Sistema: Metanol(A) Agua(B) DIAGRAMA T-x,y a Presión constanteConstantes d A1 7.87863 8.07131

presión en Ki A2 1473.11 1730.63 Ingrese la Presión, mmMercurio, =A3 230 233.426 TsA=

TsB=

T °C PsA113.24574772 3862.9894249111.48374772 3670.9546497

A12 0.7923 109.72174772 3486.6215509A21 0.5434 107.95974772 3309.7660664

106.19774772 3140.1675224104.43574772 2977.6086698102.67374772 2821.875718100.91174772 2672.758367199.149747725 2530.049838397.387747725 2393.546902195.625747725 2263.049904293.863747725 2138.3627992.101747725 2019.293126490.339747725 1905.652121588.577747725 1797.254642186.815747725 1693.919229585.053747725 1595.46811283.291747725 1501.727216181.529747725 1412.526174979.767747725 1327.6983341

76.93316577 1200DIAGRAMA P-x,y a Temperatura constante

Ingrese la Temperatura en °C =

En mmHg PsA=

PsB=

P mmHg PsA369.16186132 1386.5703116

418.3670107 1386.5703116467.57216008 1386.5703116516.77730946 1386.5703116565.98245884 1386.5703116615.18760822 1386.5703116

664.3927576 1386.5703116713.59790698 1386.5703116762.80305636 1386.5703116812.00820574 1386.5703116

21

3

sat AlnP A

T A

B vBA

A vA B vB

A vAA A

P Px

P P

Py x

P

861.21335512 1386.5703116910.4185045 1386.5703116

959.62365388 1386.57031161008.8288033 1386.57031161058.0339526 1386.5703116

1107.239102 1386.57031161156.4442514 1386.57031161205.6494008 1386.57031161254.8545502 1386.57031161304.0596995 1386.57031161386.5703116 1386.5703116

1200 1.578947368421 atm76.93316577 puro

113.2457477 puro

Raoult-DaltonPsB xAsupuesto xA calculado yA xA

1200 1.89E-06 2.20846137 1 -7.566238E-13 1.345593E-05 01131.562491 0.010167209 2.16260194 1.00013285 0.0100317576 0.0672629814 0.026950351066.384777 0.021512377 2.11345718 1.00059225 0.0211024567 0.1321007906 0.05520751004.346041 0.034230169 2.06079951 1.00149276 0.0333890649 0.1945632622 0.08486695945.3284076 0.048604421 2.0042155 1.00299504 0.0471133498 0.2549128694 0.11603201889.2169286 0.064933663 1.94348804 1.00531735 0.0625494977 0.3131397129 0.14881455835.8995607 0.083630404 1.87828951 1.00877008 0.0800457712 0.3693884948 0.18333576785.2671468 0.105626238 1.80706631 1.01390264 0.1001112763 0.4251325464 0.21972704737.2133942 0.130280747 1.73368424 1.02101394 0.123099558 0.4762095179 0.25813097691.6348513 0.160072861 1.65323576 1.03150084 0.1500082493 0.5278532425 0.29870236648.4308833 0.195106331 1.56889644 1.04645933 0.1815652377 0.577269385 0.34160945607.5036466 0.237297714 1.48019896 1.06822036 0.2189970091 0.6259127408 0.38703519568.7580615 0.287475791 1.39039804 1.09942828 0.2633405151 0.6726026068 0.43517868532.1017843 0.347283739 1.30199499 1.14424347 0.3157332813 0.7180524009 0.48625682497.4451774 0.41827989 1.21853798 1.2083837 0.3769201476 0.7633688304 0.54050601464.7012787 0.499514839 1.14588156 1.29674251 0.4463444503 0.807978075 0.59818417

433.78577 0.5893538838 1.08777349 1.41368335 0.5228359784 0.8523569398 0.65957293404.6169431 0.687007031 1.04510173 1.56437549 0.6054845935 0.898523738 0.72498005377.1156665 0.789125252 1.01792256 1.74848364 0.6944714569 0.9455313674 0.79474211351.2053494 0.893254629 1.00396904 1.96320452 0.793361093 0.9922332143 0.8692276312.6750164 1.000056465 1 2.2086056 0.9999999978 1.0000564659 1

DIAGRAMA P-x,y a Temperatura constante

81

1386.570312 puro

369.1618613 puro

Raoult-DaltonPsB xAsupuesto xA calculado yA xA

369.1618613 1.00E-06 1.34245417 1 -2.575818E-13 5.042252E-06 0369.1618613 0.034673937 1.31578194 1.00123182 0.0335098665 0.1512068769 0.04836322369.1618613 0.070505677 1.28973417 1.00501391 0.0681293594 0.2696606313 0.09672644369.1618613 0.107543596 1.264356 1.01148845 0.1039158776 0.3648315491 0.14508966369.1618613 0.145840209 1.23969322 1.0208152 0.1409282717 0.4429252402 0.19345288369.1618613 0.1854537 1.21579299 1.0331733 0.17922726 0.5081939096 0.2418161369.1618613 0.226055332 1.1929183 1.04860002 0.2188618367 0.5627849352 0.29017932369.1618613 0.269632569 1.1701092 1.06816133 0.2599705069 0.6130375424 0.33854254369.1618613 0.313921862 1.14868992 1.09112264 0.3025384909 0.6554715488 0.38690577369.1618613 0.359888906 1.12825149 1.11812412 0.3466729717 0.6933553239 0.43526899

A B

A B

369.1618613 0.407398212 1.10895884 1.14929826 0.3924439865 0.7273872529 0.48363221369.1618613 0.45724502 1.0906291 1.18542141 0.439974545 0.7594984389 0.53199543369.1618613 0.509172972 1.07352577 1.2265748 0.4893424846 0.7898029791 0.58035865369.1618613 0.562571459 1.05796868 1.27238669 0.5406089371 0.8180407331 0.62872187369.1618613 0.618522112 1.04378886 1.32384208 0.5939255297 0.8460775638 0.67708509369.1618613 0.676805455 1.03123995 1.38072582 0.6493629343 0.874025417 0.72544831369.1618613 0.737476623 1.02050388 1.4428428 0.7069713481 0.9023605785 0.77381153369.1618613 0.800495754 1.01179064 1.50960257 0.7667192621 0.9314736049 0.82217475369.1618613 0.865645638 1.0053302 1.57981833 0.8284229894 0.9616064823 0.87053797369.1618613 0.93237087 1.00134786 1.65144753 0.8916527451 0.9927001664 0.91890119369.1618613 1.000002 1 1.72185324 1 1.000002 1

Temperatura Liquido Vapor Temperatura100 0 0 100

96.4 0.02 0.134 96.493.5 0.04 0.23 93.591.2 0.06 0.304 91.289.3 0.08 0.365 89.387.7 0.1 0.418 87.784.4 0.15 0.517 84.481.7 0.2 0.579 81.7

78 0.3 0.665 7875.3 0.4 0.729 75.373.1 0.5 0.779 73.171.2 0.6 0.825 71.269.3 0.7 0.87 69.367.5 0.8 0.915 67.5

66 0.9 0.958 6665 0.95 0.979 65

64.5 1 1 64.5

Raoult-DaltonyA

00.0824446

0.160406380.234074780.303633290.36925957

0.43112560.489397730.544236840.59579843

0.64423270.6896847

0.732294440.772196950.809522440.844396390.876939650.907268560.935495030.96172669

1

Raoult-DaltonyA

00.160287510.286839170.389291510.473929920.545028910.605596660.657811680.703290370.74325733

-0.2 0 0.2 0.4 0.6 0.8 1 1.20

20

40

60

80

100

120

T vs X,Y

LiquidoVaporLiquido idealVapor ideal

Composicion

Tem

pera

tura

-0.2 0 0.2 0.4 0.6 0.8 1 1.20

200

400

600

800

1000

1200

1400

1600

P vs X,Y

LiquidoVaporLiquido idealVapor ideal

Composicion

Pres

ion

0.778657290.810230750.838566320.864137770.88733077

0.90846240.927795780.945551090.961913960.97704201

1

-0.2 0 0.2 0.4 0.6 0.8 1 1.20

200

400

600

800

1000

1200

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1600

P vs X,Y

LiquidoVaporLiquido idealVapor ideal

Composicion

Pres

ion

-0.2 0 0.2 0.4 0.6 0.8 1 1.20

20

40

60

80

100

120

T vs X,Y

LiquidoVaporLiquido idealVapor ideal

Composicion

Tem

pera

tura

-0.2 0 0.2 0.4 0.6 0.8 1 1.20

200

400

600

800

1000

1200

1400

1600

P vs X,Y

LiquidoVaporLiquido idealVapor ideal

Composicion

Pres

ion

25

-0.2 0 0.2 0.4 0.6 0.8 1 1.20

200

400

600

800

1000

1200

1400

1600

P vs X,Y

LiquidoVaporLiquido idealVapor ideal

Composicion

Pres

ion

25