catlab presentation_reeco tech

www.reecotech.com.vn

H THNG THIT B NGHIN CU XC

TC: CATLAB PCS / MS

H Ni, 04/2014

Trnh by: Trn Minh Hi

www.reecotech.com.vn 2

1. THNG TIN S LC V CNG TY REECO

2. H THNG THIT B CATLAB PCS / MS

3. MT S THIT B NGHIN CU VT LIU HP

PH, XC TC KHC

NI DUNG

Thng tin chung www.reecotech.com.vn 3

Website

Tm kin trn Google

Lnh vc kinh doanh v Phng chm hot ng www.reecotech.com.vn 4

KIN THC KINH NGHIM

NI THT PTN NI THT PTN

D N CHUYN GIAO KH&CN D N CHUYN GIAO KH&CN

THIT B KHOA HC K THUT THIT B KHOA HC K THUT

L i din c quyn, phn phi thit b v h thng KHKT cho cc hng ch to hng

u th gii.

Cc thit b v h thng KHKT c xut x t US, EURO, Israel hoc Nht Bn.

i ng cn b, nhn vin c trnh i hc v trn i hc c o to c bn v

chuyn su, vi s h tr o to t cc

hng sn xut.

To dng mi lin kt hiu qu gia cc nh khoa hc, chuyn gia ci tin, sng to vi

cng ng doanh nghip SX KD.

Sn phm v cc lnh vc KHKT lin quan www.reecotech.com.vn 5

THIT B KHOA HC K THUT THIT B KHOA HC K THUT

Specializing in

Pressure Swing Adsorption Studies

Humidity Generators Gas

Separation Processes

WORLD LEADING

SORPTION

INSTRUMENTS

>1,400,000 instruments installed

around the world!

Thermo

imaging

instruments

for clinical

applications.

KHCH HNG TIU BIU KHCH HNG TIU BIU

1. Trung tm Nghin cu Vt liu Cu trc Nano v Phn t, TP. HCM

2. Trng H Khoa hc T nhin TP. HCM

3. Trng H Cn Th

4. Vin Ti nguyn v Mi trng, TP. HCM

5. Vin Hi dng hc, Nha Trang Khnh Ha

6. Trung tm Quan trc Ti Nguyn v Mi trng tnh k Nng

7. Cng ty Qun l Khai thc Dch v Thy li TP. HCM

8. Trung tm Mi trng v Nng lng TP. HCM

9. Trung tm Quan trc mi trng, Tng cc Mi trng

10. Bnh vin Nguyn Tri Phng


An Integrated Microreactor Mass Spectrometer for

Reaction Testing, TPD/R/O and Pulse Chemisorption

Hiden CATLAB SYSTEM Hiden CATLAB SYSTEM

CATLAB System for Catalysis Studies & Thermal Analysis www.reecotech.com.vn 7

CATLAB Schematic


Module 1:

- Interchangeable catalyst cartridge

system.

- In-Bed thermocouple.

- Sample mass: typically 25 - 250mg,

2.0g (opt)

- P: ambient

- T: ambient to 1000C, accuracy: +/- 1C

- Ramp rate: 1 to 20C/min

- MFC: 4 streams 3-100ml/min, 8 streams (opt)

- Air thermostat and trace heating to minimise

condensation of liquid feeds / products

Module 2: Hiden QGA Mass Spectrometer

- Multiple Gas and Vapour Analysis : 200

amu mass range, 300 or 510 amu (opt).

- High Sensitivity: detection to 100 ppb.

- < 300 ms response time to changes in gas

concentrations.

- Fast data acquisition: up to 500

measurements per second.

- Low dead volume, heated inlet for fast

response to vapours.

- Soft ionization (APSI-MS soft ionisation mode) for reduced spectral

fragmentation and simplified data interpretation.

- Operate as stand-alone components, could be interfaced with existing lab

equipment such as TGAs (TG-MS) or Gas Chromatographs.


The HAL

201 RC type:

gold plated

ion source &

UHV


0

FLOW CONTROL

MODULE

Standard CATLAB Layout


CATLAB Control Software

Control of Mass Spectrometer, Temperature and Gas Flows in one

software package

Hardware Control Parameters

Control and calibration of

MFCs for different gases Mass Spectrometer Control Furnace Control



- Stage 1: Configure the temperature profile of the experiment - set

ramp rate, set point and dwell time for each stage

Experimental Setup

Stage 2: Configure gas flows/Pulses for each stage of the experiment

- MFC Assistant to help calculate percentage composition of each

component in gas mixture for the selected flow CATLAB System for Catalysis Studies & Thermal Analysis www.reecotech.com.vn 14

Experimental Setup (cont)


MFC Gas Mix Library Editor Gas Mix Calculator

Gas Mixing Control



Stage 3: Add measurement stages. Stages are triggered by time or temperature

depending where on the temperature profile the start/stop is placed. Different

MS analysis types can be configured for each stage of the experiment.



MID Scan setup for known species. Automatic overlap removal.

Includes library of most common gases. Ion source control for each

species preferential ionisation of some overlapping gases.

Mass Spectrometer Control


- Multiple Bar scans can be configured in 3 subscan sections for

optimised sampling of unknowns.

- Ion source control for each subscan

Mass Spectrometer Control

Data plotted with x-axis as time or temperature

MS Data Display

TPR Data

TPR Data


3D Bar Graph mode for easy identification of bar mode trends

MS Data Display (cont)


Data Analysis


- 3D Bar, 2D Bar and MID modes all available in data analysis mode.

- Multiple export/print options.

- Export selectable masses or whole scan to NIST database for identification of

unknowns.

- 2D Bar and MID view linked to enable viewing of Bar scan at any point in the

MID trace and vice versa.

- Peak fitting analysis routines

- Integrated area

- Baseline subtraction

Data Analysis (cont)


Pulse Chemisorption

Injection of single gases or multiple reactants


Pulse Chemisorption Quantification

Uptake measurements; Dispersion calculation; Metal surface

area; Pulse Adsorption Isotherm


Video clip v h thng CATLAB


Selected CATLAB Users

Johnson Matthey

Texas A&M University

Hong Kong University

Cambridge University

Bayreuth University

Research complex at Harwell

Sao Paolo University

Bulgarian Academy of Sciences

Universit catholique de Louvain

Kunming University

ETH Zurich

PDVSA (Petroleum of Venezuela)


Selected Academic References

Electronic and Geometric Structure of Ce3+ Forming Under Reducing Conditions in Shaped Ceria Nanoparticles Promoted by Platinum . J. Phys. Chem. C, 2014, 118 (4), pp 19741982. O. V. Safonova, A.

Guda, C. Paun, N. Smolentsev, P. M. Abdala, G. Smolentsev, M. Nachtegaal, J. Szlachetko, M. A. Soldatov, A.

V. Soldatov, and J. A. van Bokhoven

The effect of coke deposition on the activity and selectivity of HZSM-5 zeolite during ethylbenzene alkylation reaction in the presence of ethanol. Catal. Sci. Technol., 2014, 4, 1017-1027. Sulaiman S.

Khattaf, C. DAgostino, Muhammad Naseem Akhtar, Nabil Othman Al-Yassir, Nicholas Tan and Lynn F.

Gladden.

Reaction Kinetics of C3H6 Oxidation for Various Reaction Pathways Over Diesel Oxidation Catalysts . Topics in Catalysis, December 2013, Volume 56, Issue 18-20, pp 1916-1921. Harry Oh, Izabela S. Pieta,

Jinyong Luo, William S. Epling

An investigation of the role of surface nitrate species in the oxidation of propene on a Pt-based diesel oxidation catalyst.. Catal. Sci. Technol., 2013, 3, 2349-2356 Sarayute Chansai, Robbie Burch, Christopher

Hardacre, Harry Oh, and William S. Epling.

Molybdenum oxide on Fe2O3 core-shell catalysts; probing the nature of the structural motifs responsible for methanol oxidation catalysts .ACS Catal., 2014, 4 (1), pp 243250, Catherine Brookes , Peter P Wells ,

Giannantonio Cibin , Nikolaos Dimitratos , Wilm Jones , David J Morgan , and Michael Bowker.

Chiral Co(II) metal-organic framework in the heterogeneous catalytic oxidation of alkenes under aerobic and anaerobic conditions. ACS Catal., 2014, 4, pp 10321039 Giulia Tuci, Giuliano Giambastiani, Stephanie

Kwon, Peter Curran Stair, Randall Q. Snurr and Andrea Rossin


1. Nghin cu bn ca cc h xc tc Pd/ gi mang -Al2O3 trong qu trnh t chy

xc tc metan c s hin din ca kh gy c SO2

The durability of alumina supported Pd catalysts for the combustion of methane in the

presence of SO2

2. Lin h gia cu trc v tnh nng ca cc xc tc nn tng Cu cu trc xp trong kh

chn lc NOx t kh thi ca cc ng c diesel

Structure-performance relationships of Cu based porous catalysts for selective catalytic

reduction (SCR) of NOx gases from diesel exhausts.

3. nh hng ca tc gia nhit trong kh graphite oxide nhit thp n xp ca

sn phm

The effect of heating rate on porosity production during the low temperature reduction of

graphite oxide.

4. Sng lc xc tc cho vic gim loi H2S ca dng biogas cp liu cho pin nhin liu

mui carbonate nng chy

Screening of catalysts for H2S abatement from biogas to feed molten carbonate fuel cells.

5. Nghin cu c tnh xc tc bng phng php nhit lng hp ph

Calorimetric Adsorption for Catalyst Characterisation

Customer Research Stories

ISSUE : 1120/07


1120/01 1120/06 1120/03

Summary

Integrated microreactor and mass spectrometer

Both microreactor and mass spectrometer manufactured by Hiden

Single integrated software package to control MS and microreactor

Ideal for catalyst characterisation and reaction testing

Designed for optimum mass spectrometer performance


1/ Thit b kho st Phn tch & Tinh sch kh ca hng L&C, USA

H thng tch hp 03 cng ngh: Hp ph p sut chuyn i (PSA), Hp ph chn khng chuyn i (VSA), v Hp ph nhit chuyn i (TSA).

PSA-300LC

(2cc VMu 20cc)

nh gi kh nng

phn tch, tinh sch

kh ca cc loi vt

liu mi .

PSA-1000

(150cc VMu 3500cc)

Thch hp cho cc d n

R&D, thit lp pilot tinh

sch kh hoc trin khai

sn xut loi vt liu cho

mc ch ny. Thit b kho st Phn tch & Tinh sch kh www.reecotech.com.vn 30

Cc lnh vc s dng TB kho st Phn tch & Tinh sch kh

1.1/ Bt gi v c lp kh CO2

CO2 thot ra c coi l nguyn nhn

ch yu gy bin i kh hu, lm cho

tri t nng ln, m v nguy c th Vit

Nam l mt trong 5 nc hng chu nng

nht. GS.TSKH. H S Thong, PetroTimes.

CO2 thot ra c coi l nguyn nhn

ch yu gy bin i kh hu, lm cho

tri t nng ln, m v nguy c th Vit

Nam l mt trong 5 nc hng chu nng

nht. GS.TSKH. H S Thong, PetroTimes.

Thit b kho st Phn tch & Tinh sch kh www.reecotech.com.vn 31

1.2/ Phn tch cc hydrocarbon nh, k c tinh sch kh TN, biogas,

1.3/ Phn tch khng kh

Nitrogen Generator Portable Oxygen

Concentrator


ng dng nghin cu:

- Phn tch, lu gi CO2

bng vt liu MOFs;

- Loi b kh c VOC trong

kh thi, nitrosamines trong

khi thuc l,;

- Tinh sch kh thin nhin,

biogas.

KHCH

HNG

TIU

BIU:

Integrated

software

HR/Vapor Generator

PSA/VSA/TSA System

MS


0.00E+00

5.00E-10

1.00E-09

1.50E-09

2.00E-09

2.50E-09

0 500 1000 1500 2000 2500 3000

Ion

Cu

rre

nt,

A

Time, Sec

MS

MS:16 MS:18 MS:44

PSA Data


SpaciMS for determination of intra catalyst reactor chemistry www.reecotech.com.vn 35

2. HIDEN SPACI- MS

SPACI-MS (Spatially Resolved Capillary Inlet MS): probing inside of a

monolith, aims at revealing what is happening inside the blackbox.

Measurements:

- Pinpoint and measure diverse pollutants

inside narrow channels of catalyst

monoliths

- Determine transient species distribution in

reactors

- Minimal disruption of reactor flow and

catalyst chemistry

- For sampling from confined space

reactors

- Channelised automotive engine catalysts

- Catalysed Fuel Reformers

- Proton Exchange Membranes

- Fuel Cell Flow Channels

- Exhaust Gas Recirculation (EGR) in

internal combustion engines

Up to 16 capillary sampling probes and

thermocouples

SpaciMS for determination of intra catalyst reactor chemistry www.reecotech.com.vn 36

3. Gas sorption & vapor sorption analysis instruments

WORLD LEADING SORPTION

INSTRUMENTS

The IMI Series offers a multifunctional platform for the

study of physisorption, chemisorption and gas absorption

by materials, from entry level manometric analyzers to

advanced multistream dynamic flow systems.

The IGA Series: The unique IGA method exploits the

relaxation of the sample after pressure or temperature

change to simultaneously determine kinetic parameters

and equilibrium uptake.

The IGAsorp is a fully automated bench top gravimetric

analysis system designed to quickly and accurately

measure the magnitude and kinetics of moisture

sorption by materials.

The XEMIS is a high accuracy sorption microbalance

for precision weighing in extreme environments.

Available as a standalone microbalance or as part of a

fully integrated sorption analyzer, the XEMIS provides

remarkable flexibility, as well as outstanding weighing

stability and accuracy.

Product Applications

Gas sorption analysis

Isotherm determination

Kinetic analysis

Thermodynamic studies

Hydrogen storage

Methane storage

Carbon dioxide sequestration

Gas separation and purification

Supercritical gas adsorption

Shale gas and coal bed methane

Gas solubility in ionic liquids

Chemisorption studies

Chemical reaction studies

Porous coordination frameworks

Activated carbon, carbon molecular sieves and templated carbons

Zeolites and zeotypes

Porous polymers

Gas sorption & vapor sorption analysis instruments www.reecotech.com.vn 37

Thng tin lin h:

ThS. Trn Minh Hi

Cng ty TNHH Khoa hc v K thut REECO

/c: 46/41/37 ng Vn Chui, P. 4, Q. 3, TP. H Ch Minh

T: 0903166704 Email: [email protected]

Website: www.reecotech.com.vn

Thng tin lin h:

ThS. Trn Minh Hi

Cng ty TNHH Khoa hc v K thut REECO

/c: 46/41/37 ng Vn Chui, P. 4, Q. 3, TP. H Ch Minh

T: 0903166704 Email: [email protected]

Website: www.reecotech.com.vn

Cm n Qu v lng nghe!

H thng L vi phn ng kt ni vi My khi ph - Nghin cu xc

nh chc nng, c tnh ca Xc tc d th.

Module 1: L vi phn ng, kim sot

cht ch thng s dng v nhit ;

Module 2: My khi ph t cc.

- H thng cartridge thay mu kho st.

- u d nhit ti v tr mu trong cell o.

- Khi lng mu: 25 - 250mg, 2.0g (opt)

- p sut: p sut mi trng xung quanh

- Nhit : mi trng 1000C, 1C

- Tc gia nhit: t 1 n 20C/pht

- MFC: 4 dng 3-100ml/pht, 8 dng (opt)

Module 1: L VI PHN NG


- Phn tch lin tc , nhiu thnh phn kh v

hi cng lc vi gii o: 0 200 amu, n

300 hoc 510 amu (opt).

- nhy cao: 100 ppb.

- Thi gian cho p ng < 300 ms i vi s

thay i nng kh.

- Ly s liu cc nhanh: 500 php o/giy.

- Tch hp chc nng phn tch CO khi c hin din ca N2 v CO2.

- S dng k thut ion ha mm gip gim phn mnh ph v n gin ha s liu.

- Dead-volume rt thp, u thu mu dng ng mao qun thch anh c gia nhit,

gip chng ngng t v cho nhy cao vi trong phn tch hi.

- Vn hnh l mt thit b phn tch c lp, hoc kt hp d dng thnh mt h

thng vi cc thit b khc trong nh Phn tch nhit (TG-MS), sc k, l phn

ng,... My khi ph phn tch nh lng kh www.reecotech.com.vn 40

Model QGA:

H thng L vi phn ng kt ni vi My khi ph www.reecotech.com.vn 41

ng dng ca H thng CATLAB: Nghin cu xc nh chc nng, c tnh ca Xc tc d th.

Xc nh din tch b mt/ bao ph ca kim loi (Phng php:

Hp ph/ Gii hp theo chng trnh nhit - TPD).

Nng lng lin kt ca cc phn t hp ph (TPD).

ng hc phn ng (p chy, oxi ha, metan ha), (TPRx).

Xc nh axit b mt, (NH3 / Pyridine TPD).

Kho st tnh hon nguyn ca xc tc, (TPR).

C ch phn ng, (TPRx).

Xc nh c tnh ca b mt kt ta carbon, (TPO).

Phng php Gii hp theo chng trnh nhit (TPD)

Phng php TPD (Temperature Programmed Desorption) c thc hin thng

qua vic gia nhit tuyn tnh mu xc tc c cho tip xc trc (predose)

vi mt tc cht nht nh, ng thi theo di, xc nh, nh gi cc kh thot ra

trong sut qu trnh gia nhit ny. PP ny cho php:

Xc nh dng, s lng v mnh ca cc tm hot ng xc tc;

ng hc hp ph v C ch gii hp;

Nng lng hot ha hp ph/ gii hp;

Nhit hp ph;


Bc phn ng gii hp ph (Order of Desorption)

- Bc 0: tc gii hp khng ph thuc vo

bao ph

- Bc 1: tc gii hp ~ ( bao ph tc thi)1

- Bc 2: tc gii hp ~ ( bao ph tc thi)2 Nhit

2nd order

1st order

0 order

Phng php Kh theo chng trnh nhit (TPR)

Phng php TPR (Temperature Programmed Reduction) kho st phn

ng kh ca H2 vi vt liu xc tc.

S(solid) + 1% H2/He R(solid) + H2O

PP ny cho php:


Xc nh cc tiu phn kh c trn b

mt xc tc;

Xc nh s oxi ha biu kin ca xc tc

kim loi gn trn gi mang hoc ion kim loi

trong zeolite v oxit;

Xc nh tng tc gia gi mang v kim

loi;

nh hng hin tng trn y (spillover

phenomena) v s hnh thnh hp kim.

Kho st TPR trn mu CuO

Phng php Oxi ha theo chng trnh nhit (TPO)

Phng php TPO (Temperature Programmed Oxidation) dng

kh Oxi long oxi ha b mt xc tc hoc kt ta carbon.

Phng php c ng dng :

Nghin cu qu trnh oxi ha;

Kim tra mc oxi ha b mt;

Kho st iu kin v nhit thiu kt nhm loi b nhng

tp cht lm nh hng phn ng ca pha hot ng xc tc.


Phng php Phn ng theo chng trnh nhit (TPRx)

Phng php TPRx (Temperature Programmed Reaction) c th c thc

hin di hai iu kin:

1. Cho xc tc ng hp ph cc tc cht phn ng trc khi thc hin

chng trnh gia nhit trong kh tr.


2. a hn hp tc cht phn ng i qua

xc tc bng dng kh mang song song

vi vic thc hin CT gia nhit.

Cho php:

c tnh cc thng s ng hc;

Ti u ha nhit phn ng;

Nghin cu c ch phn ng;

Nghin cu s gim hot tnh xc tc.

Kho st TPRx phn ng reforming

trn xc tc Ni to sysgas

CH4 + CO2 2H2 + 2CO

K thut kho st hp ph ha hc xung ng xc nh tng lng

hp thu, din tch b mt v phn tn xc tc kim loi (vd: Pd/Al2O3).


Sc k kh

(GC)

u do nhit &

dn (TCD)

Khi ph

(QMS)

u im C th phn tch c

nhiu kh gii hp.

nh lng chnh xc

kh phn tch.

Cho tn hiu o lin

tc ca MT thnh

phn phn tch.

Cho tn hiu o lin tc,

xc nh ng thi CC

thnh phn phn tch.

nh lng chnh xc kh

phn tch.

D dng pht hin r kh

v thnh phn khng tinh

khit (gy nhim bn).

Nhc im Khng th thc hin

c cc php o lin

tc.

Khng th xc nh

c mt thnh phn

cha nh danh m m

khng kt hp thm

vi detector.

Ch c th theo di

lin tc mt thnh

phn phn tch c

trong kh mang.

Nc tuyt i

khng c c trong

dng kh phn tch.

Vn chi ph ?!

Bng so snh u v nhc im ca cc loi Detector dng kho st xc

tc bng k thut chng trnh nhit 1

1. A. Trovarelli,6th Italian Chem. Soc. Seminar on Catalysis, 2001, 220


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