritation [Warning Specific target organ toxicity single exposureRespiratory tract irritation]

H410 (1538) Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquaticenvironment long-term hazard]

H412 (3077) Harmful to aquatic life with long lasting effects [Hazardous to the aquatic environment long-term hazard]

Information may vary between notifications depending on impurities additives and other factors Thepercentage value in parenthesis indicates the notified classification ratio from companies that provide hazardcodes Only hazard codes with percentage values above 10 are shown

Precautionary StatementCodes

P261 P264 P270 P271 P273 P280 P301+P312 P302+P352 P304+P340 P305+P351+P338 P312 P321P330 P332+P313 P337+P313 P362 P391 P403+P233 P405 and P501

(The corresponding statement to each P-code can be found at the GHS Classification page)

European Chemicals Agency (ECHA)

812 Hazard Classes and Categories

Skin Irrit 2 (3077)

Eye Irrit 2 (2308)

STOT SE 3 (2308)

Aquatic Chronic 1 (1538)

Aquatic Chronic 3 (3077)

European Chemicals Agency (ECHA)

82 Safety and Hazard Properties

821 NIOSH Recommendations

Recommended Exposure Limit 10 Hr Time-Weighted Avg 1 mgcu m Copper (dusts and mists)NIOSH NIOSH Pocket Guide to Chemical Hazards DHHS (NIOSH) Publication No 97-140 Washington DC US Government Printing Office1997 p 76

IrritantEnvironmental

Hazard

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1321

Hazardous Substances Data Bank (HSDB)

83 Accidental Release Measures

831 Disposal Methods

SRP At the time of review criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significantrevision Prior to implementing land disposal of waste residue (including waste sludge) consult with environmental regulatoryagencies for guidance on acceptable disposal practices

Hazardous Substances Data Bank (HSDB)

Group III Containers (both combustible and non-combustible) that previously held organic mercury lead cadmium arsenic orinorganic pesticides should be triple rinsed punctured and disposed of in a sanitary landfill Non-rinsed containers should beencapsulated and buried at a specially designated landfill site Organic mercury lead cadmium arsenic or inorganicpesticides

40 CFR 165 (7188)

Hazardous Substances Data Bank (HSDB)

84 Exposure Control and Personal Protection

841 Threshold Limit Values (TLV)

8 hr Time Weighted Avg (TWA) 1 mgcu m Copper dusts and mists as CuAmerican Conference of Governmental Industrial Hygienists TLVs and BEIs Threshold Limit Values for Chemical Substances and Physical Agentsand Biological Exposure Indices Cincinnati OH 2008 p 21

Hazardous Substances Data Bank (HSDB)

Excursion Limit Recommendation Excursions in worker exposure levels may exceed 3 times the TLV-TWA for no more than atotal of 30 minutes during a work day and under no circumstances should they exceed 5 times the TLV-TWA provided that theTLV-TWA is not exceeded Copper dusts and mists as Cu

American Conference of Governmental Industrial Hygienists TLVs and BEIs Threshold Limit Values for Chemical Substances and Physical Agentsand Biological Exposure Indices Cincinnati OH 2008 p 5

Hazardous Substances Data Bank (HSDB)

842 Acceptable Daily Intakes

The available human data indicate that gastrointestinal distress occurred following ingestion of solutions that contained 5-7 mgof copper and other unknown chemicals as a single dose These data were used to derive a 1 day health advisory of 13 mglwhich when spread over a day should provide protection from these acute effects Since the effects appear to be local irritationthis health advisory is recommended for both the child and the adult There are no data indicating that human exposure tocopper results in chronic toxic effects Furthermore there is a nutritional requirement for copper and acute effects appear to bethe effects of concern Therefore the one day health advisory 13 mgl will also be used as the adjustable acceptable dailyintake Copper

USEPA Drinking Water Criteria Document for Copper (Final Draft) pI-2 (1985) EPA-600X-84-190-1

Hazardous Substances Data Bank (HSDB)

85 Stability and Reactivity

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1421

851 Hazardous Reactivities and Incompatibilities

Solutions of sodium hypobromite are decomposed by powerful catalytic action of cupric ions even as impurities Cupric saltsFire Protection Guide to Hazardous Materials 12 ed Quincy MA National Fire Protection Association 1997 p 491-181

Hazardous Substances Data Bank (HSDB)

86 Regulatory Information

861 Federal Drinking Water Standards

EPA 1300 ugl (Action Level) CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

862 Federal Drinking Water Guidelines

EPA 1000 ugl CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

863 State Drinking Water Guidelines

(AZ) ARIZONA 1300 ugl CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

864 Clean Water Act Requirements

Toxic pollutant designated pursuant to section 307(a)(1) of the Federal Water Pollution Control Act and is subject to effluentlimitations Copper and cmpd

40 CFR 40115 (712000)

Hazardous Substances Data Bank (HSDB)

87 Other Safety Information

871 Toxic Combustion Products

DANGEROUS WHEN HEATED TO DECOMPOSITION CAN EMIT HIGHLY TOXIC FUMES OF PO(X) PHOSPHATESSax NI Dangerous Properties of Industrial Materials 4th ed New York Van Nostrand Reinhold 1975 p 1021

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1521

9 Toxicity

91 Toxicological Information

911 Antidote and Emergency Treatment

Basic treatment Establish a patent airway Suction if necessary Watch for signs of respiratory insufficiency and assist ventilationsif necessary Administer oxygen by nonrebreather mask at 10 to 15 Lmin Monitor for shock and treat if necessary For eyecontamination flush eyes immediately with water Irrigate each eye continuously with normal saline during transport Do notuse emetics For ingestion rinse mouth and administer 5 mlkg up to 200 ml of water for dilution if the patient can swallow hasa strong gag reflex and does not drool Administer activated charcoal Copper and related compounds

Bronstein AC PL Currance Emergency Care for Hazardous Materials Exposure 2nd ed St Louis MO Mosby Lifeline 1994 p 350

Hazardous Substances Data Bank (HSDB)

Advanced treatment Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious Startan IV with lactated Ringers SRP To keep open minimal flow rate Watch for signs of fluid overload For hypotension withsigns of hypovolemia administer fluid cautiously Consider vasopressors if hypotensive with a normal fluid volume Watch forsigns of fluid overload Use proparacaine hydrochloride to assist eye irrigation Copper and related compounds

Bronstein AC PL Currance Emergency Care for Hazardous Materials Exposure 2nd ed St Louis MO Mosby Lifeline 1994 p 351

Hazardous Substances Data Bank (HSDB)

92 Ecological Information

921 Natural Pollution Sources

Basic salts occur in nature as the minerals cornetite dihydrite libethenite phosphorochalcite pseudolibethenitepseudomalachite tagilite

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1621

10 Literature

101 Springer Nature References

Springer Nature

102 Chemical Co-Occurrences in Literature

PubChem

103 Chemical-Gene Co-Occurrences in Literature

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1721

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1821

11 Patents

111 WIPO PATENTSCOPE

Patents are available for this chemical structure

httpspatentscopewipointsearchenresultjsfinchikey=GQDHEYWVLBJKBA-UHFFFAOYSA-H

PATENTSCOPE (WIPO)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1921

12 Classification

121 Ontologies

1211 ChemIDplus

ChemIDplus

1212 UN GHS Classification

UN Globally Harmonized System of Classification and Labelling of Chemicals (GHS)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2021

13 Information Sources

FILTER BY SOURCE

1 ChemIDplusLICENSEhttpswwwnlmnihgovcopyrighthtml

Copper(II) phosphatehttpschemnlmnihgovchemidplussid0007798234

ChemIDplus Chemical Information Classificationhttpschemnlmnihgovchemidplus

2 EPA Chemicals under the TSCALICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Phosphoric acid copper(2+) salt (23)httpswwwepagovchemicals-under-tsca

3 EPA DSSToxLICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Copper(II) phosphatehttpscomptoxepagovdashboardDTXSID00872547

4 European Chemicals Agency (ECHA)LICENSEUse of the information documents and data from the ECHA website is subject to the terms and conditions of this Legal Notice and subject to otherbinding limitations provided for under applicable law the information documents and data made available on the ECHA website may be reproduceddistributed andor used totally or in part for non-commercial purposes provided that ECHA is acknowledged as the source Source European ChemicalsAgency httpechaeuropaeu Such acknowledgement must be included in each copy of the material ECHA permits and encourages organisations andindividuals to create links to the ECHA website under the following cumulative conditions Links can only be made to webpages that provide a link to theLegal Notice pagehttpsechaeuropaeuwebguestlegal-notice

Tricopper bis(orthophosphate)httpsechaeuropaeusubstance-information-substanceinfo100029322

Tricopper bis(orthophosphate)httpsechaeuropaeuinformation-on-chemicalscl-inventory-database-disclidetails62531

5 Hazardous Substances Data Bank (HSDB)COPPER(II) PHOSPHATEhttpspubchemncbinlmnihgovsourcehsdb267

6 FDASPL Indexing DataLICENSEUnless otherwise noted the contents of the FDA website (wwwfdagov) both text and graphics are not copyrighted They are in the public domain andmay be republished reprinted and otherwise used freely by anyone without the need to obtain permission from FDA Credit to the US Food and DrugAdministration as the source is appreciated but not requiredhttpswwwfdagovabout-fdaabout-websitewebsite-policieslinking

N8NP6FR80RhttpswwwfdagovForIndustryDataStandardsSubstanceRegistrationSystem-UniqueIngredientIdentifierUNII

7 Springer Naturehttpspubchemncbinlmnihgovsubstance341378879

8 Wikipediafosfato de cobre (II)httpsenwikipediaorgwikiCopper(II)_phosphate

ALL SOURCES

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2121

9 PubChemhttpspubchemncbinlmnihgov

10 Sistema Globalmente Armonizado de Clasificacioacuten y Etiquetado de Productos Quiacutemicos(GHS) de las Naciones UnidasAacuterbol de clasificacioacuten GHShttpwwwuneceorgtransdangerpublighsghs_welcome_ehtml

11 PATENTSCOPE (OMPI)SID 403419907httpspubchemncbinlmnihgovsubstance403419907

Page 12: Fosfato de cobre (II) - Universidad Veracruzana

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1221

8 Safety and Hazards

81 Hazards Identification

811 GHS Classification

Pictogram(s)

Signal Warning

GHS Hazard Statements

Aggregated GHS information provided by 13 companies from 5 notifications to the ECHA CampL Inventory Eachnotification may be associated with multiple companies

H302 (3077) Harmful if swallowed [Warning Acute toxicity oral]

H315 (3077) Causes skin irritation [Warning Skin corrosionirritation]

H319 (2308) Causes serious eye irritation [Warning Serious eye damageeye irritation]

H335 (2308) May cause respiratory irritation [Warning Specific target organ toxicity single exposureRespiratory tract irritation]

H410 (1538) Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquaticenvironment long-term hazard]

H412 (3077) Harmful to aquatic life with long lasting effects [Hazardous to the aquatic environment long-term hazard]

Information may vary between notifications depending on impurities additives and other factors Thepercentage value in parenthesis indicates the notified classification ratio from companies that provide hazardcodes Only hazard codes with percentage values above 10 are shown

Precautionary StatementCodes

P261 P264 P270 P271 P273 P280 P301+P312 P302+P352 P304+P340 P305+P351+P338 P312 P321P330 P332+P313 P337+P313 P362 P391 P403+P233 P405 and P501

(The corresponding statement to each P-code can be found at the GHS Classification page)

European Chemicals Agency (ECHA)

812 Hazard Classes and Categories

Skin Irrit 2 (3077)

Eye Irrit 2 (2308)

STOT SE 3 (2308)

Aquatic Chronic 1 (1538)

Aquatic Chronic 3 (3077)

European Chemicals Agency (ECHA)

82 Safety and Hazard Properties

821 NIOSH Recommendations

Recommended Exposure Limit 10 Hr Time-Weighted Avg 1 mgcu m Copper (dusts and mists)NIOSH NIOSH Pocket Guide to Chemical Hazards DHHS (NIOSH) Publication No 97-140 Washington DC US Government Printing Office1997 p 76

IrritantEnvironmental

Hazard

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1321

Hazardous Substances Data Bank (HSDB)

83 Accidental Release Measures

831 Disposal Methods

SRP At the time of review criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significantrevision Prior to implementing land disposal of waste residue (including waste sludge) consult with environmental regulatoryagencies for guidance on acceptable disposal practices

Hazardous Substances Data Bank (HSDB)

Group III Containers (both combustible and non-combustible) that previously held organic mercury lead cadmium arsenic orinorganic pesticides should be triple rinsed punctured and disposed of in a sanitary landfill Non-rinsed containers should beencapsulated and buried at a specially designated landfill site Organic mercury lead cadmium arsenic or inorganicpesticides

40 CFR 165 (7188)

Hazardous Substances Data Bank (HSDB)

84 Exposure Control and Personal Protection

841 Threshold Limit Values (TLV)

8 hr Time Weighted Avg (TWA) 1 mgcu m Copper dusts and mists as CuAmerican Conference of Governmental Industrial Hygienists TLVs and BEIs Threshold Limit Values for Chemical Substances and Physical Agentsand Biological Exposure Indices Cincinnati OH 2008 p 21

Hazardous Substances Data Bank (HSDB)

Excursion Limit Recommendation Excursions in worker exposure levels may exceed 3 times the TLV-TWA for no more than atotal of 30 minutes during a work day and under no circumstances should they exceed 5 times the TLV-TWA provided that theTLV-TWA is not exceeded Copper dusts and mists as Cu

American Conference of Governmental Industrial Hygienists TLVs and BEIs Threshold Limit Values for Chemical Substances and Physical Agentsand Biological Exposure Indices Cincinnati OH 2008 p 5

Hazardous Substances Data Bank (HSDB)

842 Acceptable Daily Intakes

The available human data indicate that gastrointestinal distress occurred following ingestion of solutions that contained 5-7 mgof copper and other unknown chemicals as a single dose These data were used to derive a 1 day health advisory of 13 mglwhich when spread over a day should provide protection from these acute effects Since the effects appear to be local irritationthis health advisory is recommended for both the child and the adult There are no data indicating that human exposure tocopper results in chronic toxic effects Furthermore there is a nutritional requirement for copper and acute effects appear to bethe effects of concern Therefore the one day health advisory 13 mgl will also be used as the adjustable acceptable dailyintake Copper

USEPA Drinking Water Criteria Document for Copper (Final Draft) pI-2 (1985) EPA-600X-84-190-1

Hazardous Substances Data Bank (HSDB)

85 Stability and Reactivity

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1421

851 Hazardous Reactivities and Incompatibilities

Solutions of sodium hypobromite are decomposed by powerful catalytic action of cupric ions even as impurities Cupric saltsFire Protection Guide to Hazardous Materials 12 ed Quincy MA National Fire Protection Association 1997 p 491-181

Hazardous Substances Data Bank (HSDB)

86 Regulatory Information

861 Federal Drinking Water Standards

EPA 1300 ugl (Action Level) CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

862 Federal Drinking Water Guidelines

EPA 1000 ugl CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

863 State Drinking Water Guidelines

(AZ) ARIZONA 1300 ugl CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

864 Clean Water Act Requirements

Toxic pollutant designated pursuant to section 307(a)(1) of the Federal Water Pollution Control Act and is subject to effluentlimitations Copper and cmpd

40 CFR 40115 (712000)

Hazardous Substances Data Bank (HSDB)

87 Other Safety Information

871 Toxic Combustion Products

DANGEROUS WHEN HEATED TO DECOMPOSITION CAN EMIT HIGHLY TOXIC FUMES OF PO(X) PHOSPHATESSax NI Dangerous Properties of Industrial Materials 4th ed New York Van Nostrand Reinhold 1975 p 1021

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1521

9 Toxicity

91 Toxicological Information

911 Antidote and Emergency Treatment

Basic treatment Establish a patent airway Suction if necessary Watch for signs of respiratory insufficiency and assist ventilationsif necessary Administer oxygen by nonrebreather mask at 10 to 15 Lmin Monitor for shock and treat if necessary For eyecontamination flush eyes immediately with water Irrigate each eye continuously with normal saline during transport Do notuse emetics For ingestion rinse mouth and administer 5 mlkg up to 200 ml of water for dilution if the patient can swallow hasa strong gag reflex and does not drool Administer activated charcoal Copper and related compounds

Bronstein AC PL Currance Emergency Care for Hazardous Materials Exposure 2nd ed St Louis MO Mosby Lifeline 1994 p 350

Hazardous Substances Data Bank (HSDB)

Advanced treatment Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious Startan IV with lactated Ringers SRP To keep open minimal flow rate Watch for signs of fluid overload For hypotension withsigns of hypovolemia administer fluid cautiously Consider vasopressors if hypotensive with a normal fluid volume Watch forsigns of fluid overload Use proparacaine hydrochloride to assist eye irrigation Copper and related compounds

Bronstein AC PL Currance Emergency Care for Hazardous Materials Exposure 2nd ed St Louis MO Mosby Lifeline 1994 p 351

Hazardous Substances Data Bank (HSDB)

92 Ecological Information

921 Natural Pollution Sources

Basic salts occur in nature as the minerals cornetite dihydrite libethenite phosphorochalcite pseudolibethenitepseudomalachite tagilite

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1621

10 Literature

101 Springer Nature References

Springer Nature

102 Chemical Co-Occurrences in Literature

PubChem

103 Chemical-Gene Co-Occurrences in Literature

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1721

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1821

11 Patents

111 WIPO PATENTSCOPE

Patents are available for this chemical structure

httpspatentscopewipointsearchenresultjsfinchikey=GQDHEYWVLBJKBA-UHFFFAOYSA-H

PATENTSCOPE (WIPO)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1921

12 Classification

121 Ontologies

1211 ChemIDplus

ChemIDplus

1212 UN GHS Classification

UN Globally Harmonized System of Classification and Labelling of Chemicals (GHS)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2021

13 Information Sources

FILTER BY SOURCE

1 ChemIDplusLICENSEhttpswwwnlmnihgovcopyrighthtml

Copper(II) phosphatehttpschemnlmnihgovchemidplussid0007798234

ChemIDplus Chemical Information Classificationhttpschemnlmnihgovchemidplus

2 EPA Chemicals under the TSCALICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Phosphoric acid copper(2+) salt (23)httpswwwepagovchemicals-under-tsca

3 EPA DSSToxLICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Copper(II) phosphatehttpscomptoxepagovdashboardDTXSID00872547

4 European Chemicals Agency (ECHA)LICENSEUse of the information documents and data from the ECHA website is subject to the terms and conditions of this Legal Notice and subject to otherbinding limitations provided for under applicable law the information documents and data made available on the ECHA website may be reproduceddistributed andor used totally or in part for non-commercial purposes provided that ECHA is acknowledged as the source Source European ChemicalsAgency httpechaeuropaeu Such acknowledgement must be included in each copy of the material ECHA permits and encourages organisations andindividuals to create links to the ECHA website under the following cumulative conditions Links can only be made to webpages that provide a link to theLegal Notice pagehttpsechaeuropaeuwebguestlegal-notice

Tricopper bis(orthophosphate)httpsechaeuropaeusubstance-information-substanceinfo100029322

Tricopper bis(orthophosphate)httpsechaeuropaeuinformation-on-chemicalscl-inventory-database-disclidetails62531

5 Hazardous Substances Data Bank (HSDB)COPPER(II) PHOSPHATEhttpspubchemncbinlmnihgovsourcehsdb267

6 FDASPL Indexing DataLICENSEUnless otherwise noted the contents of the FDA website (wwwfdagov) both text and graphics are not copyrighted They are in the public domain andmay be republished reprinted and otherwise used freely by anyone without the need to obtain permission from FDA Credit to the US Food and DrugAdministration as the source is appreciated but not requiredhttpswwwfdagovabout-fdaabout-websitewebsite-policieslinking

N8NP6FR80RhttpswwwfdagovForIndustryDataStandardsSubstanceRegistrationSystem-UniqueIngredientIdentifierUNII

7 Springer Naturehttpspubchemncbinlmnihgovsubstance341378879

8 Wikipediafosfato de cobre (II)httpsenwikipediaorgwikiCopper(II)_phosphate

ALL SOURCES

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2121

9 PubChemhttpspubchemncbinlmnihgov

10 Sistema Globalmente Armonizado de Clasificacioacuten y Etiquetado de Productos Quiacutemicos(GHS) de las Naciones UnidasAacuterbol de clasificacioacuten GHShttpwwwuneceorgtransdangerpublighsghs_welcome_ehtml

11 PATENTSCOPE (OMPI)SID 403419907httpspubchemncbinlmnihgovsubstance403419907

Page 13: Fosfato de cobre (II) - Universidad Veracruzana

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1321

Hazardous Substances Data Bank (HSDB)

83 Accidental Release Measures

831 Disposal Methods

SRP At the time of review criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significantrevision Prior to implementing land disposal of waste residue (including waste sludge) consult with environmental regulatoryagencies for guidance on acceptable disposal practices

Hazardous Substances Data Bank (HSDB)

Group III Containers (both combustible and non-combustible) that previously held organic mercury lead cadmium arsenic orinorganic pesticides should be triple rinsed punctured and disposed of in a sanitary landfill Non-rinsed containers should beencapsulated and buried at a specially designated landfill site Organic mercury lead cadmium arsenic or inorganicpesticides

40 CFR 165 (7188)

Hazardous Substances Data Bank (HSDB)

84 Exposure Control and Personal Protection

841 Threshold Limit Values (TLV)

8 hr Time Weighted Avg (TWA) 1 mgcu m Copper dusts and mists as CuAmerican Conference of Governmental Industrial Hygienists TLVs and BEIs Threshold Limit Values for Chemical Substances and Physical Agentsand Biological Exposure Indices Cincinnati OH 2008 p 21

Hazardous Substances Data Bank (HSDB)

Excursion Limit Recommendation Excursions in worker exposure levels may exceed 3 times the TLV-TWA for no more than atotal of 30 minutes during a work day and under no circumstances should they exceed 5 times the TLV-TWA provided that theTLV-TWA is not exceeded Copper dusts and mists as Cu

American Conference of Governmental Industrial Hygienists TLVs and BEIs Threshold Limit Values for Chemical Substances and Physical Agentsand Biological Exposure Indices Cincinnati OH 2008 p 5

Hazardous Substances Data Bank (HSDB)

842 Acceptable Daily Intakes

The available human data indicate that gastrointestinal distress occurred following ingestion of solutions that contained 5-7 mgof copper and other unknown chemicals as a single dose These data were used to derive a 1 day health advisory of 13 mglwhich when spread over a day should provide protection from these acute effects Since the effects appear to be local irritationthis health advisory is recommended for both the child and the adult There are no data indicating that human exposure tocopper results in chronic toxic effects Furthermore there is a nutritional requirement for copper and acute effects appear to bethe effects of concern Therefore the one day health advisory 13 mgl will also be used as the adjustable acceptable dailyintake Copper

USEPA Drinking Water Criteria Document for Copper (Final Draft) pI-2 (1985) EPA-600X-84-190-1

Hazardous Substances Data Bank (HSDB)

85 Stability and Reactivity

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1421

851 Hazardous Reactivities and Incompatibilities

Solutions of sodium hypobromite are decomposed by powerful catalytic action of cupric ions even as impurities Cupric saltsFire Protection Guide to Hazardous Materials 12 ed Quincy MA National Fire Protection Association 1997 p 491-181

Hazardous Substances Data Bank (HSDB)

86 Regulatory Information

861 Federal Drinking Water Standards

EPA 1300 ugl (Action Level) CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

862 Federal Drinking Water Guidelines

EPA 1000 ugl CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

863 State Drinking Water Guidelines

(AZ) ARIZONA 1300 ugl CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

864 Clean Water Act Requirements

Toxic pollutant designated pursuant to section 307(a)(1) of the Federal Water Pollution Control Act and is subject to effluentlimitations Copper and cmpd

40 CFR 40115 (712000)

Hazardous Substances Data Bank (HSDB)

87 Other Safety Information

871 Toxic Combustion Products

DANGEROUS WHEN HEATED TO DECOMPOSITION CAN EMIT HIGHLY TOXIC FUMES OF PO(X) PHOSPHATESSax NI Dangerous Properties of Industrial Materials 4th ed New York Van Nostrand Reinhold 1975 p 1021

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1521

9 Toxicity

91 Toxicological Information

911 Antidote and Emergency Treatment

Basic treatment Establish a patent airway Suction if necessary Watch for signs of respiratory insufficiency and assist ventilationsif necessary Administer oxygen by nonrebreather mask at 10 to 15 Lmin Monitor for shock and treat if necessary For eyecontamination flush eyes immediately with water Irrigate each eye continuously with normal saline during transport Do notuse emetics For ingestion rinse mouth and administer 5 mlkg up to 200 ml of water for dilution if the patient can swallow hasa strong gag reflex and does not drool Administer activated charcoal Copper and related compounds

Bronstein AC PL Currance Emergency Care for Hazardous Materials Exposure 2nd ed St Louis MO Mosby Lifeline 1994 p 350

Hazardous Substances Data Bank (HSDB)

Advanced treatment Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious Startan IV with lactated Ringers SRP To keep open minimal flow rate Watch for signs of fluid overload For hypotension withsigns of hypovolemia administer fluid cautiously Consider vasopressors if hypotensive with a normal fluid volume Watch forsigns of fluid overload Use proparacaine hydrochloride to assist eye irrigation Copper and related compounds

Bronstein AC PL Currance Emergency Care for Hazardous Materials Exposure 2nd ed St Louis MO Mosby Lifeline 1994 p 351

Hazardous Substances Data Bank (HSDB)

92 Ecological Information

921 Natural Pollution Sources

Basic salts occur in nature as the minerals cornetite dihydrite libethenite phosphorochalcite pseudolibethenitepseudomalachite tagilite

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1621

10 Literature

101 Springer Nature References

Springer Nature

102 Chemical Co-Occurrences in Literature

PubChem

103 Chemical-Gene Co-Occurrences in Literature

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1721

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1821

11 Patents

111 WIPO PATENTSCOPE

Patents are available for this chemical structure

httpspatentscopewipointsearchenresultjsfinchikey=GQDHEYWVLBJKBA-UHFFFAOYSA-H

PATENTSCOPE (WIPO)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1921

12 Classification

121 Ontologies

1211 ChemIDplus

ChemIDplus

1212 UN GHS Classification

UN Globally Harmonized System of Classification and Labelling of Chemicals (GHS)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2021

13 Information Sources

FILTER BY SOURCE

1 ChemIDplusLICENSEhttpswwwnlmnihgovcopyrighthtml

Copper(II) phosphatehttpschemnlmnihgovchemidplussid0007798234

ChemIDplus Chemical Information Classificationhttpschemnlmnihgovchemidplus

2 EPA Chemicals under the TSCALICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Phosphoric acid copper(2+) salt (23)httpswwwepagovchemicals-under-tsca

3 EPA DSSToxLICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Copper(II) phosphatehttpscomptoxepagovdashboardDTXSID00872547

4 European Chemicals Agency (ECHA)LICENSEUse of the information documents and data from the ECHA website is subject to the terms and conditions of this Legal Notice and subject to otherbinding limitations provided for under applicable law the information documents and data made available on the ECHA website may be reproduceddistributed andor used totally or in part for non-commercial purposes provided that ECHA is acknowledged as the source Source European ChemicalsAgency httpechaeuropaeu Such acknowledgement must be included in each copy of the material ECHA permits and encourages organisations andindividuals to create links to the ECHA website under the following cumulative conditions Links can only be made to webpages that provide a link to theLegal Notice pagehttpsechaeuropaeuwebguestlegal-notice

Tricopper bis(orthophosphate)httpsechaeuropaeusubstance-information-substanceinfo100029322

Tricopper bis(orthophosphate)httpsechaeuropaeuinformation-on-chemicalscl-inventory-database-disclidetails62531

5 Hazardous Substances Data Bank (HSDB)COPPER(II) PHOSPHATEhttpspubchemncbinlmnihgovsourcehsdb267

6 FDASPL Indexing DataLICENSEUnless otherwise noted the contents of the FDA website (wwwfdagov) both text and graphics are not copyrighted They are in the public domain andmay be republished reprinted and otherwise used freely by anyone without the need to obtain permission from FDA Credit to the US Food and DrugAdministration as the source is appreciated but not requiredhttpswwwfdagovabout-fdaabout-websitewebsite-policieslinking

N8NP6FR80RhttpswwwfdagovForIndustryDataStandardsSubstanceRegistrationSystem-UniqueIngredientIdentifierUNII

7 Springer Naturehttpspubchemncbinlmnihgovsubstance341378879

8 Wikipediafosfato de cobre (II)httpsenwikipediaorgwikiCopper(II)_phosphate

ALL SOURCES

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2121

9 PubChemhttpspubchemncbinlmnihgov

10 Sistema Globalmente Armonizado de Clasificacioacuten y Etiquetado de Productos Quiacutemicos(GHS) de las Naciones UnidasAacuterbol de clasificacioacuten GHShttpwwwuneceorgtransdangerpublighsghs_welcome_ehtml

11 PATENTSCOPE (OMPI)SID 403419907httpspubchemncbinlmnihgovsubstance403419907

Page 14: Fosfato de cobre (II) - Universidad Veracruzana

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1421

851 Hazardous Reactivities and Incompatibilities

Solutions of sodium hypobromite are decomposed by powerful catalytic action of cupric ions even as impurities Cupric saltsFire Protection Guide to Hazardous Materials 12 ed Quincy MA National Fire Protection Association 1997 p 491-181

Hazardous Substances Data Bank (HSDB)

86 Regulatory Information

861 Federal Drinking Water Standards

EPA 1300 ugl (Action Level) CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

862 Federal Drinking Water Guidelines

EPA 1000 ugl CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

863 State Drinking Water Guidelines

(AZ) ARIZONA 1300 ugl CopperUSEPAOffice of Water Federal-State Toxicology and Risk Analysis Committee (FSTRAC) Summary of State and Federal Drinking Water Standardsand Guidelines (1193) To Present

Hazardous Substances Data Bank (HSDB)

864 Clean Water Act Requirements

Toxic pollutant designated pursuant to section 307(a)(1) of the Federal Water Pollution Control Act and is subject to effluentlimitations Copper and cmpd

40 CFR 40115 (712000)

Hazardous Substances Data Bank (HSDB)

87 Other Safety Information

871 Toxic Combustion Products

DANGEROUS WHEN HEATED TO DECOMPOSITION CAN EMIT HIGHLY TOXIC FUMES OF PO(X) PHOSPHATESSax NI Dangerous Properties of Industrial Materials 4th ed New York Van Nostrand Reinhold 1975 p 1021

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1521

9 Toxicity

91 Toxicological Information

911 Antidote and Emergency Treatment

Basic treatment Establish a patent airway Suction if necessary Watch for signs of respiratory insufficiency and assist ventilationsif necessary Administer oxygen by nonrebreather mask at 10 to 15 Lmin Monitor for shock and treat if necessary For eyecontamination flush eyes immediately with water Irrigate each eye continuously with normal saline during transport Do notuse emetics For ingestion rinse mouth and administer 5 mlkg up to 200 ml of water for dilution if the patient can swallow hasa strong gag reflex and does not drool Administer activated charcoal Copper and related compounds

Bronstein AC PL Currance Emergency Care for Hazardous Materials Exposure 2nd ed St Louis MO Mosby Lifeline 1994 p 350

Hazardous Substances Data Bank (HSDB)

Advanced treatment Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious Startan IV with lactated Ringers SRP To keep open minimal flow rate Watch for signs of fluid overload For hypotension withsigns of hypovolemia administer fluid cautiously Consider vasopressors if hypotensive with a normal fluid volume Watch forsigns of fluid overload Use proparacaine hydrochloride to assist eye irrigation Copper and related compounds

Bronstein AC PL Currance Emergency Care for Hazardous Materials Exposure 2nd ed St Louis MO Mosby Lifeline 1994 p 351

Hazardous Substances Data Bank (HSDB)

92 Ecological Information

921 Natural Pollution Sources

Basic salts occur in nature as the minerals cornetite dihydrite libethenite phosphorochalcite pseudolibethenitepseudomalachite tagilite

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1621

10 Literature

101 Springer Nature References

Springer Nature

102 Chemical Co-Occurrences in Literature

PubChem

103 Chemical-Gene Co-Occurrences in Literature

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1721

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1821

11 Patents

111 WIPO PATENTSCOPE

Patents are available for this chemical structure

httpspatentscopewipointsearchenresultjsfinchikey=GQDHEYWVLBJKBA-UHFFFAOYSA-H

PATENTSCOPE (WIPO)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1921

12 Classification

121 Ontologies

1211 ChemIDplus

ChemIDplus

1212 UN GHS Classification

UN Globally Harmonized System of Classification and Labelling of Chemicals (GHS)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2021

13 Information Sources

FILTER BY SOURCE

1 ChemIDplusLICENSEhttpswwwnlmnihgovcopyrighthtml

Copper(II) phosphatehttpschemnlmnihgovchemidplussid0007798234

ChemIDplus Chemical Information Classificationhttpschemnlmnihgovchemidplus

2 EPA Chemicals under the TSCALICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Phosphoric acid copper(2+) salt (23)httpswwwepagovchemicals-under-tsca

3 EPA DSSToxLICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Copper(II) phosphatehttpscomptoxepagovdashboardDTXSID00872547

4 European Chemicals Agency (ECHA)LICENSEUse of the information documents and data from the ECHA website is subject to the terms and conditions of this Legal Notice and subject to otherbinding limitations provided for under applicable law the information documents and data made available on the ECHA website may be reproduceddistributed andor used totally or in part for non-commercial purposes provided that ECHA is acknowledged as the source Source European ChemicalsAgency httpechaeuropaeu Such acknowledgement must be included in each copy of the material ECHA permits and encourages organisations andindividuals to create links to the ECHA website under the following cumulative conditions Links can only be made to webpages that provide a link to theLegal Notice pagehttpsechaeuropaeuwebguestlegal-notice

Tricopper bis(orthophosphate)httpsechaeuropaeusubstance-information-substanceinfo100029322

Tricopper bis(orthophosphate)httpsechaeuropaeuinformation-on-chemicalscl-inventory-database-disclidetails62531

5 Hazardous Substances Data Bank (HSDB)COPPER(II) PHOSPHATEhttpspubchemncbinlmnihgovsourcehsdb267

6 FDASPL Indexing DataLICENSEUnless otherwise noted the contents of the FDA website (wwwfdagov) both text and graphics are not copyrighted They are in the public domain andmay be republished reprinted and otherwise used freely by anyone without the need to obtain permission from FDA Credit to the US Food and DrugAdministration as the source is appreciated but not requiredhttpswwwfdagovabout-fdaabout-websitewebsite-policieslinking

N8NP6FR80RhttpswwwfdagovForIndustryDataStandardsSubstanceRegistrationSystem-UniqueIngredientIdentifierUNII

7 Springer Naturehttpspubchemncbinlmnihgovsubstance341378879

8 Wikipediafosfato de cobre (II)httpsenwikipediaorgwikiCopper(II)_phosphate

ALL SOURCES

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2121

9 PubChemhttpspubchemncbinlmnihgov

10 Sistema Globalmente Armonizado de Clasificacioacuten y Etiquetado de Productos Quiacutemicos(GHS) de las Naciones UnidasAacuterbol de clasificacioacuten GHShttpwwwuneceorgtransdangerpublighsghs_welcome_ehtml

11 PATENTSCOPE (OMPI)SID 403419907httpspubchemncbinlmnihgovsubstance403419907

Page 15: Fosfato de cobre (II) - Universidad Veracruzana

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1521

9 Toxicity

91 Toxicological Information

911 Antidote and Emergency Treatment

Basic treatment Establish a patent airway Suction if necessary Watch for signs of respiratory insufficiency and assist ventilationsif necessary Administer oxygen by nonrebreather mask at 10 to 15 Lmin Monitor for shock and treat if necessary For eyecontamination flush eyes immediately with water Irrigate each eye continuously with normal saline during transport Do notuse emetics For ingestion rinse mouth and administer 5 mlkg up to 200 ml of water for dilution if the patient can swallow hasa strong gag reflex and does not drool Administer activated charcoal Copper and related compounds

Bronstein AC PL Currance Emergency Care for Hazardous Materials Exposure 2nd ed St Louis MO Mosby Lifeline 1994 p 350

Hazardous Substances Data Bank (HSDB)

Advanced treatment Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious Startan IV with lactated Ringers SRP To keep open minimal flow rate Watch for signs of fluid overload For hypotension withsigns of hypovolemia administer fluid cautiously Consider vasopressors if hypotensive with a normal fluid volume Watch forsigns of fluid overload Use proparacaine hydrochloride to assist eye irrigation Copper and related compounds

Bronstein AC PL Currance Emergency Care for Hazardous Materials Exposure 2nd ed St Louis MO Mosby Lifeline 1994 p 351

Hazardous Substances Data Bank (HSDB)

92 Ecological Information

921 Natural Pollution Sources

Basic salts occur in nature as the minerals cornetite dihydrite libethenite phosphorochalcite pseudolibethenitepseudomalachite tagilite

Budavari S (ed) The Merck Index - An Encyclopedia of Chemicals Drugs and Biologicals Whitehouse Station NJ Merck and Co Inc 1996 p 447

Hazardous Substances Data Bank (HSDB)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1621

10 Literature

101 Springer Nature References

Springer Nature

102 Chemical Co-Occurrences in Literature

PubChem

103 Chemical-Gene Co-Occurrences in Literature

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1721

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1821

11 Patents

111 WIPO PATENTSCOPE

Patents are available for this chemical structure

httpspatentscopewipointsearchenresultjsfinchikey=GQDHEYWVLBJKBA-UHFFFAOYSA-H

PATENTSCOPE (WIPO)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1921

12 Classification

121 Ontologies

1211 ChemIDplus

ChemIDplus

1212 UN GHS Classification

UN Globally Harmonized System of Classification and Labelling of Chemicals (GHS)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2021

13 Information Sources

FILTER BY SOURCE

1 ChemIDplusLICENSEhttpswwwnlmnihgovcopyrighthtml

Copper(II) phosphatehttpschemnlmnihgovchemidplussid0007798234

ChemIDplus Chemical Information Classificationhttpschemnlmnihgovchemidplus

2 EPA Chemicals under the TSCALICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Phosphoric acid copper(2+) salt (23)httpswwwepagovchemicals-under-tsca

3 EPA DSSToxLICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Copper(II) phosphatehttpscomptoxepagovdashboardDTXSID00872547

4 European Chemicals Agency (ECHA)LICENSEUse of the information documents and data from the ECHA website is subject to the terms and conditions of this Legal Notice and subject to otherbinding limitations provided for under applicable law the information documents and data made available on the ECHA website may be reproduceddistributed andor used totally or in part for non-commercial purposes provided that ECHA is acknowledged as the source Source European ChemicalsAgency httpechaeuropaeu Such acknowledgement must be included in each copy of the material ECHA permits and encourages organisations andindividuals to create links to the ECHA website under the following cumulative conditions Links can only be made to webpages that provide a link to theLegal Notice pagehttpsechaeuropaeuwebguestlegal-notice

Tricopper bis(orthophosphate)httpsechaeuropaeusubstance-information-substanceinfo100029322

Tricopper bis(orthophosphate)httpsechaeuropaeuinformation-on-chemicalscl-inventory-database-disclidetails62531

5 Hazardous Substances Data Bank (HSDB)COPPER(II) PHOSPHATEhttpspubchemncbinlmnihgovsourcehsdb267

6 FDASPL Indexing DataLICENSEUnless otherwise noted the contents of the FDA website (wwwfdagov) both text and graphics are not copyrighted They are in the public domain andmay be republished reprinted and otherwise used freely by anyone without the need to obtain permission from FDA Credit to the US Food and DrugAdministration as the source is appreciated but not requiredhttpswwwfdagovabout-fdaabout-websitewebsite-policieslinking

N8NP6FR80RhttpswwwfdagovForIndustryDataStandardsSubstanceRegistrationSystem-UniqueIngredientIdentifierUNII

7 Springer Naturehttpspubchemncbinlmnihgovsubstance341378879

8 Wikipediafosfato de cobre (II)httpsenwikipediaorgwikiCopper(II)_phosphate

ALL SOURCES

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2121

9 PubChemhttpspubchemncbinlmnihgov

10 Sistema Globalmente Armonizado de Clasificacioacuten y Etiquetado de Productos Quiacutemicos(GHS) de las Naciones UnidasAacuterbol de clasificacioacuten GHShttpwwwuneceorgtransdangerpublighsghs_welcome_ehtml

11 PATENTSCOPE (OMPI)SID 403419907httpspubchemncbinlmnihgovsubstance403419907

Page 16: Fosfato de cobre (II) - Universidad Veracruzana

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1621

10 Literature

101 Springer Nature References

Springer Nature

102 Chemical Co-Occurrences in Literature

PubChem

103 Chemical-Gene Co-Occurrences in Literature

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1721

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1821

11 Patents

111 WIPO PATENTSCOPE

Patents are available for this chemical structure

httpspatentscopewipointsearchenresultjsfinchikey=GQDHEYWVLBJKBA-UHFFFAOYSA-H

PATENTSCOPE (WIPO)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1921

12 Classification

121 Ontologies

1211 ChemIDplus

ChemIDplus

1212 UN GHS Classification

UN Globally Harmonized System of Classification and Labelling of Chemicals (GHS)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2021

13 Information Sources

FILTER BY SOURCE

1 ChemIDplusLICENSEhttpswwwnlmnihgovcopyrighthtml

Copper(II) phosphatehttpschemnlmnihgovchemidplussid0007798234

ChemIDplus Chemical Information Classificationhttpschemnlmnihgovchemidplus

2 EPA Chemicals under the TSCALICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Phosphoric acid copper(2+) salt (23)httpswwwepagovchemicals-under-tsca

3 EPA DSSToxLICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Copper(II) phosphatehttpscomptoxepagovdashboardDTXSID00872547

4 European Chemicals Agency (ECHA)LICENSEUse of the information documents and data from the ECHA website is subject to the terms and conditions of this Legal Notice and subject to otherbinding limitations provided for under applicable law the information documents and data made available on the ECHA website may be reproduceddistributed andor used totally or in part for non-commercial purposes provided that ECHA is acknowledged as the source Source European ChemicalsAgency httpechaeuropaeu Such acknowledgement must be included in each copy of the material ECHA permits and encourages organisations andindividuals to create links to the ECHA website under the following cumulative conditions Links can only be made to webpages that provide a link to theLegal Notice pagehttpsechaeuropaeuwebguestlegal-notice

Tricopper bis(orthophosphate)httpsechaeuropaeusubstance-information-substanceinfo100029322

Tricopper bis(orthophosphate)httpsechaeuropaeuinformation-on-chemicalscl-inventory-database-disclidetails62531

5 Hazardous Substances Data Bank (HSDB)COPPER(II) PHOSPHATEhttpspubchemncbinlmnihgovsourcehsdb267

6 FDASPL Indexing DataLICENSEUnless otherwise noted the contents of the FDA website (wwwfdagov) both text and graphics are not copyrighted They are in the public domain andmay be republished reprinted and otherwise used freely by anyone without the need to obtain permission from FDA Credit to the US Food and DrugAdministration as the source is appreciated but not requiredhttpswwwfdagovabout-fdaabout-websitewebsite-policieslinking

N8NP6FR80RhttpswwwfdagovForIndustryDataStandardsSubstanceRegistrationSystem-UniqueIngredientIdentifierUNII

7 Springer Naturehttpspubchemncbinlmnihgovsubstance341378879

8 Wikipediafosfato de cobre (II)httpsenwikipediaorgwikiCopper(II)_phosphate

ALL SOURCES

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2121

9 PubChemhttpspubchemncbinlmnihgov

10 Sistema Globalmente Armonizado de Clasificacioacuten y Etiquetado de Productos Quiacutemicos(GHS) de las Naciones UnidasAacuterbol de clasificacioacuten GHShttpwwwuneceorgtransdangerpublighsghs_welcome_ehtml

11 PATENTSCOPE (OMPI)SID 403419907httpspubchemncbinlmnihgovsubstance403419907

Page 17: Fosfato de cobre (II) - Universidad Veracruzana

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1721

PubChem

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1821

11 Patents

111 WIPO PATENTSCOPE

Patents are available for this chemical structure

httpspatentscopewipointsearchenresultjsfinchikey=GQDHEYWVLBJKBA-UHFFFAOYSA-H

PATENTSCOPE (WIPO)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1921

12 Classification

121 Ontologies

1211 ChemIDplus

ChemIDplus

1212 UN GHS Classification

UN Globally Harmonized System of Classification and Labelling of Chemicals (GHS)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2021

13 Information Sources

FILTER BY SOURCE

1 ChemIDplusLICENSEhttpswwwnlmnihgovcopyrighthtml

Copper(II) phosphatehttpschemnlmnihgovchemidplussid0007798234

ChemIDplus Chemical Information Classificationhttpschemnlmnihgovchemidplus

2 EPA Chemicals under the TSCALICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Phosphoric acid copper(2+) salt (23)httpswwwepagovchemicals-under-tsca

3 EPA DSSToxLICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Copper(II) phosphatehttpscomptoxepagovdashboardDTXSID00872547

4 European Chemicals Agency (ECHA)LICENSEUse of the information documents and data from the ECHA website is subject to the terms and conditions of this Legal Notice and subject to otherbinding limitations provided for under applicable law the information documents and data made available on the ECHA website may be reproduceddistributed andor used totally or in part for non-commercial purposes provided that ECHA is acknowledged as the source Source European ChemicalsAgency httpechaeuropaeu Such acknowledgement must be included in each copy of the material ECHA permits and encourages organisations andindividuals to create links to the ECHA website under the following cumulative conditions Links can only be made to webpages that provide a link to theLegal Notice pagehttpsechaeuropaeuwebguestlegal-notice

Tricopper bis(orthophosphate)httpsechaeuropaeusubstance-information-substanceinfo100029322

Tricopper bis(orthophosphate)httpsechaeuropaeuinformation-on-chemicalscl-inventory-database-disclidetails62531

5 Hazardous Substances Data Bank (HSDB)COPPER(II) PHOSPHATEhttpspubchemncbinlmnihgovsourcehsdb267

6 FDASPL Indexing DataLICENSEUnless otherwise noted the contents of the FDA website (wwwfdagov) both text and graphics are not copyrighted They are in the public domain andmay be republished reprinted and otherwise used freely by anyone without the need to obtain permission from FDA Credit to the US Food and DrugAdministration as the source is appreciated but not requiredhttpswwwfdagovabout-fdaabout-websitewebsite-policieslinking

N8NP6FR80RhttpswwwfdagovForIndustryDataStandardsSubstanceRegistrationSystem-UniqueIngredientIdentifierUNII

7 Springer Naturehttpspubchemncbinlmnihgovsubstance341378879

8 Wikipediafosfato de cobre (II)httpsenwikipediaorgwikiCopper(II)_phosphate

ALL SOURCES

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2121

9 PubChemhttpspubchemncbinlmnihgov

10 Sistema Globalmente Armonizado de Clasificacioacuten y Etiquetado de Productos Quiacutemicos(GHS) de las Naciones UnidasAacuterbol de clasificacioacuten GHShttpwwwuneceorgtransdangerpublighsghs_welcome_ehtml

11 PATENTSCOPE (OMPI)SID 403419907httpspubchemncbinlmnihgovsubstance403419907

Page 18: Fosfato de cobre (II) - Universidad Veracruzana

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1821

11 Patents

111 WIPO PATENTSCOPE

Patents are available for this chemical structure

httpspatentscopewipointsearchenresultjsfinchikey=GQDHEYWVLBJKBA-UHFFFAOYSA-H

PATENTSCOPE (WIPO)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1921

12 Classification

121 Ontologies

1211 ChemIDplus

ChemIDplus

1212 UN GHS Classification

UN Globally Harmonized System of Classification and Labelling of Chemicals (GHS)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2021

13 Information Sources

FILTER BY SOURCE

1 ChemIDplusLICENSEhttpswwwnlmnihgovcopyrighthtml

Copper(II) phosphatehttpschemnlmnihgovchemidplussid0007798234

ChemIDplus Chemical Information Classificationhttpschemnlmnihgovchemidplus

2 EPA Chemicals under the TSCALICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Phosphoric acid copper(2+) salt (23)httpswwwepagovchemicals-under-tsca

3 EPA DSSToxLICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Copper(II) phosphatehttpscomptoxepagovdashboardDTXSID00872547

4 European Chemicals Agency (ECHA)LICENSEUse of the information documents and data from the ECHA website is subject to the terms and conditions of this Legal Notice and subject to otherbinding limitations provided for under applicable law the information documents and data made available on the ECHA website may be reproduceddistributed andor used totally or in part for non-commercial purposes provided that ECHA is acknowledged as the source Source European ChemicalsAgency httpechaeuropaeu Such acknowledgement must be included in each copy of the material ECHA permits and encourages organisations andindividuals to create links to the ECHA website under the following cumulative conditions Links can only be made to webpages that provide a link to theLegal Notice pagehttpsechaeuropaeuwebguestlegal-notice

Tricopper bis(orthophosphate)httpsechaeuropaeusubstance-information-substanceinfo100029322

Tricopper bis(orthophosphate)httpsechaeuropaeuinformation-on-chemicalscl-inventory-database-disclidetails62531

5 Hazardous Substances Data Bank (HSDB)COPPER(II) PHOSPHATEhttpspubchemncbinlmnihgovsourcehsdb267

6 FDASPL Indexing DataLICENSEUnless otherwise noted the contents of the FDA website (wwwfdagov) both text and graphics are not copyrighted They are in the public domain andmay be republished reprinted and otherwise used freely by anyone without the need to obtain permission from FDA Credit to the US Food and DrugAdministration as the source is appreciated but not requiredhttpswwwfdagovabout-fdaabout-websitewebsite-policieslinking

N8NP6FR80RhttpswwwfdagovForIndustryDataStandardsSubstanceRegistrationSystem-UniqueIngredientIdentifierUNII

7 Springer Naturehttpspubchemncbinlmnihgovsubstance341378879

8 Wikipediafosfato de cobre (II)httpsenwikipediaorgwikiCopper(II)_phosphate

ALL SOURCES

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2121

9 PubChemhttpspubchemncbinlmnihgov

10 Sistema Globalmente Armonizado de Clasificacioacuten y Etiquetado de Productos Quiacutemicos(GHS) de las Naciones UnidasAacuterbol de clasificacioacuten GHShttpwwwuneceorgtransdangerpublighsghs_welcome_ehtml

11 PATENTSCOPE (OMPI)SID 403419907httpspubchemncbinlmnihgovsubstance403419907

Page 19: Fosfato de cobre (II) - Universidad Veracruzana

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 1921

12 Classification

121 Ontologies

1211 ChemIDplus

ChemIDplus

1212 UN GHS Classification

UN Globally Harmonized System of Classification and Labelling of Chemicals (GHS)

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2021

13 Information Sources

FILTER BY SOURCE

1 ChemIDplusLICENSEhttpswwwnlmnihgovcopyrighthtml

Copper(II) phosphatehttpschemnlmnihgovchemidplussid0007798234

ChemIDplus Chemical Information Classificationhttpschemnlmnihgovchemidplus

2 EPA Chemicals under the TSCALICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Phosphoric acid copper(2+) salt (23)httpswwwepagovchemicals-under-tsca

3 EPA DSSToxLICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Copper(II) phosphatehttpscomptoxepagovdashboardDTXSID00872547

4 European Chemicals Agency (ECHA)LICENSEUse of the information documents and data from the ECHA website is subject to the terms and conditions of this Legal Notice and subject to otherbinding limitations provided for under applicable law the information documents and data made available on the ECHA website may be reproduceddistributed andor used totally or in part for non-commercial purposes provided that ECHA is acknowledged as the source Source European ChemicalsAgency httpechaeuropaeu Such acknowledgement must be included in each copy of the material ECHA permits and encourages organisations andindividuals to create links to the ECHA website under the following cumulative conditions Links can only be made to webpages that provide a link to theLegal Notice pagehttpsechaeuropaeuwebguestlegal-notice

Tricopper bis(orthophosphate)httpsechaeuropaeusubstance-information-substanceinfo100029322

Tricopper bis(orthophosphate)httpsechaeuropaeuinformation-on-chemicalscl-inventory-database-disclidetails62531

5 Hazardous Substances Data Bank (HSDB)COPPER(II) PHOSPHATEhttpspubchemncbinlmnihgovsourcehsdb267

6 FDASPL Indexing DataLICENSEUnless otherwise noted the contents of the FDA website (wwwfdagov) both text and graphics are not copyrighted They are in the public domain andmay be republished reprinted and otherwise used freely by anyone without the need to obtain permission from FDA Credit to the US Food and DrugAdministration as the source is appreciated but not requiredhttpswwwfdagovabout-fdaabout-websitewebsite-policieslinking

N8NP6FR80RhttpswwwfdagovForIndustryDataStandardsSubstanceRegistrationSystem-UniqueIngredientIdentifierUNII

7 Springer Naturehttpspubchemncbinlmnihgovsubstance341378879

8 Wikipediafosfato de cobre (II)httpsenwikipediaorgwikiCopper(II)_phosphate

ALL SOURCES

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2121

9 PubChemhttpspubchemncbinlmnihgov

10 Sistema Globalmente Armonizado de Clasificacioacuten y Etiquetado de Productos Quiacutemicos(GHS) de las Naciones UnidasAacuterbol de clasificacioacuten GHShttpwwwuneceorgtransdangerpublighsghs_welcome_ehtml

11 PATENTSCOPE (OMPI)SID 403419907httpspubchemncbinlmnihgovsubstance403419907

Page 20: Fosfato de cobre (II) - Universidad Veracruzana

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2021

13 Information Sources

FILTER BY SOURCE

1 ChemIDplusLICENSEhttpswwwnlmnihgovcopyrighthtml

Copper(II) phosphatehttpschemnlmnihgovchemidplussid0007798234

ChemIDplus Chemical Information Classificationhttpschemnlmnihgovchemidplus

2 EPA Chemicals under the TSCALICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Phosphoric acid copper(2+) salt (23)httpswwwepagovchemicals-under-tsca

3 EPA DSSToxLICENSEhttpswwwepagovprivacyprivacy-act-laws-policies-and-resources

Copper(II) phosphatehttpscomptoxepagovdashboardDTXSID00872547

4 European Chemicals Agency (ECHA)LICENSEUse of the information documents and data from the ECHA website is subject to the terms and conditions of this Legal Notice and subject to otherbinding limitations provided for under applicable law the information documents and data made available on the ECHA website may be reproduceddistributed andor used totally or in part for non-commercial purposes provided that ECHA is acknowledged as the source Source European ChemicalsAgency httpechaeuropaeu Such acknowledgement must be included in each copy of the material ECHA permits and encourages organisations andindividuals to create links to the ECHA website under the following cumulative conditions Links can only be made to webpages that provide a link to theLegal Notice pagehttpsechaeuropaeuwebguestlegal-notice

Tricopper bis(orthophosphate)httpsechaeuropaeusubstance-information-substanceinfo100029322

Tricopper bis(orthophosphate)httpsechaeuropaeuinformation-on-chemicalscl-inventory-database-disclidetails62531

5 Hazardous Substances Data Bank (HSDB)COPPER(II) PHOSPHATEhttpspubchemncbinlmnihgovsourcehsdb267

6 FDASPL Indexing DataLICENSEUnless otherwise noted the contents of the FDA website (wwwfdagov) both text and graphics are not copyrighted They are in the public domain andmay be republished reprinted and otherwise used freely by anyone without the need to obtain permission from FDA Credit to the US Food and DrugAdministration as the source is appreciated but not requiredhttpswwwfdagovabout-fdaabout-websitewebsite-policieslinking

N8NP6FR80RhttpswwwfdagovForIndustryDataStandardsSubstanceRegistrationSystem-UniqueIngredientIdentifierUNII

7 Springer Naturehttpspubchemncbinlmnihgovsubstance341378879

8 Wikipediafosfato de cobre (II)httpsenwikipediaorgwikiCopper(II)_phosphate

ALL SOURCES

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2121

9 PubChemhttpspubchemncbinlmnihgov

10 Sistema Globalmente Armonizado de Clasificacioacuten y Etiquetado de Productos Quiacutemicos(GHS) de las Naciones UnidasAacuterbol de clasificacioacuten GHShttpwwwuneceorgtransdangerpublighsghs_welcome_ehtml

11 PATENTSCOPE (OMPI)SID 403419907httpspubchemncbinlmnihgovsubstance403419907

Page 21: Fosfato de cobre (II) - Universidad Veracruzana

2122020 Fosfato de cobre (II) | Cu3 (PO4) 2 - PubChem

httpspubchemncbinlmnihgovcompoundCopper_II_-phosphate 2121

9 PubChemhttpspubchemncbinlmnihgov

10 Sistema Globalmente Armonizado de Clasificacioacuten y Etiquetado de Productos Quiacutemicos(GHS) de las Naciones UnidasAacuterbol de clasificacioacuten GHShttpwwwuneceorgtransdangerpublighsghs_welcome_ehtml

11 PATENTSCOPE (OMPI)SID 403419907httpspubchemncbinlmnihgovsubstance403419907