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    Sapphire Derived OpticalFibers

    Clemson University ResearchFoundation

    [email protected]

    Inventors:John Ballato, Ph.D.

    Department of Materials Science and EngineeringClemson University

    Peter Dragic, Ph.D.Department of Electrical and Computer Engineering

    University of Illinois at Urbana-Champaign

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    Background/Problem

    www.clemson.edu/curf

    Optical fibers are enablers of a wide varietyof modern technologies.

    Conventional fibers are nearing their limitsas the demands of modern communicationand laser systems are growing rapidly.

    A variety of materials, such as aluminumoxide, are known to enhance performancebut have not been able to be manufactured

    in scalable and low cost manner.

    What is needed are new materialcompositions and methods that enablehigher performance optical fibers.

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    The Invention

    Key Features:

    Industry acceptedmanufacturing technique

    Commodity / low costmaterials that previouslyhave not been amenable tofiber optic manufacturing

    www.clemson.edu/curf

    Scalable Sapphire Derived Optical Fibers

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    Example Applications

    www.clemson.edu/curf

    MilitaryLasers

    MaterialsProcessing

    Optical FiberSensors

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    The Science Uses a molten-core technique to

    add sapphire (Al 2O3) to silica(SiO2) glass

    Addition of alumina to the silica

    fibers greatly enhances thefibers immunity to selectedoptical nonlinearities

    The core material melts at atemperature where the claddingglass draws into fiber

    The high quench rates permitpreviously unrealizable corecompositions to be directlyobtained in fiber form

    www.clemson.edu/curf

    Figure 1. Pure sapphire (Al 2O3) rodsleeved into a large thick-walled SiO 2 tube and drawn into fiber.

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    Ongoing/Future Development Steps

    www.clemson.edu/curf

    Reduce optical attenuation; presently about 100dB/km, which is reasonable for many practicalapplications but lower is always better

    Identification of other core compositions that enableadditional reductions in optical nonlinearities (SBS)as well as reduced thermal effects

    Active versions made into fiber-based lasers andamplifiers

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    The Market

    www.clemson.edu/curf

    MilitaryLasers

    MaterialsProcessing

    Optical FiberSensors

    $4 billion dollars by2017

    20.3% Annualgrowth rate

    Source: ElectroniCast , Aptos, CA,USA

    $2 billion

    37% Growth in2010

    Source: T2+2 Market Overview:Lasers in Manufacturing

    $419 million 2.7% Annual growth

    rate in 2012Note: Includes scientific research and

    military markets

    Source: The Laser Focus World quantitative market survey

    http://www.electronicast.com/http://www.electronicast.com/
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    Summary of Benefits Invention overcomes limitations of current options Continuous process High speed manufacturing compatible with existing commercial processes Low cost precursor materials enable scalability and competitive pricing for

    entry into new markets Record low Brillouin scattering; which is a limit in present high power

    systems

    Attractive Markets Large markets Diverse applications Significant growth due to industry demands

    Intellectual Property Provisional patent has been filed

    www.clemson.edu/curf

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    Related Publications J. Ballato, et al., On the Fabrication of All-Glass Optical Fibers from Crystals, Journal of Applied Physics 105 , Article 053110 (2009).

    P. Dragic, P.-C. Law, J. Ballato, T. Hawkins, and P. Foy, Brillouin Spectroscopy of YAG-Derived Optical Fibers,Optics Express 18 , 10055 10067 (2010).

    P. Dragic, J. Ballato, T. Hawkins, and P. Foy, Feasibility of Yb:YAG-Derived Silicate Fibers as Gain Media,Optical Materials 34 , 1294 1298 (2012).

    P. Dragic, T. Hawkins, S. Morris, and J. Ballato, Sapphire-derived all-glass optical fibers, Nature Photonics 6, 629 - 635 (2012).

    P. Dragic, J. Ballato, S. Morris, and T. Hawkins, Pockels Coefficients of Alumina in Aluminosilicate OpticalFiber, Journal of the Optical Society of America B 30 , 244 250 (2013).

    P. Dragic, C. Kucera, J. Furtick, J. Guerrier, T. Hawkins, and J. Ballato, Brillouin Spectroscopy of a NovelBaria-doped Silica Glass Optical Fiber, Optics Express 21 , 10924 10941 (2013).

    P. Dragic, J. Ballato, S. Morris, and T. Hawkins, The Brillouin gain coefficient of Yb-doped aluminosilicateglass optical fibers, Optical Materials 35 , 1627 1632 (2013). P. Dragic and J. Ballato, Characterization of the Raman Gain Spectra in Yb:YAG-Derived Optical Fibers,

    Electronics Letters 49 , 895 897 (2013); Article highlighted in Inside View section. J. Ballato and P. Dragic, Rethinking Optical Fiber: New Demands, Old Glasses, Invited Feature Article ,

    Journal of the American Ceramic Society 96 , 2675 2692 (2013);

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    Email [email protected] for more informationon this technology

    CURF is seeking commercialization and sponsoredresearch opportunities

    mailto:[email protected]:[email protected]