estudio cobres negros_udc

35
 Grupo Geometalurgia Instituto GEA Universidad de Concepción Prof. Sonia Helle (Directora GEA) Dr . Marcos Pincheira Dra. Ursula Kelm MSc. Ing. Oscar Jerez

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  • Grupo Geometalurgia Instituto GEA

    Universidad de Concepcin

    Prof. Sonia Helle (Directora GEA) Dr. Marcos Pincheira Dra. Ursula Kelm MSc. Ing. Oscar Jerez

  • Equipo de Trabajo:

    Instituto GEA: Marcos Pincheira, Sonia Helle, Ursula Kelm y Oscar Jerez

    Instituto de Geologa Econmica Aplicada GEA

    Octubre-2012

    Estudio de mineralizacin de mena de muestras de cabeza mediante mineraloga automatizada y tcnicas complementarias de AAS, DRX y

    EPMA

  • Objetivo del estudio

    Caracterizar mineralgicamente muestras de cabeza y ripio con mineralizacin oxidada de cobre que incluye principalmente fases de cobres negros y filosilicatos portadores de cobre, para conocer su respuesta a la lixiviacin frente a diferentes condiciones xido reductoras y de pH.

  • Fotos macroscpicas de muestras seleccionadas

    0 2 cm

  • El estudio se desarrolla con la complementacin de tcnicas (Microscopa, AAS, DRX y EPMA y Qemscan)

    Identificacin de probables fases de cobre negro mediante microscopa en luz reflejada

    Estudio de la microqumica cuantitativa de las fases de cobre negro y filosilicatos con Cu mediante Microsonda Electrnica (EPMA).

    Modificacin de la SIP y estudio de la mineraloga cuantitativa de mena y ganga va Qemscan

    Estudio de mineralizacin arglica por Difraccin de Rayos X (DRX)

    Estudio de la solubilidad mediante extraccin secuencial

  • 1- Microscopa ptica

    en la fase inicial

    2- Microsonda electrnica en

    la cuantificacin de la

    microqumica

    3- Anlisis Qemscan de la

    mineraloga cuantitativa de

    mena

    4- Difraccin de rayos X en

    la caracterizacin de las

    arcillas

    5- Solubilidad de la mena por

    extraccin secuencial

  • Estudio de Microsonda: Texturas de los cobres negros en imgenes de electrones retro

    dispersados (BSE) de microsonda

  • Resultados de la microqumica cuantitativa de las fases de cobre negro Fe mediante Microsonda Electrnica

    Cu Mn Fe Al Si O Cl Ba Ca K P S Zn

    mximo 11.73 2.98 60.77 3.12 7.21 43.10 0.19 0.09 0.67 n.d. 2.01 0.14 1.15

    mnimo 0.14 0.07 36.12 0.03 0.23 29.57 0.01 0.05 0.03 n.d. 0.03 0.03 0.05

    media 5.13 0.97 49.36 0.90 3.02 37.66 0.04 0.06 0.27 n.d. 0.58 0.07 0.42

    Desviacin estandar 2.55 0.70 6.07 0.69 1.74 2.76 0.04 0.01 0.18 n.d. 0.56 0.03 0.46

    Elemento medidosEstadigrafos bsicos de las fases de cobre negro ricas en hierro

    Tabla 12: Estadgrafos bsicos de las fases de cobre negro ricos en hierro, contenidos en % en peso.

    Cu Mn Fe Si Al Zn P Ba K Ca Cl S O

    Mximo 21.21 5.11 70.66 13.62 4.91 1.57 1.55 0.18 2.31 8.73 1.04 4.86 45.26

    Mnimo 0.00 0.04 23.25 0.03 0.02 0.05 0.02 0.03 0.04 0.05 0.01 0.02 21.00

    Media 2.84 0.60 49.54 2.79 0.75 0.39 0.23 0.08 1.02 0.42 0.09 0.12 35.97

    Desviacin estndar 2.91 0.93 8.10 2.71 0.91 0.37 0.37 0.03 1.17 0.63 0.13 0.33 3.49

    Estadigrafos bsicos de las fases de cobre negro ricas en hierro muestras G-9 a G-25Elementos medidos

    Tabla 13: Estadgrafos bsicos de las fases de cobre negro ricos en manganeso, contenidos en % en

    peso.

  • Resultados de estudio de la microqumica cuantitativa de las fases de cobre negro Mn mediante Microsonda Electrnica

    Cu Mn Fe Al Si O Cl Ba Ca K P S Zn

    mximo 25.84 32.41 5.72 9.41 14.54 44.47 0.33 2.50 3.85 1.45 0.42 2.95 0.17

    mnimo 10.87 8.40 0.10 0.13 0.16 19.70 0.02 0.09 0.48 0.01 0.02 0.03 0.05

    media 19.27 17.63 1.93 3.16 8.33 29.84 0.09 0.61 1.00 0.20 0.08 0.51 0.09

    Desviacin estandar 4.93 7.84 2.10 3.03 4.54 8.63 0.09 0.63 0.94 0.33 0.14 0.81 0.04

    Elemento medidosEstadigrafos bsicos de las fases de cobre negro ricas en manganeso

    Tabla 14: Estadgrafos bsicos de las fases de cobre negro ricos en manganeso, contenidos en % en

    peso.

    Cu Mn Fe Si Al Zn P Ba K Ca Cl S O

    Mximo 24.09 58.28 6.82 7.56 1.90 0.27 0.16 3.43 0.70 4.29 0.21 0.50 41.72

    Mnimo 0.76 12.48 0.06 0.25 0.16 0.06 0.02 0.07 0.02 0.10 0.01 0.04 20.77

    Media 11.64 33.50 0.87 1.57 0.74 0.17 0.06 0.97 0.16 1.35 0.04 0.15 32.75

    Desviacin estndar 5.97 13.75 1.47 1.62 0.44 0.08 0.03 0.81 0.15 0.98 0.05 0.11 5.86

    Elementos medidosEstadigrafos bsicos de las fases de cobre negro ricas en manganeso muestras G-9 a G-25

    Tabla 15: Estadgrafos bsicos de las fases de cobre negro ricos en manganeso, contenidos en % en

    peso.

  • Cu Mn Fe Si Al Zn P Ba K Ca Cl S O

    Mximo 12.65 35.18 38.52 2.98 1.35 0.34 0.26 1.10 0.81 0.89 0.39 0.39 38.13

    Mnimo 0.76 10.31 12.82 0.57 0.24 0.07 0.04 0.11 0.73 0.11 0.05 0.03 28.85

    Media 4.15 22.75 23.59 1.47 0.58 0.23 0.10 0.46 0.76 0.58 0.14 0.21 33.78

    Desviacin estndar 5.12 10.07 8.62 1.00 0.46 0.10 0.08 0.35 0.04 0.41 0.14 0.13 3.23

    Elementos medidosEstadigrafos bsicos de las fases de cobre negro ricas en hierro y manganeso muestras G9 a G-25

    Resultados de estudio de la microqumica cuantitativa de las fases de cobre negro Mn-Fe mediante Microsonda Electrnica

    Tabla 16: Estadgrafos bsicos de las fases de cobre negro ricos en hierro y manganeso, contenidos en

    % en peso.

  • Resultados de la microqumica cuantitativa de los filosilicatos portadores de cobre (arcillas con cobre) mediante Microsonda

    Electrnica

    Remplazo de clivajes por cobre negro

    Izquierda; feldespatos y plagioclasas turbias por la alteracin arglica. Centro; clorita (color

    verde) remplazando antiguos ferromagnesianos. Las zonas opacas (negro) corresponden

    a minerales metlicos, en parte probablemente cobre negro. Derecha; biotita (color caf

    claro) parcialmente remplazada a lo largo del clivaje por cobre negro. Microscopa ptica

    luz transmitida, nicoles paralelos, (100-200 aumentos).

  • Si Na Al Ca K Mg Fe Ti S Cu O Suma

    G-24 area 2 pto 96 109 Caolinita 22.85 0.13 18.03 0.14 0.21 0.43 1.11 n.d. 0.03 0.29 51.90 95.12

    G-24 area 5 pto 112 123 Caolinita 22.84 0.06 19.87 0.09 0.04 0.16 0.34 n.d. n.d. 0.16 54.28 97.84

    G-24 area 5 pto 114 125 Caolinita 23.77 0.14 19.28 0.16 0.10 0.34 0.79 n.d. n.d. 0.22 50.35 95.15

    G-24 area 6 pto 118 129 Caolinita 21.64 0.04 18.95 0.09 0.03 0.07 0.27 n.d. 0.07 0.29 50.73 92.18

    G-24 area 7 pto 124 135 Caolinita 21.14 0.05 18.77 0.04 0.09 0.82 2.09 n.d. 0.04 0.19 51.14 94.36

    G-24 area 7 pto 126 137 Caolinita 22.86 0.04 19.57 0.08 0.04 0.17 0.52 n.d. 0.02 0.36 50.70 94.36

    G-24 area 1 pto 89 103 Caolinita 22.43 0.03 18.83 0.04 0.16 0.13 0.22 n.d. n.d. 0.08 48.89 90.82

    G-24 area 2 pto 99 112 Caolinita 22.07 0.16 18.31 0.11 0.16 0.25 1.15 n.d. 0.03 0.25 46.44 88.91

    G-25 area 1 pto 128 139 Montmorillonita (Fe)? 20.83 0.16 11.80 0.94 0.16 0.72 4.21 n.d. n.d. 0.53 44.73 84.09

    G-25 area 3 pto 143 150 Montmorillonita (Mg)? 22.04 0.27 10.27 1.54 0.26 1.66 0.70 n.d. n.d. 0.46 45.29 82.49

    MDL (%) 0.0388 0.0172 0.0262 0.0231 0.0144 0.0176 0.0332 0.0368 0.0157 0.0394 0.2885

    % PesoMuestra N

    N

    medicinMineral

    n.d. Bajo el lmite de deteccin

    Tabla 29: Minerales de arcilla, como producto de alteracin de otros silicatos, especialmente

    feldespatos.

    Resultados de la microqumica cuantitativa de filosilicatos portadores de cobre

  • Resultados de la microqumica cuantitativa de filosilicatos portadores de cobre Si Na Al Ca K Mg Fe Ti S Cu O Suma

    G-23 Pto 08 37 Biotita-Cu 18.41 0.12 7.98 n.d. 7.76 10.38 7.88 1.80 n.d. 0.18 45.66 100.17

    G-23 Pto 14 F-069 41 Biotita-Cu 17.21 0.13 8.38 0.11 7.37 9.83 8.11 1.80 n.d. 0.85 44.07 97.86

    G-23 Pto 21 47 Biotita-Cu 17.68 0.10 8.72 n.d. 8.21 9.94 7.92 1.67 n.d. 0.11 44.25 98.60

    G-23 Pto 22 48 Biotita-Cu 17.54 0.13 9.06 n.d. 7.81 9.90 7.99 1.80 n.d. 0.32 43.68 98.24

    G-23 Pto 26 51 Biotita-Cu 17.49 0.09 8.79 0.04 7.89 9.60 8.29 2.01 n.d. 0.18 44.33 98.71

    G-19 area 2 pto 50 64 Biotita-Cu 16.50 0.10 8.66 0.03 7.26 7.53 12.46 1.21 n.d. 0.63 44.70 99.07

    G-19 area 3 pto 57 71 Biotita-Cu 16.49 0.16 8.45 0.10 6.67 7.80 12.30 1.54 n.d. 0.86 44.40 98.77

    G-19 area 3 pto 61 75 Biotita-Cu 16.73 0.13 8.83 0.04 7.16 8.35 10.91 1.45 n.d. 0.24 45.16 99.01

    G-24 area 1 pto 88 102 Biotita-Cu 17.29 0.12 8.73 0.05 7.81 7.84 11.52 1.39 n.d. 0.05 42.82 97.62

    G-24 area 4 pto 106 118 Biotita-Cu 17.01 0.08 8.48 0.37 6.98 8.51 8.48 1.91 n.d. 0.06 44.61 96.49

    G-24 area 4 pto 108 120 Biotita-Cu 18.23 0.15 8.81 0.13 7.79 9.51 9.34 1.71 n.d. 0.04 43.15 98.85

    G-24 area 5 pto 109 121 Biotita-Cu 17.67 0.09 8.32 n.d. 7.59 8.55 9.74 1.57 n.d. 0.04 44.77 98.34

    G-24 area 5 pto 113 124 Biotita-Cu 16.72 0.15 8.34 0.06 7.37 8.01 10.86 1.88 n.d. 0.05 41.38 94.81

    G-24 area 6 pto 116 127 Biotita-Cu 17.08 0.20 8.17 0.15 6.38 8.92 10.05 1.85 n.d. 0.99 44.20 97.99

    G-25 area 1 pto 133 142 Biotita-Cu 17.29 0.11 8.25 n.d. 8.06 8.83 10.54 2.22 n.d. 0.07 42.61 97.98

    G-25 area 2 pto 137 145 Biotita-Cu 17.78 0.13 8.26 0.05 7.85 8.46 10.99 2.33 n.d. 0.17 44.09 100.11

    G-25 area 2 pto 139 147 Biotita-Cu 16.59 0.16 8.29 0.04 7.56 8.31 10.71 2.36 n.d. 0.31 44.52 98.85

    G-25 area 4 pto 149 154 Biotita-Cu 16.98 0.11 8.21 0.16 6.62 8.69 9.35 1.89 n.d. 0.90 45.50 98.40

    G-25 area 5 pto 153 158 Biotita-Cu 17.65 0.26 8.55 0.13 7.35 8.65 10.48 1.80 n.d. 0.17 43.73 98.77

    G-25 area 5 pto 154 159 Biotita-Cu 17.71 0.18 8.19 0.08 7.51 8.44 10.43 1.70 n.d. 0.25 43.39 97.88

    G-25 area 6 pto 157 162 Biotita-Cu 17.10 0.19 8.55 0.16 6.81 8.36 10.82 2.24 n.d. 0.39 43.35 97.97

    G-25 area 6 pto 162 165 Biotita-Cu 17.24 0.17 8.14 0.13 6.88 8.53 9.72 1.56 n.d. 0.41 41.68 94.46

    G-23 Pto 15 F069 42 Biotita-Cu 17.38 0.14 7.87 0.11 6.47 9.69 7.75 1.96 n.d. 1.79 45.07 98.22

    G-25 area 4 pto 150 155 Biotita-Cu 16.39 0.17 7.79 0.28 4.35 8.17 9.63 2.16 n.d. 4.19 44.78 97.90

    G-23 Pto 07 36 Biotita-Cu 20.15 0.12 12.09 0.27 2.29 4.87 4.49 0.32 n.d. 7.28 44.58 96.46

    G-24 area 6 pto 115 126 Biotita-Cu 16.17 0.21 7.72 0.17 5.86 8.34 9.96 1.84 n.d. 2.77 43.92 96.96

    G-23 Pto 19 F-069 45 Clinicloro-Cu 12.97 0.08 10.38 0.04 n.d. 12.56 12.26 n.d. n.d. 1.32 47.56 97.17

    G-24 area 7 pto 127 138 Clinicloro-Cu 12.99 0.02 9.98 n.d. n.d. 11.24 15.86 0.04 n.d. 0.10 47.50 97.73

    G-25 area 5 pto 156 161 Clinicloro-Cu 12.88 0.03 8.58 0.10 n.d. 9.10 12.59 n.d. n.d. 4.00 44.84 92.12

    G-19 area 2 pto 53 67 Clinicloro-Cu 11.04 n.d. 9.14 0.10 n.d. 10.82 22.04 0.08 n.d. 0.91 44.28 98.41

    G-19 area 2 pto 56 70 Clorita-Cu 20.82 0.24 7.41 1.44 0.15 1.12 4.73 n.d. 0.03 7.91 35.72 79.57

    G-19 area 2 pto 55 69 Clorita-Cu 22.38 0.17 8.24 1.48 0.41 1.42 9.26 n.d. n.d. 3.28 40.99 87.63

    G-22 Pto 15 F-62 11 Muscovita 21.41 0.18 16.29 0.04 8.98 1.99 2.39 n.d. n.d. 0.10 48.47 99.84

    G-23 Pto 29 F-071 53 Muscovita 21.30 0.34 17.50 n.d. 8.55 0.99 1.66 0.22 n.d. 0.06 49.51 100.14

    G-24 area 1 pto 86 100 Muscovita 21.78 0.77 20.20 0.05 7.86 0.10 0.62 0.04 n.d. 0.04 48.58 100.04

    G-19 area 4 pto 67 81 Anfibola-Cu? 23.11 0.37 5.29 1.58 0.75 1.58 15.49 n.d. n.d. 0.70 41.52 90.39

    MDL (%) 0.0388 0.0172 0.0262 0.0231 0.0144 0.0176 0.0332 0.0368 0.0157 0.0394 0.2885

    Muestra NN

    medicinMineral

    % Peso

    Tabla 30: Micas (y ferromagnesiano tipo anfbol) con contenido de Cu.

  • Resultados de la microqumica cuantitativa de filosilicatos portadores de cobre

    Si Na Al Ca K Mg Fe Ti S Cu O Suma

    G-22 pto 04 3 Feldespato-K argilizado 28.92 0.44 9.48 n.d. 13.46 n.d. n.d. n.d. n.d. 0.13 47.58 100.01

    G-22 pto 05 4 Feldespato-K argilizado 28.89 1.15 9.66 0.02 12.09 n.d. n.d. n.d. n.d. 0.04 48.29 100.14

    G-22 pto 06 5 Feldespato-K argilizado 29.27 1.17 9.54 0.05 12.38 n.d. n.d. n.d. n.d. n.d. 48.32 100.73

    G-22 Pto 08 F-62 6 Feldespato-K argilizado 29.50 0.88 9.33 0.05 12.64 n.d. 0.04 n.d. n.d. 0.52 47.83 100.79

    G-22 Pto 10 F-62 8 Feldespato-K argilizado 29.57 0.91 9.59 0.02 12.94 n.d. n.d. n.d. n.d. n.d. 48.26 101.30

    G-22 Pto 12 F-62 9 Feldespato-K argilizado 29.68 1.17 9.59 n.d. 12.42 n.d. n.d. n.d. n.d. n.d. 48.14 101.00

    G-22 Pto 14 F-62 10 Feldespato-K argilizado 29.80 0.77 9.44 n.d. 13.17 n.d. n.d. n.d. n.d. n.d. 48.20 101.38

    G-22 Pto 17 F-64 13 Feldespato-K argilizado 29.89 0.50 9.48 0.02 13.54 n.d. n.d. n.d. n.d. n.d. 47.42 100.85

    G-22 Pto 18 F-64 14 Feldespato-K argilizado 29.30 1.60 9.41 0.04 11.32 n.d. n.d. n.d. n.d. n.d. 47.85 99.52

    G-22 Pto 24 F-65 17 Feldespato-K argilizado 30.83 0.91 9.50 n.d. 12.98 n.d. n.d. n.d. n.d. n.d. 47.32 101.54

    G-22 Pto 27 F-65 19 Feldespato-K argilizado 29.54 0.80 9.08 0.03 12.96 n.d. n.d. n.d. n.d. 0.04 46.86 99.31

    G-22 Pto 29 F-65 20 Feldespato-K argilizado 30.03 0.51 9.23 n.d. 13.33 n.d. n.d. n.d. n.d. 0.04 47.81 100.95

    G-22 Pto 30 F-63 21 Feldespato-K argilizado 30.00 1.11 9.23 n.d. 12.51 0.02 0.06 n.d. n.d. n.d. 47.98 100.91

    G-22 Pto 33 F-63 24 Feldespato-K argilizado 29.77 0.75 9.36 0.03 13.20 n.d. 0.05 n.d. n.d. 0.04 48.32 101.52

    G-22 Pto 36 F-63 26 Feldespato-K argilizado 29.92 1.25 9.29 0.03 12.41 n.d. n.d. n.d. n.d. n.d. 47.46 100.36

    G-22 Pto 37 F-61 27 Feldespato-K argilizado 30.33 1.38 9.06 n.d. 12.30 n.d. 0.04 n.d. n.d. n.d. 48.01 101.12

    G-22 Pto 38 F-61 28 Feldespato-K argilizado 29.62 0.83 8.96 0.03 12.83 n.d. n.d. n.d. n.d. n.d. 47.88 100.15

    G-22 Pto 41 F-61 31 Feldespato-K argilizado 30.08 0.99 9.19 0.08 12.61 n.d. n.d. n.d. n.d. n.d. 47.66 100.62

    G-23 Pto 01 33 Feldespato-K argilizado 29.95 0.91 9.56 n.d. 12.59 n.d. n.d. n.d. n.d. n.d. 47.20 100.21

    G-23 Pto 02 34 Feldespato-K argilizado 30.19 0.96 9.90 0.04 12.36 n.d. 0.04 n.d. n.d. 0.07 48.26 101.81

    G-23 Pto 06 35 Feldespato-K argilizado 29.62 0.27 9.89 0.03 12.77 0.41 0.45 n.d. n.d. 0.27 47.71 101.42

    G-23 Pto 09 38 Feldespato-K argilizado 30.01 0.55 9.77 n.d. 13.05 n.d. n.d. n.d. n.d. 0.05 47.31 100.74

    G-23 Pto 13 40 Feldespato-K argilizado 30.29 1.18 9.73 n.d. 12.27 n.d. 0.04 n.d. n.d. n.d. 47.93 101.45

    G-23 Pto 18 F-069 44 Feldespato-K argilizado 29.75 0.70 9.78 n.d. 12.86 n.d. n.d. n.d. n.d. n.d. 48.05 101.14

    G-23 Pto 23 49 Feldespato-K argilizado 30.14 1.34 9.66 0.03 11.88 n.d. 0.05 n.d. n.d. n.d. 48.24 101.34

    G-23 Pto 25 50 Feldespato-K argilizado 29.79 0.80 9.48 n.d. 12.62 n.d. 0.04 n.d. n.d. n.d. 47.19 99.92

    G-23 Pto 30 F-071 54 Feldespato-K argilizado 29.49 1.14 9.87 0.09 11.85 n.d. 0.05 0.05 n.d. n.d. 47.92 100.46

    G-23 Pto 31 F-071 55 Feldespato-K argilizado 29.75 0.65 9.60 n.d. 12.90 n.d. 0.06 n.d. n.d. n.d. 47.52 100.48

    G-23 Pto 33 56 Feldespato-K argilizado 29.92 1.01 9.57 0.03 12.37 n.d. n.d. n.d. n.d. n.d. 47.70 100.60

    G-23 Pto 36 58 Feldespato-K argilizado 30.13 0.59 9.72 n.d. 13.15 n.d. n.d. n.d. n.d. 0.04 47.55 101.19

    G-24 area 2 pto 94 107 Feldespato-K argilizado 28.99 1.58 9.38 n.d. 10.93 n.d. n.d. n.d. n.d. n.d. 48.26 99.14

    G-24 area 2 pto 100 113 Feldespato-K argilizado 29.52 0.66 9.72 n.d. 12.64 n.d. n.d. n.d. n.d. n.d. 48.91 101.45

    G-24 area 5 pto 111 122 Feldespato-K argilizado 29.51 0.72 9.40 n.d. 12.47 n.d. n.d. n.d. n.d. n.d. 48.27 100.37

    G-24 area 6 pto 119 130 Feldespato-K argilizado 29.41 0.87 9.68 n.d. 12.16 n.d. 0.06 n.d. n.d. 0.04 45.26 97.48

    G-24 area 6 pto 120 131 Feldespato-K argilizado 29.20 0.39 9.53 n.d. 12.72 n.d. 0.05 n.d. n.d. n.d. 47.70 99.59

    G-24 area 7 pto 121 132 Feldespato-K argilizado 29.44 0.42 9.63 n.d. 13.26 0.02 0.12 n.d. n.d. n.d. 48.05 100.94

    G-25 area 1 pto 130 140 Feldespato-K argilizado 30.05 1.03 9.49 n.d. 12.32 n.d. 0.04 n.d. n.d. n.d. 48.76 101.69

    G-25 area 1 pto 131 141 Feldespato-K argilizado 29.68 0.82 9.69 n.d. 12.68 n.d. n.d. n.d. n.d. n.d. 48.05 100.92

    G-25 area 2 pto 138 146 Feldespato-K argilizado 30.23 1.65 9.67 n.d. 11.39 n.d. 0.04 n.d. n.d. n.d. 47.68 100.67

    G-25 area 5 pto 155 160 Feldespato-K argilizado 29.93 1.00 9.67 n.d. 12.36 n.d. 0.05 n.d. n.d. n.d. 47.64 100.65

    G-24 area 7 pto 125 136 Feldespato-K argilizado 27.03 0.19 9.65 n.d. 12.00 0.64 1.54 n.d. n.d. n.d. 42.94 93.99

    G-19 area 4 pto 63 77 Feldespato-K illitizado ? 25.21 0.52 9.05 0.96 1.24 1.73 8.35 n.d. n.d. 0.72 47.41 95.19

    G-24 area 1 pto 87 101 Feldespato-K illitizado ? 24.57 0.53 14.65 0.17 4.89 0.98 1.62 0.05 n.d. 0.25 47.00 94.72

    G-24 area 2 pto 92 105 Feldespato-K illitizado ? 25.51 0.36 8.31 0.21 5.22 0.59 3.37 n.d. 0.09 0.50 37.30 81.46

    G-24 area 2 pto 95 108 Feldespato-K illitizado ? 25.34 0.56 14.71 0.26 2.35 0.97 3.29 n.d. 0.04 0.62 44.62 92.76

    G-24 area 6 pto 117 128 Feldespato-K illitizado ? 22.79 0.10 14.72 0.48 1.93 0.59 1.65 n.d. 0.05 0.26 44.73 87.32

    G-24 area 7 pto 123 134 Feldespato-K illitizado ? 23.41 0.53 15.40 0.16 3.00 0.51 1.17 n.d. 0.02 0.32 43.34 87.85

    G-22 pto 01 1 Plagioclasa caolinizada 29.10 4.92 11.47 2.34 0.20 n.d. 0.07 n.d. n.d. 0.05 52.17 100.32

    G-22 Pto 16 F-64 12 Plagioclasa caolinizada 29.51 7.27 11.09 2.19 0.16 n.d. n.d. n.d. n.d. n.d. 46.30 96.52

    G-22 Pto 20 F-64 15 Plagioclasa caolinizada 18.39 3.44 7.02 2.16 0.28 0.02 0.08 n.d. n.d. 1.07 51.48 83.94

    G-24 area 1 pto 91 104 Plagioclasa caolinizada 24.06 0.22 18.92 0.15 0.78 0.28 0.34 n.d. n.d. 0.28 46.18 91.19

    G-25 area 2 pto 134 143 Plagioclasa caolinizada 21.83 0.17 12.83 0.93 0.31 1.22 2.28 n.d. n.d. 0.62 48.99 89.18

    G-25 area 2 pto 135 144 Plagioclasa caolinizada 22.88 0.20 11.89 1.18 0.36 1.32 2.32 n.d. n.d. 0.60 48.24 89.00

    G-25 area 3 pto 140 148 Plagioclasa caolinizada 22.90 0.16 11.80 1.08 0.31 1.35 3.35 n.d. n.d. 0.44 46.61 88.01

    G-25 area 3 pto 141 149 Plagioclasa caolinizada 22.39 0.19 11.41 1.24 0.28 1.42 2.81 n.d. n.d. 0.56 46.95 87.26

    G-25 area 4 pto 147 153 Plagioclasa caolinizada 21.73 0.19 9.81 1.70 0.29 1.61 1.76 n.d. 0.02 0.46 44.56 82.14

    G-25 area 6 pto 159 163 Plagioclasa caolinizada 23.65 0.96 11.66 1.32 0.63 1.41 1.14 n.d. n.d. 0.74 47.62 89.12

    G-25 area 6 pto 160 164 Plagioclasa caolinizada 23.95 0.26 12.82 1.02 0.43 1.41 2.03 n.d. n.d. 0.69 44.49 87.10

    G-22 pto 03 2 Albita argilizada 29.39 6.35 11.80 2.82 0.11 n.d. 0.07 n.d. n.d. n.d. 50.71 101.26

    G-22 Pto 09 F-62 7 Albita argilizada 29.62 7.41 11.00 1.93 0.93 n.d. 0.05 n.d. n.d. 0.05 50.52 101.52

    G-22 Pto 22 F-64 16 Albita argilizada 30.80 8.46 10.49 1.20 0.23 n.d. n.d. n.d. n.d. 0.06 50.30 101.55

    G-22 Pto 26 F-65 18 Albita argilizada 28.85 7.04 11.79 3.32 0.35 n.d. 0.07 n.d. n.d. n.d. 50.38 101.81

    G-22 Pto 31 F-63 22 Albita argilizada 29.81 8.13 11.02 1.96 0.17 0.02 0.07 n.d. n.d. 0.07 50.73 101.99

    G-22 Pto 32 F-63 23 Albita argilizada 28.95 7.81 10.36 1.92 0.20 n.d. 0.07 n.d. n.d. 1.50 50.66 101.47

    G-22 Pto 35 F-63 25 Albita argilizada 29.57 7.49 11.41 1.96 0.38 0.03 0.22 n.d. n.d. 0.62 49.23 100.91

    G-22 Pto 39 F-61 29 Albita argilizada 29.64 7.85 11.04 2.43 0.14 n.d. n.d. n.d. n.d. n.d. 50.64 101.74

    G-24 area 4 pto 102 115 Albita argilizada 26.17 7.48 11.16 2.19 0.11 n.d. n.d. n.d. n.d. n.d. 54.31 101.42

    G-24 area 4 pto 103 116 Albita argilizada 24.61 7.50 10.14 2.15 0.14 n.d. n.d. n.d. n.d. n.d. 53.69 98.23

    MDL (%) 0.0388 0.0172 0.0262 0.0231 0.0144 0.0176 0.0332 0.0368 0.0157 0.0394 0.2885

    n.d. Bajo el lmite de deteccin

    Muestra N N medicin Mineral% Peso

    Si Na Al Ca K Mg Fe Ti S Cu O Suma

    G-22 pto 04 3 Feldespato-K argilizado 28.92 0.44 9.48 n.d. 13.46 n.d. n.d. n.d. n.d. 0.13 47.58 100.01

    G-22 pto 05 4 Feldespato-K argilizado 28.89 1.15 9.66 0.02 12.09 n.d. n.d. n.d. n.d. 0.04 48.29 100.14

    G-22 pto 06 5 Feldespato-K argilizado 29.27 1.17 9.54 0.05 12.38 n.d. n.d. n.d. n.d. n.d. 48.32 100.73

    G-22 Pto 08 F-62 6 Feldespato-K argilizado 29.50 0.88 9.33 0.05 12.64 n.d. 0.04 n.d. n.d. 0.52 47.83 100.79

    G-22 Pto 10 F-62 8 Feldespato-K argilizado 29.57 0.91 9.59 0.02 12.94 n.d. n.d. n.d. n.d. n.d. 48.26 101.30

    G-22 Pto 12 F-62 9 Feldespato-K argilizado 29.68 1.17 9.59 n.d. 12.42 n.d. n.d. n.d. n.d. n.d. 48.14 101.00

    G-22 Pto 14 F-62 10 Feldespato-K argilizado 29.80 0.77 9.44 n.d. 13.17 n.d. n.d. n.d. n.d. n.d. 48.20 101.38

    G-22 Pto 17 F-64 13 Feldespato-K argilizado 29.89 0.50 9.48 0.02 13.54 n.d. n.d. n.d. n.d. n.d. 47.42 100.85

    G-22 Pto 18 F-64 14 Feldespato-K argilizado 29.30 1.60 9.41 0.04 11.32 n.d. n.d. n.d. n.d. n.d. 47.85 99.52

    G-22 Pto 24 F-65 17 Feldespato-K argilizado 30.83 0.91 9.50 n.d. 12.98 n.d. n.d. n.d. n.d. n.d. 47.32 101.54

    G-22 Pto 27 F-65 19 Feldespato-K argilizado 29.54 0.80 9.08 0.03 12.96 n.d. n.d. n.d. n.d. 0.04 46.86 99.31

    G-22 Pto 29 F-65 20 Feldespato-K argilizado 30.03 0.51 9.23 n.d. 13.33 n.d. n.d. n.d. n.d. 0.04 47.81 100.95

    G-22 Pto 30 F-63 21 Feldespato-K argilizado 30.00 1.11 9.23 n.d. 12.51 0.02 0.06 n.d. n.d. n.d. 47.98 100.91

    G-22 Pto 33 F-63 24 Feldespato-K argilizado 29.77 0.75 9.36 0.03 13.20 n.d. 0.05 n.d. n.d. 0.04 48.32 101.52

    G-22 Pto 36 F-63 26 Feldespato-K argilizado 29.92 1.25 9.29 0.03 12.41 n.d. n.d. n.d. n.d. n.d. 47.46 100.36

    G-22 Pto 37 F-61 27 Feldespato-K argilizado 30.33 1.38 9.06 n.d. 12.30 n.d. 0.04 n.d. n.d. n.d. 48.01 101.12

    G-22 Pto 38 F-61 28 Feldespato-K argilizado 29.62 0.83 8.96 0.03 12.83 n.d. n.d. n.d. n.d. n.d. 47.88 100.15

    G-22 Pto 41 F-61 31 Feldespato-K argilizado 30.08 0.99 9.19 0.08 12.61 n.d. n.d. n.d. n.d. n.d. 47.66 100.62

    G-23 Pto 01 33 Feldespato-K argilizado 29.95 0.91 9.56 n.d. 12.59 n.d. n.d. n.d. n.d. n.d. 47.20 100.21

    G-23 Pto 02 34 Feldespato-K argilizado 30.19 0.96 9.90 0.04 12.36 n.d. 0.04 n.d. n.d. 0.07 48.26 101.81

    G-23 Pto 06 35 Feldespato-K argilizado 29.62 0.27 9.89 0.03 12.77 0.41 0.45 n.d. n.d. 0.27 47.71 101.42

    G-23 Pto 09 38 Feldespato-K argilizado 30.01 0.55 9.77 n.d. 13.05 n.d. n.d. n.d. n.d. 0.05 47.31 100.74

    G-23 Pto 13 40 Feldespato-K argilizado 30.29 1.18 9.73 n.d. 12.27 n.d. 0.04 n.d. n.d. n.d. 47.93 101.45

    G-23 Pto 18 F-069 44 Feldespato-K argilizado 29.75 0.70 9.78 n.d. 12.86 n.d. n.d. n.d. n.d. n.d. 48.05 101.14

    G-23 Pto 23 49 Feldespato-K argilizado 30.14 1.34 9.66 0.03 11.88 n.d. 0.05 n.d. n.d. n.d. 48.24 101.34

    G-23 Pto 25 50 Feldespato-K argilizado 29.79 0.80 9.48 n.d. 12.62 n.d. 0.04 n.d. n.d. n.d. 47.19 99.92

    G-23 Pto 30 F-071 54 Feldespato-K argilizado 29.49 1.14 9.87 0.09 11.85 n.d. 0.05 0.05 n.d. n.d. 47.92 100.46

    G-23 Pto 31 F-071 55 Feldespato-K argilizado 29.75 0.65 9.60 n.d. 12.90 n.d. 0.06 n.d. n.d. n.d. 47.52 100.48

    G-23 Pto 33 56 Feldespato-K argilizado 29.92 1.01 9.57 0.03 12.37 n.d. n.d. n.d. n.d. n.d. 47.70 100.60

    G-23 Pto 36 58 Feldespato-K argilizado 30.13 0.59 9.72 n.d. 13.15 n.d. n.d. n.d. n.d. 0.04 47.55 101.19

    G-24 area 2 pto 94 107 Feldespato-K argilizado 28.99 1.58 9.38 n.d. 10.93 n.d. n.d. n.d. n.d. n.d. 48.26 99.14

    G-24 area 2 pto 100 113 Feldespato-K argilizado 29.52 0.66 9.72 n.d. 12.64 n.d. n.d. n.d. n.d. n.d. 48.91 101.45

    G-24 area 5 pto 111 122 Feldespato-K argilizado 29.51 0.72 9.40 n.d. 12.47 n.d. n.d. n.d. n.d. n.d. 48.27 100.37

    G-24 area 6 pto 119 130 Feldespato-K argilizado 29.41 0.87 9.68 n.d. 12.16 n.d. 0.06 n.d. n.d. 0.04 45.26 97.48

    G-24 area 6 pto 120 131 Feldespato-K argilizado 29.20 0.39 9.53 n.d. 12.72 n.d. 0.05 n.d. n.d. n.d. 47.70 99.59

    G-24 area 7 pto 121 132 Feldespato-K argilizado 29.44 0.42 9.63 n.d. 13.26 0.02 0.12 n.d. n.d. n.d. 48.05 100.94

    G-25 area 1 pto 130 140 Feldespato-K argilizado 30.05 1.03 9.49 n.d. 12.32 n.d. 0.04 n.d. n.d. n.d. 48.76 101.69

    G-25 area 1 pto 131 141 Feldespato-K argilizado 29.68 0.82 9.69 n.d. 12.68 n.d. n.d. n.d. n.d. n.d. 48.05 100.92

    G-25 area 2 pto 138 146 Feldespato-K argilizado 30.23 1.65 9.67 n.d. 11.39 n.d. 0.04 n.d. n.d. n.d. 47.68 100.67

    G-25 area 5 pto 155 160 Feldespato-K argilizado 29.93 1.00 9.67 n.d. 12.36 n.d. 0.05 n.d. n.d. n.d. 47.64 100.65

    G-24 area 7 pto 125 136 Feldespato-K argilizado 27.03 0.19 9.65 n.d. 12.00 0.64 1.54 n.d. n.d. n.d. 42.94 93.99

    G-19 area 4 pto 63 77 Feldespato-K illitizado ? 25.21 0.52 9.05 0.96 1.24 1.73 8.35 n.d. n.d. 0.72 47.41 95.19

    G-24 area 1 pto 87 101 Feldespato-K illitizado ? 24.57 0.53 14.65 0.17 4.89 0.98 1.62 0.05 n.d. 0.25 47.00 94.72

    G-24 area 2 pto 92 105 Feldespato-K illitizado ? 25.51 0.36 8.31 0.21 5.22 0.59 3.37 n.d. 0.09 0.50 37.30 81.46

    G-24 area 2 pto 95 108 Feldespato-K illitizado ? 25.34 0.56 14.71 0.26 2.35 0.97 3.29 n.d. 0.04 0.62 44.62 92.76

    G-24 area 6 pto 117 128 Feldespato-K illitizado ? 22.79 0.10 14.72 0.48 1.93 0.59 1.65 n.d. 0.05 0.26 44.73 87.32

    G-24 area 7 pto 123 134 Feldespato-K illitizado ? 23.41 0.53 15.40 0.16 3.00 0.51 1.17 n.d. 0.02 0.32 43.34 87.85

    G-22 pto 01 1 Plagioclasa caolinizada 29.10 4.92 11.47 2.34 0.20 n.d. 0.07 n.d. n.d. 0.05 52.17 100.32

    G-22 Pto 16 F-64 12 Plagioclasa caolinizada 29.51 7.27 11.09 2.19 0.16 n.d. n.d. n.d. n.d. n.d. 46.30 96.52

    G-22 Pto 20 F-64 15 Plagioclasa caolinizada 18.39 3.44 7.02 2.16 0.28 0.02 0.08 n.d. n.d. 1.07 51.48 83.94

    G-24 area 1 pto 91 104 Plagioclasa caolinizada 24.06 0.22 18.92 0.15 0.78 0.28 0.34 n.d. n.d. 0.28 46.18 91.19

    G-25 area 2 pto 134 143 Plagioclasa caolinizada 21.83 0.17 12.83 0.93 0.31 1.22 2.28 n.d. n.d. 0.62 48.99 89.18

    G-25 area 2 pto 135 144 Plagioclasa caolinizada 22.88 0.20 11.89 1.18 0.36 1.32 2.32 n.d. n.d. 0.60 48.24 89.00

    G-25 area 3 pto 140 148 Plagioclasa caolinizada 22.90 0.16 11.80 1.08 0.31 1.35 3.35 n.d. n.d. 0.44 46.61 88.01

    G-25 area 3 pto 141 149 Plagioclasa caolinizada 22.39 0.19 11.41 1.24 0.28 1.42 2.81 n.d. n.d. 0.56 46.95 87.26

    G-25 area 4 pto 147 153 Plagioclasa caolinizada 21.73 0.19 9.81 1.70 0.29 1.61 1.76 n.d. 0.02 0.46 44.56 82.14

    G-25 area 6 pto 159 163 Plagioclasa caolinizada 23.65 0.96 11.66 1.32 0.63 1.41 1.14 n.d. n.d. 0.74 47.62 89.12

    G-25 area 6 pto 160 164 Plagioclasa caolinizada 23.95 0.26 12.82 1.02 0.43 1.41 2.03 n.d. n.d. 0.69 44.49 87.10

    G-22 pto 03 2 Albita argilizada 29.39 6.35 11.80 2.82 0.11 n.d. 0.07 n.d. n.d. n.d. 50.71 101.26

    G-22 Pto 09 F-62 7 Albita argilizada 29.62 7.41 11.00 1.93 0.93 n.d. 0.05 n.d. n.d. 0.05 50.52 101.52

    G-22 Pto 22 F-64 16 Albita argilizada 30.80 8.46 10.49 1.20 0.23 n.d. n.d. n.d. n.d. 0.06 50.30 101.55

    G-22 Pto 26 F-65 18 Albita argilizada 28.85 7.04 11.79 3.32 0.35 n.d. 0.07 n.d. n.d. n.d. 50.38 101.81

    G-22 Pto 31 F-63 22 Albita argilizada 29.81 8.13 11.02 1.96 0.17 0.02 0.07 n.d. n.d. 0.07 50.73 101.99

    G-22 Pto 32 F-63 23 Albita argilizada 28.95 7.81 10.36 1.92 0.20 n.d. 0.07 n.d. n.d. 1.50 50.66 101.47

    G-22 Pto 35 F-63 25 Albita argilizada 29.57 7.49 11.41 1.96 0.38 0.03 0.22 n.d. n.d. 0.62 49.23 100.91

    G-22 Pto 39 F-61 29 Albita argilizada 29.64 7.85 11.04 2.43 0.14 n.d. n.d. n.d. n.d. n.d. 50.64 101.74

    G-24 area 4 pto 102 115 Albita argilizada 26.17 7.48 11.16 2.19 0.11 n.d. n.d. n.d. n.d. n.d. 54.31 101.42

    G-24 area 4 pto 103 116 Albita argilizada 24.61 7.50 10.14 2.15 0.14 n.d. n.d. n.d. n.d. n.d. 53.69 98.23

    MDL (%) 0.0388 0.0172 0.0262 0.0231 0.0144 0.0176 0.0332 0.0368 0.0157 0.0394 0.2885

    n.d. Bajo el lmite de deteccin

    Muestra N N medicin Mineral% Peso

    Tabla 31: Feldespatos y plagioclasas alterados a minerales de arcillas.

  • Mineraloga Automatizada Qemscan: Modificacin de la base de datos SIP del Qemscan para el estudio de las

    fases de cobre negro y filosilicatos con cobre

    Composicin qumica y

    densidad del mineral

    Condiciones de borde para la

    identificacin por el Qemscan

  • Grupo MineralAgrupamiento mineral

    presente estudioDescripcin

    Background Resina epxica de la briqueta

    Chrysocolla Monominerales de crisocola e interfaces crisocola con otros minerales

    Atacamite

    Fe-Cu Black Copper Fase liberadas de cobre negro rico en Fe e interfaces cobre negro-Fe con otros minerales

    Mn-Cu-Black Copper Fase liberadas de cobre negro rico en Mn e interfaces cobre negro-Fe con otros minerales

    Cu-Clays Agregados de caolinita con contenidos menores de Cu

    Cu-Biotite Agregados de biotita con remplazo de cobre negro en los clivajes

    Cu-Muscovite-Sericite Agregados de micas blancas con remplazo de cobre negro en los clivajes

    Cu-Chlorite-Clinichlore Agregados de clorita con remplazo de cobre negro en los clivajes

    Sulfuros primarios pirita, calcopirita, bornita, molibdenita etc.

    xidos e hidrxidos de Fe-Ti Magnetita, hematita, goethita

    Alumino-silicatos Cuarzo, f ledespatos, plagioclasas, anfiboles, piroxenos etc. No incluidos los f ilosilicatos

    Filosilicatos Biotita, muscovita, arcillas, cloritas etc.

    Carbonatos Monominerales y agregados de calcita e interfases con otras especies

    Sulfatos Yeso, anhidrita, alunita, jarosita

    Otros minerales de ganga Otros minerales de ganga

    Oxidados de cobre

    Filosilicatos con Cu

    Ganga

    Agrupamiento mineral (lista secundaria) utilizada en

    para las fases de cobre negro y filosilicatos con cobre

  • Estudio de la mineraloga cuantitativa de mena y ganga va Qemscan

    Porcentaje en peso de los minerales de

    mena y ganga en las muestras

    G-1 G-2 G-3 G-4 G-5 G-6 G-7 G-8 G-9 G-10 G-11 G-12 G-13 G-14 G-15 G-16 G-17 G-18 G-19 G-20 G-21 G-22 G-23 G-24 G-25 G-26 G-27

    Chrysocolla 3.13 0.30 0.43 0.85 1.69 0.45 0.13 0.22 0.06 0.01 0.03 0.12 0.07 0.02 0.03 0.24 0.24 0.00 0.02 0.00 0.00 2.08 1.10 1.39 0.85 0.21 0.14

    Fe-Cu Black Copper 30.11 5.93 9.54 2.44 3.81 4.62 1.07 0.59 0.95 0.24 0.17 1.22 0.31 0.22 0.16 2.06 3.04 0.51 0.32 0.82 0.44 4.30 1.85 2.39 1.76 0.69 0.52

    Mn-Cu-Black Copper 29.21 0.36 0.21 0.30 1.13 0.02 0.11 0.02 0.01 0.00 0.01 0.23 0.00 0.00 0.00 1.17 0.22 0.31 0.58 2.84 0.11 0.35 0.01 0.23 0.14 0.22 0.10

    Atacamite 0.01 0.01 0.02 0.01 0.01 0.00 0.00 0.02 0.00 0.00 0.00 0.01 0.00 0.00 0.01 0.01 0.01 0.00 0.00 0.01 0.00 0.01 0.01 0.00 0.01 0.00 0.01

    Cu-Chlorite/Clinichlore 0.02 3.26 0.46 0.01 0.02 0.11 0.18 0.19 0.54 0.02 0.06 0.08 0.00 0.01 0.01 0.04 0.94 1.96 0.00 0.02 0.21 0.19 0.68 0.14 0.30 0.36 0.18

    Cu-Muscovite/Sericite 1.22 0.06 0.14 0.09 0.29 0.04 0.05 0.05 0.17 0.00 0.01 0.03 0.01 0.01 0.01 0.06 0.25 0.00 0.00 0.01 0.00 0.42 0.05 0.02 0.11 0.03 0.04

    Cu-Biotite 1.87 2.90 14.73 0.10 0.08 0.28 0.50 0.60 0.50 0.04 0.05 0.64 0.03 0.04 0.04 0.07 1.19 1.61 0.01 0.06 1.61 0.48 0.75 0.34 0.57 0.44 0.21

    Cu- Clay 1.86 0.41 4.30 0.24 0.35 0.70 0.54 2.87 0.29 0.07 0.21 0.77 0.45 0.71 0.46 0.61 0.37 0.01 0.05 0.38 0.01 1.17 1.46 0.52 0.55 0.31 0.21

    Sulphide 0.44 0.02 0.02 0.08 0.11 0.02 0.02 0.01 0.06 0.25 0.09 0.05 0.09 0.17 0.24 0.01 0.02 0.04 0.01 0.16 0.36 0.04 0.01 0.08 0.02 0.15 0.04

    Silicates 13.58 68.91 53.59 74.05 75.22 70.27 72.96 73.15 70.99 71.32 74.77 77.09 80.04 79.74 78.60 34.13 42.36 61.45 65.31 66.56 58.53 70.35 80.36 73.83 80.22 67.15 59.17

    Phyllosilicates 10.83 16.01 15.64 19.18 15.65 22.50 21.05 20.14 22.70 22.15 21.17 17.70 16.87 17.37 18.32 55.64 38.11 22.07 28.75 24.10 30.10 17.61 12.81 18.62 14.35 27.12 34.20

    Sulphates 7.07 0.00 0.07 0.02 0.01 0.02 0.01 0.01 0.07 0.50 0.38 0.04 0.29 0.33 0.38 0.00 0.63 0.00 0.00 0.50 0.01 0.02 0.00 0.00 0.01 0.26 0.27

    Carbonates 0.02 0.00 0.01 0.00 0.01 0.01 0.13 0.21 0.08 0.04 0.03 0.18 0.05 0.00 0.16 0.00 7.34 0.01 0.00 2.71 0.01 2.17 0.00 0.00 0.00 0.14 0.52

    Fe-Ti Oxides 0.25 1.70 0.67 2.25 1.42 0.63 2.79 1.20 3.14 4.86 2.62 1.21 1.45 0.99 1.29 5.88 4.98 10.26 4.40 1.35 7.32 0.71 0.73 2.25 1.00 2.67 3.95

    Other Gangue 0.37 0.13 0.17 0.36 0.20 0.34 0.46 0.71 0.43 0.52 0.41 0.62 0.34 0.38 0.29 0.07 0.30 1.76 0.55 0.47 1.30 0.10 0.19 0.17 0.12 0.24 0.45

    % PesoMineral/Muestra

  • Porcentaje en peso de la mena y filosilicatos portadores de

    cobre en las muestras G-4 a G-6; G-8; G-16 a G-18, G-20 y

    G-22 a G-25

  • G-1 G-2 G-3 G-6 G-7 G-8 G-9 G-12 G-14 G-17 G-18 G-21 G-22 G-23 G-24 G-25 G-26

    Cu-Chlorite/Clinichlore 0.02 3.26 0.46 0.11 0.18 0.19 0.54 0.08 0.01 0.94 1.96 0.21 0.19 0.68 0.14 0.3 0.36

    Cu-Muscovite/Sericite 1.22 0.06 0.14 0.04 0.05 0.05 0.17 0.03 0.01 0.25 0 0 0.42 0.05 0.02 0.11 0.03

    Cu-Biotite 1.87 2.9 14.73 0.28 0.5 0.6 0.5 0.64 0.04 1.19 1.61 1.61 0.48 0.75 0.34 0.57 0.44

    Cu- Clay 1.86 0.41 4.3 0.7 0.54 2.87 0.29 0.77 0.71 0.37 0.01 0.01 1.17 1.46 0.52 0.55 0.31

    Suma 4.97 6.63 19.63 1.13 1.27 3.71 1.5 1.52 0.77 2.75 3.58 1.83 2.26 2.94 1.02 1.53 1.14

    Mineral/Muestra% Peso

    Muestras con contenidos de filosilicatos portadores de cobre superiores a 1% en peso

    El anlisis de los filosilicatos portadores de cobre, muestra que la mayora de

    las muestras presenta contenidos apreciables de arcillas-Cu, biotitas-Cu y

    Clorita-Cu.

  • Cobre aportado por las especies de mena y filosilicatos portadores

    de cobre (% peso)

  • Cobre aportado por las especies de mena y filosilicatos portadores

    de cobre (% peso)

  • Ch

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    Chrysocolla 0.00 6.26 5.92 9.18 0.00 2.53 3.80 18.46 0.00 1.62 2.58 6.12 0.00 19.63 11.18 30.43 0.00 9.73 3.28 12.84 0.00 14.11 8.02 24.79

    Fe-Cu Black Copper 34.07 0.00 40.67 14.62 21.54 0.00 39.82 8.27 18.01 0.00 50.18 6.52 24.46 0.00 28.35 9.15 35.97 0.00 59.65 8.45 17.51 0.00 13.61 4.55

    Mn-Cu-Black Copper 9.42 11.88 0.00 2.80 1.58 1.94 0.00 0.58 0.21 0.37 0.00 0.00 1.59 3.24 0.00 0.43 0.09 0.42 0.00 0.34 1.02 1.39 0.00 0.21

    Cu Micas 1.88 9.15 0.56 1.63 0.89 18.34 0.77 1.15 1.13 33.02 1.35 1.45 1.83 5.19 0.49 4.68 0.58 3.58 1.54 1.01 3.21 11.64 2.70 2.89

    Cu- (clay) 3.53 8.13 0.44 2.72 11.71 1.86 0.50 22.69 16.94 9.50 9.05 14.33 3.14 3.80 0.99 4.04 5.90 7.48 0.00 9.80 10.63 7.31 4.10 10.54

    Silicates 24.30 12.89 5.80 2.33 25.03 9.00 10.83 13.46 43.34 24.08 15.15 26.09 28.73 14.61 13.83 15.11 29.02 23.04 4.05 22.97 18.53 10.29 21.61 7.23

    Phyllosilicates 1.03 28.15 0.86 2.02 2.40 18.17 1.91 2.88 9.79 20.30 4.23 12.32 2.83 16.62 3.42 3.40 4.26 33.07 4.25 10.47 2.96 23.23 14.12 7.85

    Fe-Ti Oxides 0.01 0.46 0.17 0.08 0.13 23.51 0.58 0.19 0.03 1.65 0.25 0.16 0.08 12.69 0.30 0.00 0.06 2.59 0.00 0.00 0.06 9.08 0.50 0.00

    Others Gangue 6.34 2.19 4.28 27.29 6.94 5.20 9.35 7.12 1.41 0.89 1.72 2.33 8.28 6.41 7.39 11.28 2.85 2.03 2.70 5.41 9.46 2.30 9.49 16.53

    Muestra G-22

    Transiciones Minerales

    Muestra G-1 Muestra G-2 Muestra G-3 Muestra G-5 Muestra G-6

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    Chrysocolla 0.00 4.44 0.62 10.89 0.00 1.41 0.72 17.70 0.00 0.01 0.01 0.00 0.00 20.30 18.10 26.56

    Fe-Cu Black Copper 23.24 0.00 24.33 1.99 16.67 0.00 11.16 4.07 2.88 0.00 2.93 0.23 32.25 0.00 15.22 6.25

    Mn-Cu-Black Copper 0.50 3.74 0.00 0.00 0.36 0.47 0.00 0.09 6.73 4.59 0.00 11.90 1.02 0.54 0.00 0.00

    Cu Micas 3.95 2.89 0.39 2.61 11.30 9.52 0.95 8.67 0.00 1.17 0.01 0.11 0.64 6.77 0.05 3.13

    Cu- (clay) 16.80 2.20 0.26 32.82 14.28 1.76 0.81 17.61 0.96 8.06 0.05 2.40 8.92 5.07 1.08 15.23

    Silicates 25.33 5.56 10.80 7.06 18.14 3.79 6.99 8.41 48.08 8.25 7.03 1.72 9.95 9.65 11.15 11.33

    Phyllosilicates 4.59 21.54 9.30 18.40 3.95 17.41 4.89 5.84 3.85 35.83 2.00 5.49 2.59 26.27 5.92 10.16

    Fe-Ti Oxides 0.11 43.25 0.93 0.31 0.04 52.56 1.11 0.09 0.00 21.36 0.19 0.11 0.04 14.87 1.76 0.00

    Others Gangue 2.43 3.18 14.62 2.45 7.38 2.65 28.26 15.49 6.73 7.48 48.84 68.88 8.00 2.08 12.08 3.13

    Muestra G-16 Muestra G-17

    Transiciones Minerales

    Muestra G-20 Muestra G-24

    Asociacin Mineral (transiciones)

    Principales asociaciones (expresadas en % de transiciones) de las fases

    de mena para las muestras con contenidos superiores a 3 % en peso de

    minerales de mena

  • En las muestras estudiadas las fases de cobre negro dominantes son aquellas

    ricas en Fe, excepto para la muestra G-19 y G-20 donde predominan

    levemente las fases de cobre negro ricas en Mn. Las razones del porcentaje

    en peso de las fases de cobre negro ricas en Mn / fases de cobre negro rico en

    Fe son las siguientes:

    G-1 G-2 G-3 G-4 G-5 G-6 G-7 G-8 G-9 G-10 G-11 G-12 G-13

    Fe-Cu Black Copper 30.11 5.93 9.54 2.44 3.81 4.62 1.07 0.59 0.95 0.24 0.17 1.22 0.31

    Mn-Cu-Black Copper 29.21 0.36 0.21 0.30 1.13 0.02 0.11 0.02 0.01 0.00 0.01 0.23 0.00

    Razn Mn-Cu-BC/Fe-Cu-BC 0.97 0.06 0.02 0.12 0.30 0.00 0.10 0.03 0.01 0.00 0.06 0.19 0.00

    Mineral/Muestra% Peso

    G-14 G-15 G-16 G-17 G-18 G-19 G-20 G-21 G-22 G-23 G-24 G-25 G-26 G-27

    Fe-Cu Black Copper 0.22 0.16 2.06 3.04 0.51 0.32 0.82 0.44 4.30 1.85 2.39 1.76 0.69 0.52

    Mn-Cu-Black Copper 0.00 0.00 1.17 0.22 0.31 0.58 2.84 0.11 0.35 0.01 0.23 0.14 0.22 0.10

    Razn Mn-Cu-BC/Fe-Cu-BC 0.00 0.00 0.57 0.07 0.61 1.81 3.46 0.25 0.08 0.01 0.10 0.08 0.32 0.19

    Mineral/Muestra% Peso

    Los contenidos de sulfuros de cobre y de pirita se encuentran a nivel de

    trazas o bien no existen en las muestras analizadas.

    Algunas conclusiones del estudio mineralgico por Qemscan

  • Existen contenidos apreciables de filosilicatos portadores de cobre. El

    recuento modal muestra que la mayora de las muestras presenta

    contenidos apreciables de arcillas-Cu, biotitas-Cu y Clorita-Cu.

    G-1 G-2 G-3 G-6 G-7 G-8 G-9 G-12 G-14 G-17 G-18 G-21 G-22 G-23 G-24 G-25 G-26

    Cu-Chlorite/Clinichlore 0.02 3.26 0.46 0.11 0.18 0.19 0.54 0.08 0.01 0.94 1.96 0.21 0.19 0.68 0.14 0.3 0.36

    Cu-Muscovite/Sericite 1.22 0.06 0.14 0.04 0.05 0.05 0.17 0.03 0.01 0.25 0 0 0.42 0.05 0.02 0.11 0.03

    Cu-Biotite 1.87 2.9 14.73 0.28 0.5 0.6 0.5 0.64 0.04 1.19 1.61 1.61 0.48 0.75 0.34 0.57 0.44

    Cu- Clay 1.86 0.41 4.3 0.7 0.54 2.87 0.29 0.77 0.71 0.37 0.01 0.01 1.17 1.46 0.52 0.55 0.31

    Suma 4.97 6.63 19.63 1.13 1.27 3.71 1.5 1.52 0.77 2.75 3.58 1.83 2.26 2.94 1.02 1.53 1.14

    Mineral/Muestra% Peso

    En las muestras con altos contenidos de biotitas-Cu y de clorita/clinicloro-

    Cu, el cobre negro se presenta remplazando estos minerales a travs del

    clivaje o a partir de fracturas que permitieron la circulacin de soluciones

    con cobre. La afinidad qumica de los elementos constituyentes de estas

    especies principalmente Fe ++ y Mg++, permitieron el remplazo de ellas

    por fases de cobre negro.

    En todos estos casos con ocurrencia de filosilicatos portadores de cobre,

    se trata de un cobre que se presenta texturalmente ocluido y podra tener

    mayor dificultad para ser lixiviado.

  • Mineraloga detectada por DRX en la roca total

    Cuarzo Plagioclasa K-Feldespato Clinocloro Mica Otros

    G-1 **(*) * * ** Esmectita, ** Yeso, * Bassanita

    G-2 **(*) * ** Tr **

    G-3 ** *** * * Hematita, Tr Esmectita, ? Calcita

    G-4 *** ** * Tr * Tr Goethita, ? Epidota

    G-5 *** ** *(*) Tr *

    G-6 *** **(*) Tr - * ** ? Calcita

    G-7 *** **(*) * * ** Tr Hematita

    G-8 *** ** * Tr - * ** ? Caolinita

    G-9 *** **(*) * * ** Tr anfbol, Tr Rutilo, Tr Hematita

    G-10 *** **(*) * * ** Tr Rutilo, ? Hematita

    G-11 *** ** * * ** Tr anfbol

    G-12 *** **(*) * * **

    G-13 *** **(*) * * ** ? Rutilo, ? Hematita

    G-14 *** ** * Tr ** Tr Yeso, Tr Rutilo

    G-15 *** ** * Tr ** Tr Yeso, Tr Rutilo

    G-16 *** Tr Tr ** ** Andalusita, ? Cuprita

    G-17 *** ** * * ** ** Andalusita, * Anhidrita, Tr Yeso

    G-18 *** *** * * actinolita *

    G-19 *** ** Tr * Tr

    G-20 *** ** Tr * ** * Yeso

    G-21 *** *** * **

    G-22 *** ** ** * * Tr Rutilo, Tr Ankerita/Calcita

    G-23 *** ** * ** Tr Rutilo

    G-24 *** ** * * ** Tr Rutilo

    G-25 *** ** * Tr *

    G-26 *** *** * * ** * Andalusita, Tr Ankerita, Tr Pirita

    G-27 *** *** * ** * Andalusita, Tr Anfibol

    Anlisis Mineralgico DRX Roca TotalMuestra

  • Mineraloga detectada por DRX en la fraccin inferior a 2 micrones.

    Esmectita Clinocloro Mica Caolinita Otros

    G-1 *** * Tr Tr Yeso

    G-2 * Tr ** * Qz, Fsp

    G-3 **(*) Tr 375C * ** Qz, Fsp

    G-4 ** * ** *(*) Qz, Fsp

    G-5 *(*) *(*) *** Qz, Fsp

    G-6 ** * *** Qz, Fsp

    G-7 ** *(*) *** Qz, Fsp

    G-8 *** ** ** Qz, Fsp

    G-9 *** * *** * Qz, Fsp

    G-10 ** Tr 375C *** * Qz, Fsp

    G-11 ** Tr 375C *** * Qz, Fsp

    G-12 *** * *** Tr Qz, Fsp

    G-13 ** * *** * Qz, Fsp

    G-14 * * *** Qz, Fsp

    G-15 ** * ** Qz, Fsp

    G-16 ** * *** Qz, Fsp, Corrensita

    G-17 ** * ** Qz, Fsp

    G-18 *** * *** Qz, Fsp

    G-19 *** * *** Qz, Fsp

    G-20 *** * *** Qz, Fsp

    G-21 *** * ** Qz, Fsp

    G-22 ** * ** Qz, Fsp

    G-23 * Tr ** Qz, Fsp

    G-24 ** * ** Qz, Fsp

    G-25 ** * ** Qz, Fsp

    G-26 *** * ** Tr Fases no-filosilicatos

    G-27 ** * ** Tr Fases no-filosilicatos

    MuestraAnlisis Mineralgico DRX fraccin arcillas

  • muestra

    Acetato de Amonio

    pH 4,5

    Clorhidrato de Hidroxilamina pH 2

    Oxalato de Amonio pH 3,3

    Oxalato de Amonio pH 3,3 50C

    Ataque con mezcla de cidos HCl-HNO3-HF

    Extraccin secuencial de Cu, Fe y Mn v/s mineralizacin simplificada Qemscan

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    8:

    DG

    S:

    47

    2, F

    ase

    7

    G1

    9:

    DG

    S:

    43

    6, F

    ase

    8

    G2

    0:

    DG

    S:

    96

    2, F

    ase

    9

    G2

    1:

    DG

    S:

    47

    0, F

    ase

    10

    G2

    2:

    DG

    S:

    42

    1, F

    ase

    5

    G2

    3:

    DG

    S:

    15

    3, F

    ase

    5

    G2

    4:

    DG

    S:

    91

    5, F

    ase

    5

    G2

    5:

    DG

    S:

    41

    8, F

    ase

    5

    G2

    6:

    P-1

    17

    1 B

    aja

    se

    cu

    en

    cia

    vo

    lca

    nic

    a

    G2

    7:

    P-1

    17

    1 A

    lta

    se

    cu

    en

    cia

    vo

    lca

    nic

    a

    Ex

    tra

    cc

    in

    de

    Cu

    po

    r e

    tap

    as,

    ra

    zn

    de

    so

    lub

    ilid

    ad

    (%

    )

    Min

    era

    liza

    ci

    n (

    % p

    eso

    )Mineralizacin vs Extraccin de Cu por Etapas

    CuS/CuT

    Cu-Clay

    Cu-Micas

    Mn-Cu-Black Copper

    Fe-Cu Black Copper

    Chrysocolla

    Cu etapa 4

    Cu etapa 3

    Cu etapa 2

    Cu etapa 1

    CuS/CuT

  • 020

    40

    60

    80

    100

    0.6

    2 /

    1.8

    6

    1.1

    9 /

    2.5

    0

    1.6

    1 /

    3.1

    1

    0.3

    6 /

    1.4

    2

    0.8

    6 /

    2.0

    2

    1.0

    4 /

    2.2

    2

    1.4

    8 /

    2.9

    9

    1.5

    6 /

    2.5

    3

    1.1

    2 /

    3.0

    1

    1.0

    0 /

    2.6

    9

    0.9

    2 /

    2.6

    6

    0.9

    5 /

    1.9

    5

    0.8

    0 /

    1.8

    4

    0.8

    6 /

    1.8

    5

    0.7

    5 /

    1.7

    7

    0.3

    9 /

    1.8

    4

    0.2

    0 /

    2.5

    2

    1.6

    7 /

    6.0

    6

    0.4

    6 /

    3.7

    3

    0.3

    4 /

    2.1

    9

    2.2

    2 /

    4.6

    8

    0.2

    1 /

    1.0

    1

    0.7

    5 /

    1.4

    6

    0.8

    6 /

    2.1

    8

    0.4

    1 /

    1.3

    2

    0.4

    9 /

    2.1

    4

    1.2

    5 /

    3.6

    1

    0

    10

    20

    30

    40

    50

    60

    70

    80

    G0

    1:

    Wa

    d b

    rech

    a f

    all

    a, F

    ase

    4

    G0

    2:

    Wa

    d-N

    eo

    toci

    ta, F

    ase

    3

    G0

    3:

    Pir

    olu

    sita

    , Fa

    se 4

    G0

    4:

    Wa

    d, F

    ase

    4

    G0

    5:

    Wa

    d B

    an

    co 2

    50

    5, F

    ase

    3

    G0

    6:

    Ne

    oto

    cita

    , Fa

    se 3

    G0

    7:

    Ga

    by

    M-1

    G0

    8:

    Ga

    by

    M-2

    G0

    9:

    Co

    l 4 C

    ab

    eza

    G1

    0:

    Co

    l 4 R

    ipio

    G1

    1:

    Co

    l 3

    2 R

    ipio

    G1

    2:

    Co

    l 36

    Ca

    be

    za

    G1

    3:

    Co

    l 3

    6 R

    ipio

    G1

    4:

    Co

    mp

    . rip

    io c

    on

    tro

    l

    G1

    5:

    Co

    mp

    . rip

    io c

    ura

    do

    op

    tim

    o

    ma

    cera

    do

    12

    G1

    6:

    DG

    S:

    88

    8, F

    ase

    5

    G1

    7:

    DG

    S:

    19

    5, F

    ase

    6

    G1

    8:

    DG

    S:

    47

    2, F

    ase

    7

    G1

    9:

    DG

    S:

    43

    6, F

    ase

    8

    G2

    0:

    DG

    S:

    96

    2, F

    ase

    9

    G2

    1:

    DG

    S:

    47

    0, F

    ase

    10

    G2

    2:

    DG

    S:

    42

    1, F

    ase

    5

    G2

    3:

    DG

    S:

    15

    3, F

    ase

    5

    G2

    4:

    DG

    S:

    91

    5, F

    ase

    5

    G2

    5:

    DG

    S:

    41

    8, F

    ase

    5

    G2

    6:

    P-1

    17

    1 B

    aja

    se

    cue

    nci

    a v

    olc

    an

    ica

    G2

    7:

    P-1

    17

    1 A

    lta

    se

    cue

    nci

    a v

    olc

    an

    ica

    Ext

    racc

    in

    de

    Fe

    po

    r e

    tap

    as,

    (%

    )

    Min

    era

    liza

    ci

    n (

    % p

    eso

    )Mineralizacin vs Extraccin de Fe por Etapas

    FeS/FeT

    Silicates

    Other Gangue

    Fe-Ti Oxides

    Phyllosilicates

    Cu-Clay

    Cu-Micas

    Mn-Cu-Black Copper

    Fe-Cu Black Copper

    Chrysocolla

    Fe etapa 4

    Fe etapa 3

    Fe etapa 2

    Fe etapa 1

  • 020

    40

    60

    80

    100

    0.6

    2 /

    1.8

    6

    1.1

    9 /

    2.5

    0

    1.6

    1 /

    3.1

    1

    0.3

    6 /

    1.4

    2

    0.8

    6 /

    2.0

    2

    1.0

    4 /

    2.2

    2

    1.4

    8 /

    2.9

    9

    1.5

    6 /

    2.5

    3

    1.1

    2 /

    3.0

    1

    1.0

    0 /

    2.6

    9

    0.9

    2 /

    2.6

    6

    0.9

    5 /

    1.9

    5

    0.8

    0 /

    1.8

    4

    0.8

    6 /

    1.8

    5

    0.7

    5 /

    1.7

    7

    0.3

    9 /

    1.8

    4

    0.2

    0 /

    2.5

    2

    1.6

    7 /

    6.0

    6

    0.4

    6 /

    3.7

    3

    0.3

    4 /

    2.1

    9

    2.2

    2 /

    4.6

    8

    0.2

    1 /

    1.0

    1

    0.7

    5 /

    1.4

    6

    0.8

    6 /

    2.1

    8

    0.4

    1 /

    1.3

    2

    0.4

    9 /

    2.1

    4

    1.2

    5 /

    3.6

    1

    0

    2

    4

    6

    8

    10

    G0

    1:

    Wa

    d b

    rech

    a f

    all

    a, F

    ase

    4

    G0

    2:

    Wa

    d-N

    eo

    toc

    ita

    , Fa

    se 3

    G0

    3:

    Pir

    olu

    sita

    , Fa

    se 4

    G0

    4:

    Wa

    d, F

    ase

    4

    G0

    5:

    Wa

    d B

    an

    co 2

    50

    5, F

    ase

    3

    G0

    6:

    Ne

    oto

    cit

    a, F

    ase

    3

    G0

    7:

    Ga

    by

    M-1

    G0

    8:

    Ga

    by

    M-2

    G0

    9:

    Co

    l 4

    Ca

    be

    za

    G1

    0:

    Co

    l 4

    Rip

    io

    G1

    1:

    Co

    l 32

    Rip

    io

    G1

    2:

    Co

    l 3

    6 C

    ab

    eza

    G1

    3:

    Co

    l 3

    6 R

    ipio

    G1

    4:

    Co

    mp

    . rip

    io c

    on

    tro

    l

    G1

    5:

    Co

    mp

    . rip

    io c

    ura

    do

    op

    tim

    o

    ma

    cera

    do

    12

    G1

    6:

    DG

    S:

    88

    8, F

    ase

    5

    G1

    7:

    DG

    S:

    19

    5, F

    ase

    6

    G1

    8:

    DG

    S:

    47

    2, F

    ase

    7

    G1

    9:

    DG

    S:

    43

    6, F

    ase

    8

    G2

    0:

    DG

    S:

    96

    2, F

    ase

    9

    G2

    1:

    DG

    S:

    47

    0, F

    ase

    10

    G2

    2:

    DG

    S:

    42

    1, F

    ase

    5

    G2

    3:

    DG

    S:

    15

    3, F

    ase

    5

    G2

    4:

    DG

    S:

    91

    5, F

    ase

    5

    G2

    5:

    DG

    S:

    41

    8, F

    ase

    5

    G2

    6:

    P-1

    17

    1 B

    aja

    se

    cue

    nci

    a v

    olc

    an

    ica

    G2

    7:

    P-1

    17

    1 A

    lta

    se

    cue

    nci

    a v

    olc

    an

    ica

    Ext

    racc

    in

    de

    Fe

    po

    r e

    tap

    as,

    ra

    zn

    de

    so

    lub

    ilid

    ad

    (%

    )

    Min

    era

    liza

    ci

    n (

    % p

    eso

    )Mineralizacin vs Extraccin de Fe por Etapas

    FeS/FeT

    Fe-Cu Black CopperFe etapa 4

    Fe etapa 3

    Fe etapa 2

    Fe etapa 1

  • 020

    40

    60

    80

    100

    0.1

    1 /

    1.1

    4

    0.0

    3 /

    0.0

    4

    0.0

    5 /

    0.0

    7

    0.0

    3 /

    0.0

    4

    0.0

    6 /

    0.0

    8

    0.0

    1 /

    0.0

    2

    0.0

    3 /

    0.0

    4

    0.0

    2 /

    0.0

    2

    0.0

    3 /

    0.0

    4

    0.0

    2 /

    0.0

    3

    0.0

    3 /

    0.0

    4

    0.0

    3 /

    0.0

    4

    0.0

    2 /

    0.0

    3

    0.0

    2 /

    0.0

    3

    0.0

    2 /

    0.0

    3

    0.0

    3 /

    0.0

    4

    0.0

    1 /

    0.0

    2

    0.0

    8 /

    0.1

    1

    0.0

    3 /

    0.0

    7

    0.2

    1 /

    0.4

    5

    0.1

    3 /

    0.1

    6

    0.0

    2 /

    0.0

    3

    0.0

    1 /

    0.0

    2

    0.0

    2 /

    0.0

    4

    0.0

    1 /

    0.0

    2

    0.0

    1 /

    0.0

    3

    0.0

    3 /

    0.0

    5

    0

    10

    20

    30

    40

    50

    60

    70

    80

    G0

    1:

    Wa

    d b

    rech

    a f

    all

    a, F

    ase

    4

    G0

    2:

    Wa

    d-N

    eo

    toci

    ta, F

    ase

    3

    G0

    3:

    Pir

    olu

    sita

    , Fa

    se 4

    G0

    4:

    Wa

    d, F

    ase

    4

    G0

    5:

    Wa

    d B

    an

    co 2

    50

    5, F

    ase

    3

    G0

    6:

    Ne

    oto

    cita

    , Fa

    se 3

    G0

    7:

    Ga

    by

    M-1

    G0

    8:

    Ga

    by

    M-2

    G0

    9:

    Co

    l 4 C

    ab

    eza

    G1

    0:

    Co

    l 4 R

    ipio

    G1

    1:

    Co

    l 32

    Rip

    io

    G1

    2:

    Co

    l 36

    Ca

    be

    za

    G1

    3:

    Co

    l 36

    Rip

    io

    G1

    4:

    Co

    mp

    . rip

    io c

    on

    tro

    l

    G1

    5:

    Co

    mp

    . rip

    io c

    ura

    do

    op

    tim

    o

    ma

    cera

    do

    12

    G1

    6:

    DG

    S:

    88

    8, F

    ase

    5

    G1

    7:

    DG

    S:

    19

    5, F

    ase

    6

    G1

    8:

    DG

    S:

    47

    2, F

    ase

    7

    G1

    9:

    DG

    S:

    43

    6, F

    ase

    8

    G2

    0:

    DG

    S:

    96

    2, F

    ase

    9

    G2

    1:

    DG

    S:

    47

    0, F

    ase

    10

    G2

    2:

    DG

    S:

    42

    1, F

    ase

    5

    G2

    3:

    DG

    S:

    15

    3, F

    ase

    5

    G2

    4:

    DG

    S:

    91

    5, F

    ase

    5

    G2

    5:

    DG

    S:

    41

    8, F

    ase

    5

    G2

    6:

    P-1

    17

    1 B

    aja

    se

    cue

    nci

    a v

    olc

    an

    ica

    G2

    7:

    P-1

    17

    1 A

    lta

    se

    cue

    nci

    a v

    olc

    an

    ica

    Ext

    racc

    in

    de

    Mn

    po

    r e

    tap

    as,

    (%

    )

    Min

    era

    liza

    ci

    n (

    % p

    eso

    )Mineralizacin vs Extraccin de Mn por Etapas

    MnS/MnT

    Silicates

    Other Gangue

    Fe-Ti Oxides

    Phyllosilicates

    Cu-Clay

    Cu-Micas

    Mn-Cu-Black Copper

    Fe-Cu Black Copper

    Chrysocolla

    Mn etapa 4

    Mn etapa 3

    Mn etapa 2

    Mn etapa 1

  • 020

    40

    60

    80

    100

    0.1

    1 /

    1.1

    4

    0.0

    3 /

    0.0

    4

    0.0

    5 /

    0.0

    7

    0.0

    3 /

    0.0

    4

    0.0

    6 /

    0.0

    8

    0.0

    1 /

    0.0

    2

    0.0

    3 /

    0.0

    4

    0.0

    2 /

    0.0

    2

    0.0

    3 /

    0.0

    4

    0.0

    2 /

    0.0

    3

    0.0

    3 /

    0.0

    4

    0.0

    3 /

    0.0

    4

    0.0

    2 /

    0.0

    3

    0.0

    2 /

    0.0

    3

    0.0

    2 /

    0.0

    3

    0.0

    3 /

    0.0

    4

    0.0

    1 /

    0.0

    2

    0.0

    8 /

    0.1

    1

    0.0

    3 /

    0.0

    7

    0.2

    1 /

    0.4

    5

    0.1

    3 /

    0.1

    6

    0.0

    2 /

    0.0

    3

    0.0

    1 /

    0.0

    2

    0.0

    2 /

    0.0

    4

    0.0

    1 /

    0.0

    2

    0.0

    1 /

    0.0

    3

    0.0

    3 /

    0.0

    5

    0

    1

    2

    3

    G0

    1:

    Wa

    d b

    rech

    a f

    all

    a, F

    ase

    4

    G0

    2:

    Wa

    d-N

    eo

    toci

    ta, F

    ase

    3

    G0

    3:

    Pir

    olu

    sita

    , Fa

    se 4

    G0

    4:

    Wa

    d, F

    ase

    4

    G0

    5:

    Wa

    d B

    an

    co 2

    50

    5, F

    ase

    3

    G0

    6:

    Ne

    oto

    cita

    , Fa

    se 3

    G0

    7:

    Ga

    by

    M-1

    G0

    8:

    Ga

    by

    M-2

    G0

    9:

    Co

    l 4 C

    ab

    eza

    G1

    0:

    Co

    l 4 R

    ipio

    G1

    1:

    Co

    l 32

    Rip

    io

    G1

    2:

    Co

    l 36

    Ca

    be

    za

    G1

    3:

    Co

    l 36

    Rip

    io

    G1

    4:

    Co

    mp

    . rip

    io c

    on

    tro

    l

    G1

    5:

    Co

    mp

    . rip

    io c

    ura

    do

    op

    tim

    o

    ma

    cera

    do

    12

    G1

    6:

    DG

    S:

    88

    8, F

    ase

    5

    G1

    7:

    DG

    S:

    19

    5, F

    ase

    6

    G1

    8:

    DG

    S:

    47

    2, F

    ase

    7

    G1

    9:

    DG

    S:

    43

    6, F

    ase

    8

    G2

    0:

    DG

    S:

    96

    2, F

    ase

    9

    G2

    1:

    DG

    S:

    47

    0, F

    ase

    10

    G2

    2:

    DG

    S:

    42

    1, F

    ase

    5

    G2

    3:

    DG

    S:

    15

    3, F

    ase

    5

    G2

    4:

    DG

    S:

    91

    5, F

    ase

    5

    G2

    5:

    DG

    S:

    41

    8, F

    ase

    5

    G2

    6:

    P-1

    17

    1 B

    aja

    se

    cue

    nci

    a v

    olc

    an

    ica

    G2

    7:

    P-1

    17

    1 A

    lta

    se

    cue

    nci

    a v

    olc

    an

    ica

    Ext

    racc

    in

    de

    Mn

    po

    r e

    tap

    as,

    ra

    zn

    de

    so

    lub

    ilid

    ad

    (%

    )

    Min

    era

    liza

    ci

    n (

    % p

    eso

    )Mineralizacin vs Extraccin de Mn por Etapas

    MnS/MnT

    Mn-Cu-Black Copper

    Mn etapa 4

    Mn etapa 3

    Mn etapa 2

    Mn etapa 1

    MnS/MnT