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    Applying the Splitting Technique to

    determine floatability components

    of an ore sample

    Javier Sierra-Villalobos, Gonzalo Montes-AtenasDepartamento de Ingeniera de Minas

    Facultad de Ciencias Fsicas y Matemticas

    Universidad de Chile

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    Introduction

    Flotation kinetics

    Splitting technique

    Overall assay data

    Mineral liberationRe-floating tests

    Floatability components

    (Gu, 2003)

    (Garca-Zuiga, 1935; Sutherland, 1948, Loveday, 1966; Harris & Chakravarti, 1970; Finch & Dobby, 1990; Trahar,

    1981; Fichera & Chudacek, 1992; King, 2001)

    (Nicol et al., 1983; Deighton,

    2001; Varadi, 2007)

    How much, What and Where is recovered?

    models based on

    computed from

    Release analysis(Dell, 1953)

    based on

    determining

    Slipitting up a sample

    using

    (King & Schneider, 2000)

    MLA

    data reconciliation

    determining the

    state of releaseVariables

    affecting

    flotation

    kinetics

    keeping

    constant

    (Dell, 1953; Runge, 1997 & 2007;Franzidis et al. , 1999)Kinetics models

    compared to

    mass balance

    applying

    (Imaizumi & Inoue, 1963;

    Kelsall, 1961; kelly & Carlson,

    1991)

    (Franzidis et al. , 1999)(De Bruyn & Modi, 1956; Harris &

    Cuadros-Paz, 1978; Chander &

    Polat, 1995)

    (Cutting et al, 1981;

    Sutherland, 1977)

    to determine

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    Laboratory Methodology

    Tail

    Feed

    Con 1

    Con 2

    Con 3

    Con 4

    FFTail

    SFTail

    P80=213 m

    P80=189 m

    P80=255 m

    P80=207 m

    P80=271 m

    R

    P80=151 m

    Con 1

    Con 2

    Con 3

    Con 4

    Con 5

    FFCon

    P80=272 m

    P80=209 m

    Con 1

    Con 2

    Con 3

    Con 4

    Con 5

    SFCon1

    SFCon2

    R

    R

    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    BATCH FLOTATION KINETICSRESULTS

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    Chalcopyrite and pyrite the major

    sulphide minerals in the ore

    High collector dosage promoting the

    flotation of all mineral particles having

    the appropriate liberation of

    chalcopyrite and pyrite (Dell , 1953).

    Kinetics and mineralogy analyses

    0

    20

    40

    60

    80

    0 20 40 60 80

    PyRecovery(%)

    Cpy Recovery (%)

    0 g/t

    40 g/t

    80 g/t

    160 g/t

    + MLA

    results

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    Results 1. FSM Model

    = 1 1 +1

    F-S Model First flotation Con1 Con3

    ks (min-1) 0.3516 0.2660

    kf (min-1) 2.1221 0.0657 3.0998

    ms (wt.%) 0.0248 0.4843

    mf (wt.%) 0.0376 0.5000 0.2499

    Pearson coefficient, R2 0.9999 0.9920 0.9999

    Fast-slow model (FSM) considering mass recovery as sulphides recovery

    0

    20

    40

    60

    80

    0 3 6 9

    Cumulativerecovery(%)

    Time (min)

    0

    20

    40

    60

    80

    0 3 6 9

    Cumulativerecovery(%)

    Time (min)

    0

    2

    4

    6

    8

    0 3 6 9

    Cumulativerecovery(%)

    Time (min)

    First flotatiom Con 1 Con 3

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    y = -0.0274x + 0.5427

    y = -0.1452x + 0.2771

    y = -0.4359x + 0.18020.02

    0.05

    0.14

    0.37

    1.00

    0 2 4 6 8 10

    1-R

    m,s

    (%)

    Time (min)

    Results 2. Imaizumi & Inoues gr. Model

    For Con 3,

    Mass of slow floating components

    ms=(1-M1)*(1-(1-M2))=0.1267

    Mass of intermediate floating component

    mi=(1-M1)*(1-M2)*(1-(1-M3))=0.0596

    Mass of fast floating component

    mf=(1-M1)*(1-M2)*(1-M3)=0.2710

    (*) data obtained using linear

    regression.

    Imaizumi and Inoue First flotation Con 1 Con 3

    k1 (min-1) 0.0014 0.0478 (*) 0.0274

    k2 (min-1) 0.0236 0.1452k3 (min

    -1) 0.4359

    M1 0.9495 0.9710(*) 0.5427

    M2 0.0347 0.2771

    M3 0.1802

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    Results 3.Characterisation of flotation

    products/concentrates

    0

    20

    40

    60

    80

    100

    1 10 100 1000

    Cpy-Pyr

    ecovery(%)

    Size (m)

    Con1 FFCon

    0

    20

    40

    60

    80

    100

    1 10 100 1000

    Cpy-Pyrecovery(%)

    Size (m)

    Con3 SFCon1 SFCon2

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    Conclusions

    The ST was successfully applied to the Ernest Henry ore.

    However, the number of repetitions and the difficulties to keep

    the surface properties make the technique sensitive to the

    operational procedure.

    The floatability components were best described using

    Imaizumi and Inoue s graphical method as it differentiates

    clearly the components. FSM represents the overall results

    accurately, however the floatability components depend onthe number of constant previously established.

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    Conclusions

    Size and liberation studies of the floatability components

    showed dissimilar trends when comparing the concentrates of

    the first flotation test and reflotation tests. These results are

    not in agreement with the study published by Dell in 1953.

    The fast floating materials consisted of fully liberated

    intermediate and coarse particles. The slow floating materialsconsisted of coarse particles exhibiting low liberation and low

    densities as well as of highly liberated fine particles.

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    Acknowledgements

    JKMRC for the financial support of this study

    JKMRC Students: Ana Mara Rojo and Erico Tabosa

    PhD. Marco Vera

    Universidad de Concepcin

    Universidad de Chile